Martyn P. Coles
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View article: Heavier alkaline earth and heterobimetallic s-block “ate” complexes of a di(amido)siloxane ligand: solid-state structure and dynamic solution-phase behaviour
Heavier alkaline earth and heterobimetallic s-block “ate” complexes of a di(amido)siloxane ligand: solid-state structure and dynamic solution-phase behaviour Open
Heavy alkaline earth and heterobimetallic s-block “ate” complexes.
View article: 1,4-Dialumination of benzene by sodium and potassium aluminyls
1,4-Dialumination of benzene by sodium and potassium aluminyls Open
View article: CCDC 2310396: Experimental Crystal Structure Determination
CCDC 2310396: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2310398: Experimental Crystal Structure Determination
CCDC 2310398: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2310397: Experimental Crystal Structure Determination
CCDC 2310397: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Mixing and matching <i>N</i>,<i>N</i>- and <i>N</i>,<i>O</i>-chelates in anionic Mg(<scp>i</scp>) compounds: synthesis and reactivity with RNCNR and CO
Mixing and matching <i>N</i>,<i>N</i>- and <i>N</i>,<i>O</i>-chelates in anionic Mg(<span>i</span>) compounds: synthesis and reactivity with RNCNR and CO Open
Reduction of a bis(amidodimethyl)disiloxane Mg( ii ) compound affords a mixture of N , N - and N , O -chelated Mg( i ) species. Reactivity with RNCNR and CO demonstrate reducing behaviour, with the products showing a combination of ligan…
View article: Aluminyl derived ethene functionalization with heteroallenes, leading to an intramolecular ligand rearrangement
Aluminyl derived ethene functionalization with heteroallenes, leading to an intramolecular ligand rearrangement Open
Functionalization of ethene as a component of an aluminacyclopropane has been achieved using heteroallenes (CO 2 , carbodiimide). A spontaneous ‘at metal’ ligand rearrangement occurs which alleviates steric congestion at the Al centre.
View article: CCDC 2286381: Experimental Crystal Structure Determination
CCDC 2286381: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2286370: Experimental Crystal Structure Determination
CCDC 2286370: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2292511: Experimental Crystal Structure Determination
CCDC 2292511: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2292504: Experimental Crystal Structure Determination
CCDC 2292504: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Complexes containing discrete In–Pn bonds (Pn = Pnictide, Sb/Bi)
Complexes containing discrete In–Pn bonds (Pn = Pnictide, Sb/Bi) Open
The potassium indyl K[In(NONDipp)] ([NONDipp]2– = [O(SiMe2NDipp)2]2–, Dipp = 2,6-iPr2C6H3) reacts with Pn(NONtBu)Cl (Pn = pnictide = Sb, Bi) to afford complexes containing In–Pn bonds. X-ray crystallography confirms monomeric species with …
View article: Reductive Coupling of a Diazoalkane Derivative Promoted by a Potassium Aluminyl and Elimination of Dinitrogen to Generate a Reactive Aluminium Ketimide
Reductive Coupling of a Diazoalkane Derivative Promoted by a Potassium Aluminyl and Elimination of Dinitrogen to Generate a Reactive Aluminium Ketimide Open
The reaction of 9‐diazo‐9 H ‐fluorene (fluN 2 ) with the potassium aluminyl K[Al(NON)] ([NON] 2− =[O(SiMe 2 NDipp) 2 ] 2− , Dipp=2,6‐ i Pr 2 C 6 H 3 ) affords K[Al(NON)(κ N 1 , N 3 ‐{(fluN 2 ) 2 })] ( 1 ). Structural analysis shows a near …
View article: Three Oxidative Addition Routes of Alkali Metal Aluminyls to Dihydridoaluminates and Reactivity with CO<sub>2</sub>
Three Oxidative Addition Routes of Alkali Metal Aluminyls to Dihydridoaluminates and Reactivity with CO<sub>2</sub> Open
Three distinct routes are reported to the soluble, dihydridoaluminate compounds, AM[Al(NON Dipp )(H) 2 ] (AM=Li, Na, K, Rb, Cs; [NON Dipp ] 2− =[O(SiMe 2 NDipp) 2 ] 2− ; Dipp=2,6‐ i Pr 2 C 6 H 3 ) starting from the alkali metal aluminyls, …
View article: CCDC 2247346: Experimental Crystal Structure Determination
CCDC 2247346: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2247347: Experimental Crystal Structure Determination
CCDC 2247347: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2247348: Experimental Crystal Structure Determination
CCDC 2247348: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2247351: Experimental Crystal Structure Determination
CCDC 2247351: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2247349: Experimental Crystal Structure Determination
CCDC 2247349: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2247345: Experimental Crystal Structure Determination
CCDC 2247345: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2247350: Experimental Crystal Structure Determination
CCDC 2247350: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2161068: Experimental Crystal Structure Determination
CCDC 2161068: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2161064: Experimental Crystal Structure Determination
CCDC 2161064: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2161063: Experimental Crystal Structure Determination
CCDC 2161063: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2161065: Experimental Crystal Structure Determination
CCDC 2161065: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2161071: Experimental Crystal Structure Determination
CCDC 2161071: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2195976: Experimental Crystal Structure Determination
CCDC 2195976: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2161067: Experimental Crystal Structure Determination
CCDC 2161067: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2161070: Experimental Crystal Structure Determination
CCDC 2161070: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2161069: Experimental Crystal Structure Determination
CCDC 2161069: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …