Matvey V. Fedin
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View article: Inter-Kramers electric quadrupole transitions in high-spin systems induced by resonant alternating inhomogeneous electric field
Inter-Kramers electric quadrupole transitions in high-spin systems induced by resonant alternating inhomogeneous electric field Open
This study presents a theoretical analysis of the interaction of high-spin systems with inhomogeneous alternating electric field and homogeneous alternating magnetic field that induce electric quadrupole (QT, E2) and magnetic dipole transi…
View article: Pressure Sensitivity of UiO-66 Framework with Encapsulated Spin Probe: A Molecular Dynamics Study
Pressure Sensitivity of UiO-66 Framework with Encapsulated Spin Probe: A Molecular Dynamics Study Open
Probes sensitive to mechanical stress are in high demand for analyzing pressure distributions in materials. Metal–organic frameworks (MOFs) are especially promising for designing pressure sensors due to their structural tunability. In this…
View article: Thionated Perylenebisimides as Heavy‐Atom‐Free Triplet Photosensitizers: Intersystem Crossing, Electron Spin Dynamics, and Application in Photodynamic Therapy
Thionated Perylenebisimides as Heavy‐Atom‐Free Triplet Photosensitizers: Intersystem Crossing, Electron Spin Dynamics, and Application in Photodynamic Therapy Open
The thionation induced intersystem crossing (ISC) in perylenebisimide (PBI) derivatives was studied. The triplet state lifetimes of the thionated PBIs are substantially shortened (0.12–0.78 µs) as compared to the unsubstituted PBI (ca. 130…
View article: «Green-Ligand» in Metallodrugs Design—Cu(II) Complex with Phytic Acid: Synthetic Approach, EPR-Spectroscopy, and Antimycobacterial Activity
«Green-Ligand» in Metallodrugs Design—Cu(II) Complex with Phytic Acid: Synthetic Approach, EPR-Spectroscopy, and Antimycobacterial Activity Open
The interaction of sodium phytate hydrate C6H18O24P6·xNa·yH2O (phytNa) with Cu(OAc)2·H2O and 1,10-phenanthroline (phen) led to the anionic tetranuclear complex [Cu4(H2O)4(phen)4(phyt)]·2Na+·2NH4+·32H2O (1), the structure of the latter was …
View article: Scalable Approach for Grafting Qubit Candidates onto The Surface of MOF-808 Framework
Scalable Approach for Grafting Qubit Candidates onto The Surface of MOF-808 Framework Open
The development of quantum bits (qubits) is crucial for the progress of quantum technologies. Among various approaches, the qubits based on paramagnetic centers have decent advantages, including their diversity and possibilities of regular…
View article: Temperature Dependence of the Sensitivity of PVDF Pyroelectric Sensors to THz Radiation: Towards Cryogenic Applications
Temperature Dependence of the Sensitivity of PVDF Pyroelectric Sensors to THz Radiation: Towards Cryogenic Applications Open
The application of terahertz (THz) science in industrial technology and scientific research requires efficient THz detectors. Such detectors should be able to operate under various external conditions and conform to existing geometric cons…
View article: Scalable Approach for Grafting Qubit Candidates onto the Surface of MOF-808 Framework
Scalable Approach for Grafting Qubit Candidates onto the Surface of MOF-808 Framework Open
The development of quantum bits (qubits) is crucial for the progress of quantum technologies. Among various approaches, the qubits based on paramagnetic centers have decent advantages, including their diversity and possibilities of regular…
View article: CCDC 2270321: Experimental Crystal Structure Determination
CCDC 2270321: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2270320: Experimental Crystal Structure Determination
CCDC 2270320: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2270319: Experimental Crystal Structure Determination
CCDC 2270319: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Nanoscale solvent organization in metal–organic framework ZIF-8 probed by EPR of flexible β-phosphorylated nitroxides
Nanoscale solvent organization in metal–organic framework ZIF-8 probed by EPR of flexible β-phosphorylated nitroxides Open
Molecules of alcohols exhibit specific nanoordering inside cavities of metal–organic frameworks, thus creating unique environments with anomalous apparent polarity sensed by solutes.
View article: Synthesis and photoinduced behavior of DPP-anchored nitronyl nitroxides: a multifaceted approach
Synthesis and photoinduced behavior of DPP-anchored nitronyl nitroxides: a multifaceted approach Open
Understanding and controlling spin dynamics in organic dyes is of significant scientific and technological interest.
View article: CCDC 2252621: Experimental Crystal Structure Determination
CCDC 2252621: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Toward New Horizons in Verdazyl-Nitroxide High-Spin Systems: Thermally Robust Tetraradical with Quintet Ground State
Toward New Horizons in Verdazyl-Nitroxide High-Spin Systems: Thermally Robust Tetraradical with Quintet Ground State Open
High-spin organic tetraradicals with significant intramolecular exchange interactions have high potential for advanced technological applications and fundamental research, but reported to date examples exhibit limited stability and process…
View article: CCDC 2301489: Experimental Crystal Structure Determination
CCDC 2301489: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2301492: Experimental Crystal Structure Determination
CCDC 2301492: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2301487: Experimental Crystal Structure Determination
CCDC 2301487: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2301488: Experimental Crystal Structure Determination
CCDC 2301488: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2301491: Experimental Crystal Structure Determination
CCDC 2301491: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2300480: Experimental Crystal Structure Determination
CCDC 2300480: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2301486: Experimental Crystal Structure Determination
CCDC 2301486: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2301490: Experimental Crystal Structure Determination
CCDC 2301490: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Catalytic System for Cross-Coupling of Heteroaryl Iodides with a Nitronyl Nitroxide Gold Derivative at Room Temperature
Catalytic System for Cross-Coupling of Heteroaryl Iodides with a Nitronyl Nitroxide Gold Derivative at Room Temperature Open
A simple and highly effective methodology for the cross-coupling of heteroaryl iodides with NN–AuPPh3 at room temperature is reported. The protocol is based on a novel catalytic system consisting of Pd2(dba)3·CHCl3 and the phosphine ligand…
View article: Comparative Study of Single Crystal and Polymeric Pyroelectric Detectors in the 0.9–2.0 THz Range Using Monochromatic Laser Radiation of the NovoFEL
Comparative Study of Single Crystal and Polymeric Pyroelectric Detectors in the 0.9–2.0 THz Range Using Monochromatic Laser Radiation of the NovoFEL Open
The development of efficient and reliable sensors operating at room temperature is essential to advance the application of terahertz (THz) science and technology. Pyroelectric THz detectors are among the best candidates, taking into accoun…
View article: Nitronyl Nitroxide-Substituted Benzotriazinyl Tetraradical
Nitronyl Nitroxide-Substituted Benzotriazinyl Tetraradical Open
High-spin organic tetraradicals with significant intramolecular exchange interactions have high potential for advanced technological applications and basic research, but those synthesized to date possess limited stability and processabilit…
View article: CCDC 2253668: Experimental Crystal Structure Determination
CCDC 2253668: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 608712: Experimental Crystal Structure Determination
CCDC 608712: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2253666: Experimental Crystal Structure Determination
CCDC 2253666: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …