Martina Sanadar
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View article: Cobalt(II) complex formation with nitrate and chloride anions in the [C4mim][Tf2N] ionic liquid
Cobalt(II) complex formation with nitrate and chloride anions in the [C4mim][Tf2N] ionic liquid Open
This study investigates the coordination chemistry and thermodynamics of cobalt(II) complex formation with nitrate (NO3−) and chloride (Cl−) anions in the dry ionic liquid [C4mim][Tf2N]. Using UV–visible spectrophotometry, isothermal titra…
View article: Near Infrared–Circularly Polarized Luminescence/Circular Dichroism Active Yb(III) Complexes Bearing Both Central and Axial Chirality
Near Infrared–Circularly Polarized Luminescence/Circular Dichroism Active Yb(III) Complexes Bearing Both Central and Axial Chirality Open
In this contribution, we present new NIR-CPL/CD active Yb(III) complexes, which are synthesized by combining two ligands characterized by different types of chirality: central and axial chirality. The ligand bearing central chirality is re…
View article: Exploring Bioinspired Ln<sup>3+</sup> Complexes for Cu<sup>2+</sup> Detection: Design and Efficacy as MRI Contrast Agents
Exploring Bioinspired Ln<sup>3+</sup> Complexes for Cu<sup>2+</sup> Detection: Design and Efficacy as MRI Contrast Agents Open
Imaging extracellular Cu 2+ in vivo is important due to its role in physiological and pathological processes. Magnetic resonance imaging is a promising modality for this purpose but developing contrast agents selective for Cu 2+ over abund…
View article: Multi-Analytical Approach for the Acid-Base, Thermal and Surface Properties Assessment of Waste Biomasses
Multi-Analytical Approach for the Acid-Base, Thermal and Surface Properties Assessment of Waste Biomasses Open
A multi-analytical approach was used to comprehensively characterize the acid-base, thermal, and surface properties of agri-food processing wastes (i.e., original and pre-treated bergamot, grape and olive pomaces). These biomasses, often u…
View article: A Bioinspired Cu<sup>2+</sup>-Responsive Magnetic Resonance Imaging Contrast Agent with Unprecedented Turn-On Response and Selectivity
A Bioinspired Cu<sup>2+</sup>-Responsive Magnetic Resonance Imaging Contrast Agent with Unprecedented Turn-On Response and Selectivity Open
Imaging extracellular Cu2+ in vivo is of paramount interest due to its biological importance in both physiological and pathological states. Magnetic resonance imaging (MRI) is a powerful technique to do so. However, the developm…
View article: Selective Co(II) and Ni(II) Separation Using the Trihexyl(tetradecyl)phosphonium Decanoate Ionic Liquid
Selective Co(II) and Ni(II) Separation Using the Trihexyl(tetradecyl)phosphonium Decanoate Ionic Liquid Open
The room temperature ionic liquid trihexyl(tetradecyl)phosphonium decanoate ([P66614][Dec]) was employed in the liquid-liquid extraction of Co(II) from hydrochloric acid solutions in the presence of Ni(II). The extraction performance in li…
View article: Hydrometallurgical recovery of metals from spent lithium-ion batteries with ionic liquids and deep eutectic solvents
Hydrometallurgical recovery of metals from spent lithium-ion batteries with ionic liquids and deep eutectic solvents Open
The widespread adoption of lithium-ion batteries (LIBs) in modern electric vehicles has successfully addressed the issues of limited oil and gas resources, as well as environmental degradation. This development is crucial for achieving "ca…
View article: Thermodynamics of complex formation of silver(I) with substituted pyridines and cyclic amines in non-aqueous solvents
Thermodynamics of complex formation of silver(I) with substituted pyridines and cyclic amines in non-aqueous solvents Open
The understanding of the thermodynamic stability and speciation of metal complexes in solution requires access to their enthalpy and entropy of formation. In this work, we specifically focus our investigation on the complexation process of…
View article: Circularly polarized luminescence activity in the near infrared spectral region of a water-soluble ytterbium(<scp>iii</scp>) complex containing a conjugated chromophoric ligand
Circularly polarized luminescence activity in the near infrared spectral region of a water-soluble ytterbium(<span>iii</span>) complex containing a conjugated chromophoric ligand Open
A chiral Yb( iii ) complex bearing a conjugated chromophoric ligand exhibits potential as NIR-to-NIR chiroptical probe for biological purposes.
