Matthis Seiler
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View article: Synthesis and Electrochemistry of Copper(I) Complexes with Weakly Basic, Fluorinated, and Multicyclic Arenes
Synthesis and Electrochemistry of Copper(I) Complexes with Weakly Basic, Fluorinated, and Multicyclic Arenes Open
The dinitrogen complex [(N 2 )Cu{Al(OR F ) 4 }] (R F = C(CF 3 ) 3 ) acts as the precursor for the synthesis of homoleptic, weakly bound Cu(I)‐arene complexes with benzene, fluorinated, and multicyclic arenes. Upon dissolution of [(N 2 )Cu{…
View article: Pushing the redox potentials of deelectronators to highly positive values using solvent effects and weakly coordinating anions
Pushing the redox potentials of deelectronators to highly positive values using solvent effects and weakly coordinating anions Open
While the development of weakly coordinating anions (WCAs) received much attention, the progress on new weakly coordinating and inert solvents almost stagnated. Here we study the effect of strategic F-substitution on the solvent properties…
View article: CCDC 2172146: Experimental Crystal Structure Determination
CCDC 2172146: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2173940: Experimental Crystal Structure Determination
CCDC 2173940: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2179801: Experimental Crystal Structure Determination
CCDC 2179801: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2176517: Experimental Crystal Structure Determination
CCDC 2176517: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2216007: Experimental Crystal Structure Determination
CCDC 2216007: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2177613: Experimental Crystal Structure Determination
CCDC 2177613: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2178939: Experimental Crystal Structure Determination
CCDC 2178939: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Isolation, Structural and Physical Characterization as well as Reactivity of Persistent Acenium Radical Cation Salts
Isolation, Structural and Physical Characterization as well as Reactivity of Persistent Acenium Radical Cation Salts Open
The unsubstituted acenium radical cations (ARCs) are extremely sensitive and were hitherto only studied in situ, i. e. in the gas phase, as dilute solutions in strong acids or by matrix isolation spectroscopy at about 10 K. In this study, …
View article: CCDC 2250354: Experimental Crystal Structure Determination
CCDC 2250354: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2192467: Experimental Crystal Structure Determination
CCDC 2192467: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2184666: Experimental Crystal Structure Determination
CCDC 2184666: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2194802: Experimental Crystal Structure Determination
CCDC 2194802: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Coordination versus Insertion: On the Interaction of 5 d‐Transition Metal Carbonyl Clusters with Silver(I)
Coordination versus Insertion: On the Interaction of 5 d‐Transition Metal Carbonyl Clusters with Silver(I) Open
The title silver(I) complex salts [Ag{Re 2 (CO) 10 }{Re(CO) 5 } 2 ] + [Al(OR F ) 4 ] − (AgRe 4 ; OR F =‐OC(CF 3 ) 3 ) and [Ag{Ir 4 (CO) 12 } 2 ] + [Al(OR F ) 4 ] − (AgIr 8 ) form upon reaction of Ag + [Al(OR F ) 4 ] − and the transition me…