Matteo Savastano
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View article: Ketoprofen Recognition and Sensing by Zn(II) Complexes with Fluorogenic Triamine Receptors
Ketoprofen Recognition and Sensing by Zn(II) Complexes with Fluorogenic Triamine Receptors Open
Ligands L1 and L2 are composed, respectively, by a diethylenetriamine or a dipropylenetriamine moiety linked at their extremities to anthracene units through methylene bridges and form stable 1:1 complexes with Zn(II), in which the metal i…
View article: Incommensurately modulated sodium polyiodide crystal structure discloses unconventional 1D iodine chains
Incommensurately modulated sodium polyiodide crystal structure discloses unconventional 1D iodine chains Open
View article: Supramolecular Assembly of Graphene–Polyamine–PdS–CdS Photocatalysts for Synergistically Enhanced and Highly Effective Hydrogen Evolution from Water under Visible Light
Supramolecular Assembly of Graphene–Polyamine–PdS–CdS Photocatalysts for Synergistically Enhanced and Highly Effective Hydrogen Evolution from Water under Visible Light Open
New composite materials for water reduction based on the CdS photocatalyst were prepared by sequential deposition of semiconductor PdS and CdS on a platform obtained from graphene nanoplatelets (GNPs) noncovalently functionalized by the ad…
View article: The Acid-Base Concept in Modern Supramolecular Chemistry
The Acid-Base Concept in Modern Supramolecular Chemistry Open
Acid-Base theories/definitions were elaborated far before the onset of Supramolecular Chemistry. While acid-base official definitions have long remained untouched, in the last decade Supramolecular Chemistry provided many new additions to …
View article: 1D Iodine Chains: The Innocent Complexity of a Thread of Iodine Beads
1D Iodine Chains: The Innocent Complexity of a Thread of Iodine Beads Open
Gold-green crystals with metallic lustre of the [Na(DMSO)3]n(I2)n compound serendipitously crystallized and attracted our attention. After following a trail starting at the discovery of the blue starch-iodine complexes (1810s) up to the fi…
View article: Fluorescent Deferoxamine Complexes of Cu(II) and Zr(IV): Insights in the Development of Dual Imaging Probes
Fluorescent Deferoxamine Complexes of Cu(II) and Zr(IV): Insights in the Development of Dual Imaging Probes Open
Deferoxamine (DFO) is widely regarded as benchmark chelator for 89 Zr(IV), a commonly used PET (positron emission tomography) tracer. We have introduced a novel fluorescent coumarin derivative of DFO (DFOKC), characterized by chelating uni…
View article: From waste to fuel cells. In situ preparation of an atomically precise Pd(II)-catalyst by selective extraction of Pd(II) from a mixture of metal ions using modified multi walled carbon nanotubes (MWCNTs) and its implementation in the oxygen reduction reaction (ORR) in alkaline solution
From waste to fuel cells. In situ preparation of an atomically precise Pd(II)-catalyst by selective extraction of Pd(II) from a mixture of metal ions using modified multi walled carbon nanotubes (MWCNTs) and its implementation in the oxygen reduction reaction (ORR) in alkaline solution Open
View article: Selective binding and fluorescence sensing of Zn(<scp>ii</scp>)/Cd(<scp>ii</scp>) using macrocyclic tetra-amines with different fluorophores: insights into the design of selective chemosensors for transition metals
Selective binding and fluorescence sensing of Zn(<span>ii</span>)/Cd(<span>ii</span>) using macrocyclic tetra-amines with different fluorophores: insights into the design of selective chemosensors for transition metals Open
Among a series of polyamine-based fluorescent ligands with quinoline of 8-hydroxyquinoline, receptors with lower ability in Zn( ii ) or Cd( ii ) binding display the highest performance in their optical sensing.
