Matthew G. Davidson
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View article: Bio-Based, Degradable, and Tunable Epoxy Thermosets from Homogenized Acids and Epoxidized Linseed Oil or Glycerol Triglycidyl Ether
Bio-Based, Degradable, and Tunable Epoxy Thermosets from Homogenized Acids and Epoxidized Linseed Oil or Glycerol Triglycidyl Ether Open
View article: Zinc‐Catalysed Depolymerization of Poly(Butylene Succinate) and Poly(Butylene Adipate‐ <i>co</i> ‐Terephthalate) and Enhanced Degradation of Catalyst‐Polymer Composite Films
Zinc‐Catalysed Depolymerization of Poly(Butylene Succinate) and Poly(Butylene Adipate‐ <i>co</i> ‐Terephthalate) and Enhanced Degradation of Catalyst‐Polymer Composite Films Open
The depolymerization of poly(butylene succinate) (PBS) and poly(butylene adipate‐ co ‐terephthalate) (PBAT) with a highly active zinc catalyst was investigated. The methanolysis of PBS in solution was optimised by varying temperature, cata…
View article: Photo-Initiated Depolymerization of Consumer Poly(methyl methacrylate): Chlorine Not Required
Photo-Initiated Depolymerization of Consumer Poly(methyl methacrylate): Chlorine Not Required Open
The chemical recycling of commodity acrylic polymers, such as the transparent thermoplastic polymethyl methacrylate (PMMA), typically requires temperatures of 350–400°C. Herein, we report chemical recycling back to monomers for PMMA betwee…
View article: Diversity in Zwitterionic Metal Ammonium Tris(phenolate)s for the Controlled Immortal Polymerization of Lactide: Dramatic Activity Enhancement and Mechanistic Insight on Expansion beyond Zirconium
Diversity in Zwitterionic Metal Ammonium Tris(phenolate)s for the Controlled Immortal Polymerization of Lactide: Dramatic Activity Enhancement and Mechanistic Insight on Expansion beyond Zirconium Open
Reaction of tris-(2,4-dimethylbenzyl)-amine, H3LMe, with tris- or tetrakis-(alkoxide)-s of large metals consistently affords, respectively, pseudo-homoleptic and homoleptic zwitterionic compounds [M-(III)-(HL
View article: Imino‐Pyrrole Zn(II) Complexes for the Rapid and Selective Chemical Recycling of Commodity Polymers
Imino‐Pyrrole Zn(II) Complexes for the Rapid and Selective Chemical Recycling of Commodity Polymers Open
Three imino‐pyrrole zinc complexes were prepared and applied to the rapid degradation of polylactic acid (PLA) and the depolymerization of bisphenol A polycarbonate (BPA‐PC) and polyethylene terephthalate (PET). PLA alcoholysis proceeded r…
View article: Imino‐Pyrrole Zn(II) Complexes for the Rapid and Selective Chemical Recycling of Commodity Polymers
Imino‐Pyrrole Zn(II) Complexes for the Rapid and Selective Chemical Recycling of Commodity Polymers Open
Three imino‐pyrrole zinc complexes were prepared and applied to the rapid degradation of polylactic acid (PLA) and the depolymerization of bisphenol A polycarbonate (BPA‐PC) and polyethylene terephthalate (PET). PLA alcoholysis proceeded r…
View article: Valorization of polyoxymethylene (POM) waste as a C<sub>1</sub> synthon for industrially relevant dialkoxymethanes and cyclic aminals
Valorization of polyoxymethylene (POM) waste as a C<sub>1</sub> synthon for industrially relevant dialkoxymethanes and cyclic aminals Open
Two novel methods of upcycling waste polyoxymethylene (POM) are reported, generating dialkoxymethanes by alcoholysis and cyclic aminals by aminolysis. Mixed plastic depolymerizations containing POM were also investigated.
