Mathieu Pascaretti
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View article: Synergistic Gold‐Silicon Catalysis: Unravelling Alkynyl Gold Reactivity and Application to the High‐Performance C‐Alkynylation of Glycals
Synergistic Gold‐Silicon Catalysis: Unravelling Alkynyl Gold Reactivity and Application to the High‐Performance C‐Alkynylation of Glycals Open
Within the synergistic gold‐silicon catalysis concept, we have reported here the efficient and highly α‐stereoselective Au‐Si‐catalyzed alkyne transfer from 1‐trimethylsilylalkynes to glycals, at room temperature and at low loading (0.2–1 …
View article: Recent advances in the construction of quaternary pseudoanomeric centers in <i>gem-C</i>,<i>C</i>-glycosides: from zaragozic acids to remdesivir
Recent advances in the construction of quaternary pseudoanomeric centers in <i>gem-C</i>,<i>C</i>-glycosides: from zaragozic acids to remdesivir Open
This review outlines recent advances in synthesizing gem-C , C -glycosides ( i.e. , glycomimetics with quaternary pseudo-anomeric centers), emphasizing innovative approaches like C–H activation and HAT methods.
View article: Gold(I)-Catalyzed Access to 1-Alkynyl <i>C</i>-Glycosides from 1-Silylated Alkynes: An Alternative Paradigm for the Direct and α-Stereoselective Alkynylation of Glycosides
Gold(I)-Catalyzed Access to 1-Alkynyl <i>C</i>-Glycosides from 1-Silylated Alkynes: An Alternative Paradigm for the Direct and α-Stereoselective Alkynylation of Glycosides Open
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