View article: Rethinking Polyiodides: The Role of Electron-Deficient Multicenter Bonds
Rethinking Polyiodides: The Role of Electron-Deficient Multicenter Bonds Open
Despite a bicentennial history, the interest in polyiodides and related systems still flourishes. The chemical puzzle provided by the intricate nature of chemical bonding in these polyanions remains challenging these days. The advent of th…
View article: Electron-deficient multicenter bonding in phase change materials: A chance for reconciliation
Electron-deficient multicenter bonding in phase change materials: A chance for reconciliation Open
In the last years, a controversy has been raised regarding the nature of the chemical bond in phase change materials. Two bonding models have claimed to be able to explain their extraordinary properties: the metavalent bonding model and th…
View article: CCDC 2309460: Experimental Crystal Structure Determination
CCDC 2309460: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2309462: Experimental Crystal Structure Determination
CCDC 2309462: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2309463: Experimental Crystal Structure Determination
CCDC 2309463: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2309461: Experimental Crystal Structure Determination
CCDC 2309461: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2309459: Experimental Crystal Structure Determination
CCDC 2309459: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Oxygen reduction reaction (ORR) in alkaline solution catalysed by an atomically precise catalyst based on a Pd(<scp>ii</scp>) complex supported on multi-walled carbon nanotubes (MWCNTs). Electrochemical and structural considerations
Oxygen reduction reaction (ORR) in alkaline solution catalysed by an atomically precise catalyst based on a Pd(<span>ii</span>) complex supported on multi-walled carbon nanotubes (MWCNTs). Electrochemical and structural considerations Open
Apical interaction of O 2 with a square planar macrocyclic Pd( ii ) complex anchored on MWCNTs gives rise to a significant electrocatalytic activity towards the oxygen reduction reaction (ORR). This finding confirms previous computational …
View article: From Waste to Fuel Cells. In Situ Preparation of an Atomically Precise Pd(Ii)-Catalyst by Selective Extraction of Pd(Ii) from a Mixture of Metal Ions Using Modified Multi Walled Carbon Nanotubes (Mwcnts) and its Implementation in the Oxygen Reduction Reaction (Orr) in Alkaline Solution
From Waste to Fuel Cells. In Situ Preparation of an Atomically Precise Pd(Ii)-Catalyst by Selective Extraction of Pd(Ii) from a Mixture of Metal Ions Using Modified Multi Walled Carbon Nanotubes (Mwcnts) and its Implementation in the Oxygen Reduction Reaction (Orr) in Alkaline Solution Open
View article: A Norbornadiene-Based Molecular System for the Storage of Solar–Thermal Energy in an Aqueous Solution: Study of the Heat-Release Process Triggered by a Co(II)-Complex
A Norbornadiene-Based Molecular System for the Storage of Solar–Thermal Energy in an Aqueous Solution: Study of the Heat-Release Process Triggered by a Co(II)-Complex Open
It is urgent yet challenging to develop new environmentally friendly and cost-effective sources of energy. Molecular solar thermal (MOST) systems for energy capture and storage are a promising option. With this in mind, we have prepared a …
View article: CCDC 2252947: Experimental Crystal Structure Determination
CCDC 2252947: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252946: Experimental Crystal Structure Determination
CCDC 2252946: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252949: Experimental Crystal Structure Determination
CCDC 2252949: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252948: Experimental Crystal Structure Determination
CCDC 2252948: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Crystal engineering of high explosives through lone pair-π interactions: Insights for improving thermal safety
Crystal engineering of high explosives through lone pair-π interactions: Insights for improving thermal safety Open
View article: CCDC 2237493: Experimental Crystal Structure Determination
CCDC 2237493: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2253139: Experimental Crystal Structure Determination
CCDC 2253139: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2253140: Experimental Crystal Structure Determination
CCDC 2253140: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2253138: Experimental Crystal Structure Determination
CCDC 2253138: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Pyrene-Containing Polyamines as Fluorescent Receptors for Recognition of PFOA in Aqueous Media
Pyrene-Containing Polyamines as Fluorescent Receptors for Recognition of PFOA in Aqueous Media Open
The globally widespread perfluorooctanoic acid (PFOA) is a concerning environmental contaminant, with a possible toxic long-term effects on the environment and human health The development of sensible, rapid, and low-cost detection systems…
View article: Evaluation of coumarin-tagged deferoxamine as a Zr(IV)-based PET/fluorescence dual imaging probe
Evaluation of coumarin-tagged deferoxamine as a Zr(IV)-based PET/fluorescence dual imaging probe Open
View article: Anion Coordination into Ligand Clefts
Anion Coordination into Ligand Clefts Open
A tripodal anion receptor has been obtained by an easy and fast single-reaction synthesis from commercial reagents. The three ligand arms-bearing aromatic groups able to form anion–π interactions define ligand clefts where large anions, su…