View article: Preface to ‘Green carbon for the chemical industry of the future’
Preface to ‘Green carbon for the chemical industry of the future’ Open
View article: Zinc {ONO} complexes for the chemical recycling of PET and PLA
Zinc {ONO} complexes for the chemical recycling of PET and PLA Open
Nine {ONO} ligands were prepared and treated with ZnEt2 to form a range of complexes. The resulting complexes were characterised in solution through 1H and 13C{1H} NMR spectroscopy, and in the solid state through single-crystal XRD and ele…
View article: Facile Synthesis of a Novel Furanic Monomer and Its ADMET Polymerization toward Fully Renewable Functional Polymers
Facile Synthesis of a Novel Furanic Monomer and Its ADMET Polymerization toward Fully Renewable Functional Polymers Open
Efficient and sustainable transformation of biomass-derived chemicals to materials with the potential to replace conventional fossil-derived polymers is considered a major challenge. In this work, we disclose the synthesis of a novel furan…
View article: Zinc {Ono} Complexes for the Chemical Recycling of Pet and Pla
Zinc {Ono} Complexes for the Chemical Recycling of Pet and Pla Open
View article: CCDC 2290157: Experimental Crystal Structure Determination
CCDC 2290157: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2290156: Experimental Crystal Structure Determination
CCDC 2290156: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2290159: Experimental Crystal Structure Determination
CCDC 2290159: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2290158: Experimental Crystal Structure Determination
CCDC 2290158: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2290160: Experimental Crystal Structure Determination
CCDC 2290160: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Unexpected Periodicity in Cationic Group 5 Initiators for the Ring-Opening Polymerization of Lactones
Unexpected Periodicity in Cationic Group 5 Initiators for the Ring-Opening Polymerization of Lactones Open
ε-Caprolactone (ε-CL) adducts of cationic, amine tris(phenolate)-supported niobium(V) and tantalum(V) ethoxides initiate the ring-opening polymerization of lactones. The Ta(V) species prepared and applied catalytically herein exhibits high…
View article: CCDC 2252664: Experimental Crystal Structure Determination
CCDC 2252664: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252663: Experimental Crystal Structure Determination
CCDC 2252663: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252661: Experimental Crystal Structure Determination
CCDC 2252661: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252662: Experimental Crystal Structure Determination
CCDC 2252662: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252658: Experimental Crystal Structure Determination
CCDC 2252658: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252660: Experimental Crystal Structure Determination
CCDC 2252660: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252659: Experimental Crystal Structure Determination
CCDC 2252659: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252657: Experimental Crystal Structure Determination
CCDC 2252657: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Coordination of ε-Caprolactone to a Cationic Niobium(V) Alkoxide Complex: Fundamental Insight into Ring-Opening Polymerization via Coordination–Insertion
Coordination of ε-Caprolactone to a Cationic Niobium(V) Alkoxide Complex: Fundamental Insight into Ring-Opening Polymerization via Coordination–Insertion Open
We report three niobium-based initiators for the catalytic ring-opening polymerization (ROP) of ε-caprolactone, exhibiting good activity and molecular weight control. In particular, we have prepared on the gram-scale and fully characterize…
View article: CCDC 2206271: Experimental Crystal Structure Determination
CCDC 2206271: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Sustainable Syntheses of Paracetamol and Ibuprofen from Biorenewable β‐pinene
Sustainable Syntheses of Paracetamol and Ibuprofen from Biorenewable β‐pinene Open
Scalable processes have been developed to convert β‐pinene into 4‐isopropenylcyclohexanone, which is then used as a feedstock for the divergent synthesis of sustainable versions of the common painkillers, paracetamol and ibuprofen. Both sy…
View article: CCDC 2253111: Experimental Crystal Structure Determination
CCDC 2253111: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Supplementary Figure 3 from Restoring Retinoic Acid Attenuates Intestinal Inflammation and Tumorigenesis in APC<sup>Min/+</sup> Mice
Supplementary Figure 3 from Restoring Retinoic Acid Attenuates Intestinal Inflammation and Tumorigenesis in APC<sup>Min/+</sup> Mice Open
Sorting strategy to obtain DCs and DC subsets from the LP.