Mark E. Thompson
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View article: 1252 Platin-based chemotherapies effectively induce an immunogenic cell death in preclinical models of triple negative breast cancer
1252 Platin-based chemotherapies effectively induce an immunogenic cell death in preclinical models of triple negative breast cancer Open
View article: Evaluation of a Residential Managed Alcohol Program for Aboriginal Peoples Experiencing Homelessness and Alcohol Dependence: Short‐Term Impacts of an Australian Trial
Evaluation of a Residential Managed Alcohol Program for Aboriginal Peoples Experiencing Homelessness and Alcohol Dependence: Short‐Term Impacts of an Australian Trial Open
Introduction Homelessness and alcohol dependence can be barriers to accessing essential services such as health care, housing, and social supports. Managed alcohol programs (MAP) have emerged as an effective harm reduction strategy for peo…
View article: Lone Pairs of Carbogenic Center Enable Thermally Activated Delayed Fluorescence from Carbon to Ligand Charge Transfer Excited States
Lone Pairs of Carbogenic Center Enable Thermally Activated Delayed Fluorescence from Carbon to Ligand Charge Transfer Excited States Open
Carbogenic compounds of the type L→C(0)←L, where L represents various ligands such as phosphines or carbenes, and C(0) denotes zerovalent carbon with two orthogonal lone pairs, are widely utilized in organic and coordination chemistry; how…
View article: Atherosclerosis as a cause of death in patients with cancer: a cohort study
Atherosclerosis as a cause of death in patients with cancer: a cohort study Open
View article: Ordered Cationic Mixing in a 1D Organic–Inorganic Hybrid
Ordered Cationic Mixing in a 1D Organic–Inorganic Hybrid Open
Hybrid metal halides are a remarkably dynamic family of materials that offer a flexible platform for exploring the novel crystal chemistry that emerges at the intersection of organic and inorganic solids. Herein, we report the discovery of…
View article: Electron-rich phenanthroline bearing N-heterocyclic imine substituents: synthesis, optical properties, metal coordination
Electron-rich phenanthroline bearing N-heterocyclic imine substituents: synthesis, optical properties, metal coordination Open
A new electron-rich 1,10-phenanthroline ligand with bulky NHI groups forms a well-structured coordination cavity, showing selective coordination of Lewis acids at phenanthroline nitrogen atoms and tunable electronic and photophysical prope…
View article: Digold photosensitizer for visible light [2 + 2] cycloaddition and <i>E</i> / <i>Z</i> isomerization reactions
Digold photosensitizer for visible light [2 + 2] cycloaddition and <i>E</i> / <i>Z</i> isomerization reactions Open
Energy transfer photocatalysis has emerged as a powerful platform for a variety of transformations, yet advances in this area are often limited by visible-light absorption of catalysts and the high cost of state-of-the-art iridium-based ca…
View article: Correction to “Intra- and Inter-Molecular Charge Transfer Dynamics of Carbene–Metal–Amide Photosensitizers”
Correction to “Intra- and Inter-Molecular Charge Transfer Dynamics of Carbene–Metal–Amide Photosensitizers” Open
[This corrects the article DOI: 10.1021/acs.jpcc.4c01994.].
View article: Structural Diversity in 2-(2-Aminoethyl)pyridine-Based Lead Iodide Hybrids
Structural Diversity in 2-(2-Aminoethyl)pyridine-Based Lead Iodide Hybrids Open
While 2D metal-organic hybrids have emerged as promising solar absorbers due to their improved moisture stability, their inferior transport properties limit their potential translation into devices. We report a new hybrid containing 2-(2-a…
View article: Intra- and Intermolecular Charge-Transfer Dynamics of Carbene–Metal–Amide Photosensitizers
Intra- and Intermolecular Charge-Transfer Dynamics of Carbene–Metal–Amide Photosensitizers Open
A series of steady-state and time-resolved spectroscopies were performed on a set of eight carbene-metal-amide (cMa) complexes, where M = Cu and Au, that have been used as photosensitizers for photosensitized electrocatalytic reactions. Us…
View article: Organic electroluminescent materials and devices
Organic electroluminescent materials and devices Open
A compound of Formula X wherein ring A is absent, or present and selected from a 5-membered or 6-membered, carbocyclic or heterocyclic ring, which is optionally substituted; ring B is absent, or present and selected from a 5-membered or 6-…
View article: Excited state management
Excited state management Open
Arrangements and techniques for providing organic emissive layers are provided, in which the emissive layer includes a first dopant having a dissociative energy level. A second dopant in the emissive layer provides a solid state sink energ…
View article: Synthesis of aza-acenes as novel n-type materials for organic electronics
Synthesis of aza-acenes as novel n-type materials for organic electronics Open
Acenes, such as aza-acenes are attractive materials for organic semiconductors, specifically for n-type materials. There are disclosed new derivatives of acenes that are fabricated using novel synthesis. For example, the disclosed fabricat…
View article: CCDC 2282395: Experimental Crystal Structure Determination
CCDC 2282395: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Light-driven hydrogen evolution<i>via</i>a novel pincer/no pincer mechanism including a possible concerted proton electron transfer
Light-driven hydrogen evolution<i>via</i>a novel pincer/no pincer mechanism including a possible concerted proton electron transfer Open
New water reduction catalysts containing secondary amines in the backbones show turnover numbers for photochemical hydrogen evolution up to 2237.
View article: CCDC 2283038: Experimental Crystal Structure Determination
CCDC 2283038: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2283098: Experimental Crystal Structure Determination
CCDC 2283098: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: “Quick-Silver” from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes
“Quick-Silver” from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes Open
A systematic study\nis presented on the physical and photophysical\nproperties of isoelectronic and isostructural Cu, Ag, and Au complexes\nwith a common amide (N-carbazolyl) and two different carbene ligands\n(i.e., CAAC = (5R,6…
View article: Blue and Near-UV Phosphorescence from Iridium Complexes with Cyclometalated Pyrazolyl or N-Heterocyclic Carbene Ligands
Blue and Near-UV Phosphorescence from Iridium Complexes with Cyclometalated Pyrazolyl or N-Heterocyclic Carbene Ligands Open
Two approaches are reported to achieve efficient blue to near-UV emission from triscyclometalated iridium(III)\nmaterials related to the previously reported complex, fac-Ir(ppz)3 (ppz = 1-phenylpyrazolyl-N,C…
View article: Temperature Dependence of Blue Phosphorescent Cyclometalated Ir(III) Complexes
Temperature Dependence of Blue Phosphorescent Cyclometalated Ir(III) Complexes Open
The photophysical properties for a series of facial (fac) cyclometalated Ir(III) complexes (fac-Ir(C∧N)3 (C∧N = 2-phenylpyridyl (ppy), 2-(4,6-difluorophenyl)pyridyl (F2ppy), 1-phenylpyrazolyl …
View article: Platinum-Functionalized Random Copolymers for Use in Solution-Processible, Efficient, Near-White Organic Light-Emitting, Diodes
Platinum-Functionalized Random Copolymers for Use in Solution-Processible, Efficient, Near-White Organic Light-Emitting, Diodes Open