View article: Circularly Polarized Luminescence from New Heteroleptic Eu(III) and Tb(III) Complexes
Circularly Polarized Luminescence from New Heteroleptic Eu(III) and Tb(III) Complexes Open
The complexes [Eu(bpcd)(tta)], [Eu(bpcd)(Coum)], and [Tb(bpcd)(Coum)] [tta = 2-thenoyltrifluoroacetyl-acetonate, Coum = 3-acetyl-4-hydroxy-coumarin, and bpcd = N,N'-bis(2-pyridylmethyl)-trans-1,2-diaminocyclohexane-…
View article: Comparative study on removal of platinum cytostatic drugs at trace level by cysteine, diethylenetriamino functionalized Si-gels and polyethyleneimine functionalized sponge: Adsorption performance and mechanisms
Comparative study on removal of platinum cytostatic drugs at trace level by cysteine, diethylenetriamino functionalized Si-gels and polyethyleneimine functionalized sponge: Adsorption performance and mechanisms Open
To efficiently remove trace Pt-based cytostatic drugs (Pt-CDs) from aqueous environments, a comparative investigation was conducted on the adsorption behavior of three commercial adsorbents including cysteine-functionalized silica gel (Si-…
View article: Evaluation of Dithiocarbamate-Modified Silica for Cisplatin Removal from Water
Evaluation of Dithiocarbamate-Modified Silica for Cisplatin Removal from Water Open
Despite the globally increasing use of platinum-based cytostatic drugs in the treatment of several types of cancer, only limited attention has been paid to developing a treatment for contaminated liquid samples originating from hospitals, …
View article: Removal of Platinum Cytostatic Drugs at Trace Levels from Hospital Wastewater Analog Samples by Commercial Functionalized Adsorbents
Removal of Platinum Cytostatic Drugs at Trace Levels from Hospital Wastewater Analog Samples by Commercial Functionalized Adsorbents Open
View article: Dynamics of the Energy Transfer Process in Eu(III) Complexes Containing Polydentate Ligands Based on Pyridine, Quinoline, and Isoquinoline as Chromophoric Antennae
Dynamics of the Energy Transfer Process in Eu(III) Complexes Containing Polydentate Ligands Based on Pyridine, Quinoline, and Isoquinoline as Chromophoric Antennae Open
In this work, we investigated from a theoretical point of view the dynamics of the energy transfer process from the ligand to Eu(III) ion for 12 isomeric species originating from six different complexes differing by nature of the ligand an…
View article: Entropy and Enthalpy Effects on Metal Complex Formation in Non-Aqueous Solvents: The Case of Silver(I) and Monoamines
Entropy and Enthalpy Effects on Metal Complex Formation in Non-Aqueous Solvents: The Case of Silver(I) and Monoamines Open
Access to the enthalpy and entropy of the formation of metal complexes in solution is essential for understanding the factors determining their thermodynamic stability and speciation. As a case study, in this report we systematically exami…
View article: Regreening properties of the soil slow-mobile H2bpcd/Fe3+ complex: Steps forward to the development of a new environmentally friendly Fe fertilizer
Regreening properties of the soil slow-mobile H2bpcd/Fe3+ complex: Steps forward to the development of a new environmentally friendly Fe fertilizer Open
The application of synthetic Fe-chelates stands for the most established agronomical practice to alleviate lime-induced chlorosis, which still constitutes a major agronomic problem. However, the percolation through the soil profile due to …
View article: The Dark Side of Platinum Based Cytostatic Drugs: From Detection to Removal
The Dark Side of Platinum Based Cytostatic Drugs: From Detection to Removal Open
The uncontrolled release of pharmaceutical drugs into the environment raised serious concerns in the last decades as they can potentially exert adverse effects on living organisms even at the low concentrations at which they are typically …
View article: Effect of the Heteroaromatic Antenna on the Binding of Chiral Eu(III) Complexes to Bovine Serum Albumin
Effect of the Heteroaromatic Antenna on the Binding of Chiral Eu(III) Complexes to Bovine Serum Albumin Open
The cationic enantiopure (R,R) and luminescent Eu(III) complex [Eu(bisoQcd)(H2O)2] OTf (with bisoQcd = N,N'-bis(2-isoquinolinmethyl)-trans-1,2-diaminocyclohexane N,N'-d…