A near-white light-emitting polymer, consisting of hole transport (HT), electron transport (ET), and phosphorescent Pt functionalities, was prepared and utilized as the emissive layer in solution-processed OLEDs. The air-stable devices had…
View article: Highly Efficient Photo- and Electroluminescence from Two-Coordinate Cu(I) Complexes Featuring Nonconventional N-Heterocyclic Carbenes
Highly Efficient Photo- and Electroluminescence from Two-Coordinate Cu(I) Complexes Featuring Nonconventional N-Heterocyclic Carbenes Open
A series of six luminescent two-coordinate\nCu(I) complexes were\ninvestigated bearing nonconventional N-heterocyclic carbene ligands,\nmonoamido-aminocarbene (MAC*) and diamidocarbene (DAC*), along with\ncarbazolyl (Cz) as well as mono- …
View article: Simultaneous Light Emission from a Mixture of Dendrimer Encapsulated Chromophores: A Model for Single-Layer Multichromophoric Organic Light-Emitting Diodes
Simultaneous Light Emission from a Mixture of Dendrimer Encapsulated Chromophores: A Model for Single-Layer Multichromophoric Organic Light-Emitting Diodes Open
The site isolation of two dyes capable of electronic interaction via Forster energy transfer has\nbeen studied with the two dyes coumarin 343 and pentathiophene encapsulated by dendrons containing\nboth solubilizing and electroactive moiet…
View article: Phosphorescence versus Thermally Activated Delayed Fluorescence: Controlling Singlet–Triplet Splitting in Brightly Emitting and Sublimable Cu(I) Compounds
Phosphorescence versus Thermally Activated Delayed Fluorescence: Controlling Singlet–Triplet Splitting in Brightly Emitting and Sublimable Cu(I) Compounds Open
Photophysical properties of two highly\nemissive three-coordinate\nCu(I) complexes, (IPr)Cu(py2-BMe2) (1) and (Bzl-3,5Me)Cu(py2-BMe2) (2), with two different N-heterocyclic (NH…
View article: Cationic Bis-cyclometalated Iridium(III) Diimine Complexes and Their Use in Efficient Blue, Green, and Red Electroluminescent Devices
Cationic Bis-cyclometalated Iridium(III) Diimine Complexes and Their Use in Efficient Blue, Green, and Red Electroluminescent Devices Open
A series of cationic Ir(III) complexes with the general formula (C∧N)2Ir(N∧N)+PF6- featuring bis-cyclometalated\n1-phenylpyrazolyl-N,C<…
View article: A Codeposition Route to CuI–Pyridine Coordination Complexes for Organic Light-Emitting Diodes
A Codeposition Route to CuI–Pyridine Coordination Complexes for Organic Light-Emitting Diodes Open
We demonstrate a new approach for utilizing CuI coordination complexes as emissive layers in organic light-emitting diodes that involves in situ codeposition of CuI and 3,5-bis(carbazol-9-yl)pyridine (mCPy). With a simple three-layer devic…
View article: Synthesis and Characterization of Phosphorescent Cyclometalated Iridium Complexes
Synthesis and Characterization of Phosphorescent Cyclometalated Iridium Complexes Open
The preparation, photophysics, and solid state structures of octahedral organometallic Ir complexes with several\ndifferent cyclometalated ligands are reported. IrCl3·nH2O cleanly cyclometalates a number of dif…
View article: Synthetic Control of Excited-State Properties in Cyclometalated Ir(III) Complexes Using Ancillary Ligands
Synthetic Control of Excited-State Properties in Cyclometalated Ir(III) Complexes Using Ancillary Ligands Open
The synthesis and photophysical characterization of a series of (N,C2‘-(2-para-tolylpyridyl))2Ir(LL‘) [(tpy)2Ir(LL‘)] (LL‘\n= 2,4-pentanedionato (acac), bis(pyrazolyl)borate ligands and their …
View article: Rapid Multiscale Computational Screening for OLED Host Materials
Rapid Multiscale Computational Screening for OLED Host Materials Open
The design of new host materials\nfor phosphorescent organic light emitting diodes (OLEDs) is challenging\nbecause several physical property requirements must be met simultaneously.\nA triplet energy (ET) higher than that…
View article: Phosphorescence Quenching by Conjugated Polymers
Phosphorescence Quenching by Conjugated Polymers Open
Energy transfer between phosphors and conjugated polymers was investigated using a fluorene trimer (F3) as a model conjugated material. The phosphors studied were bis-cyclometalated iridium complexes (FP, PPY, BT, PQ, and BTP), …