Max von Delius
YOU?
Author Swipe
View article: Asymmetric Organocatalysis Enhanced by Nanohoop Confinement
Asymmetric Organocatalysis Enhanced by Nanohoop Confinement Open
Chiral phosphoric acids are privileged organocatalysts that have been shown to facil-itate important asymmetric transformations. The BINOL scaffold is the most popular choice for rendering a phosphoric acid chiral, yet high levels of enant…
View article: Melem‐Perylene Diimide Polymer Network as Efficient Positive Electrode for Rechargeable Lithium and Magnesium Batteries
Melem‐Perylene Diimide Polymer Network as Efficient Positive Electrode for Rechargeable Lithium and Magnesium Batteries Open
Organic battery electrode materials represent a sustainable alternative compared to most inorganic electrodes, yet challenges persist regarding their energy density and cycling stability. In this work, a new organic electrode material is d…
View article: A supramolecular ferroelectric with two sublattices and polarization dependent conductivity
A supramolecular ferroelectric with two sublattices and polarization dependent conductivity Open
The possibility to combine and finetune properties of functional molecular materials by chemical design is particularly relevant for organic ferroelectrics. In this work, we investigate a class of organic molecular materials that show long…
View article: Highly polar groups and supramolecular order enable charge injection and long-range conductivity in organic materials without extended π-systems
Highly polar groups and supramolecular order enable charge injection and long-range conductivity in organic materials without extended π-systems Open
Electronic conductivity in organic materials is well-established. Both semiconductive and metallic behavior is observed in (quasi) 0-, 1-, 2- and 3-dimensional carbon-based materials and is applied in a wide range of commercial devices. De…
View article: Thioorthoester Polymers as Sulfur‐Rich Materials in Metal Scavengers and Battery Cathodes
Thioorthoester Polymers as Sulfur‐Rich Materials in Metal Scavengers and Battery Cathodes Open
Polymeric materials with dynamic covalent carbon‐heteroatom bonds are of significant interest for their stimuli‐responsiveness and recyclability. This study investigates the utility of the dynamic covalent C─S bond in thioorthoesters for s…
View article: Front Cover: Thioorthoester Polymers as Sulfur‐Rich Materials in Metal Scavengers and Battery Cathodes
Front Cover: Thioorthoester Polymers as Sulfur‐Rich Materials in Metal Scavengers and Battery Cathodes Open
View article: Melem-PDI polymer network as efficient positive electrode for rechargeable lithium and magnesium batteries
Melem-PDI polymer network as efficient positive electrode for rechargeable lithium and magnesium batteries Open
Organic battery electrode materials represent a sustainable alternative compared to most inorganic electrodes, yet challenges persist regarding their energy density and cycling stability. In this work, we describe a new organic electrode m…
View article: Highly Loaded Reactive Oxygen Species–Responsive Theranostic Lenvatinib‐Prodrug Nanoparticles Produced by Dispersion Polymerization
Highly Loaded Reactive Oxygen Species–Responsive Theranostic Lenvatinib‐Prodrug Nanoparticles Produced by Dispersion Polymerization Open
Nanoparticles represent a powerful class of materials for drug delivery, leveraging their small size for passive targeting through the enhanced permeability and retention effect in tumors. This universal approach in tumor targeting offers …
View article: Inverse vulcanization of all-cis-fluorinated cyclohexylacrylate: Tailored polymers for Li-S battery cathode materials
Inverse vulcanization of all-cis-fluorinated cyclohexylacrylate: Tailored polymers for Li-S battery cathode materials Open
View article: Photostable triphenylmethyl-based diradicals with a degenerate singlet-triplet ground state and strong photoluminescence
Photostable triphenylmethyl-based diradicals with a degenerate singlet-triplet ground state and strong photoluminescence Open
TTM-based diradicals bridged by indolocarbazoles show high diradical character and up to 18% quantum yield, offering a promising route to stable, luminescent open-shell emitters with isoenergetic singlet and triplet ground states.
View article: Carbazole-functionalized Chichibabin diradicaloids with redshifted absorption and enhanced photoluminescence
Carbazole-functionalized Chichibabin diradicaloids with redshifted absorption and enhanced photoluminescence Open
We report two carbazole-functionalized Chichibabin diradicaloids that in comparison to the parent compound exhibit red-shifted absorption and 2–3-fold brighter emission.
View article: Observation of shuttling on the one-second timescale in a [10]cycloparaphenylene/C <sub>60</sub> [2]catenane
Observation of shuttling on the one-second timescale in a [10]cycloparaphenylene/C <sub>60</sub> [2]catenane Open
[2]Catenanes comprising identical binding sites are an excellent platform to study the unusually slow kinetics of concave–convex π–π interactions.
View article: Highly Loaded ROS-Responsive Theranostic Lenvatinib-Prodrug Nanoparticles Produced by Dispersion Polymerization
Highly Loaded ROS-Responsive Theranostic Lenvatinib-Prodrug Nanoparticles Produced by Dispersion Polymerization Open
Nanoparticles represent a powerful class of materials for drug delivery, leveraging their small size for passive targeting through the enhanced permeation and retention (EPR) effect in tumors. This universal approach in tumor targeting off…
View article: Highly Loaded ROS-Responsive Theranostic Lenvatinib-Prodrug Nanoparticles Produced by Dispersion Polymerization
Highly Loaded ROS-Responsive Theranostic Lenvatinib-Prodrug Nanoparticles Produced by Dispersion Polymerization Open
Nanoparticles represent a powerful class of materials for drug delivery, leveraging their small size for passive targeting through the enhanced permeation and retention (EPR) effect in tumors. This universal approach in tumor targeting off…
View article: Ring-in-Ring Assembly Facilitates the Synthesis of a Cyclopara-phenylene Hetero[3]Catenane
Ring-in-Ring Assembly Facilitates the Synthesis of a Cyclopara-phenylene Hetero[3]Catenane Open
Cycloparaphenylenes (CPPs) represent a significant challenge for the synthesis of mechanically interlocked architectures, because they lack heteroatoms, which precludes traditional active and passive template methods. To circumvent this pr…
View article: Nanohoops Favour Light‐Induced Energy Transfer over Charge Separation in Porphyrin/[10]CPP/Fullerene Rotaxanes
Nanohoops Favour Light‐Induced Energy Transfer over Charge Separation in Porphyrin/[10]CPP/Fullerene Rotaxanes Open
[2]Rotaxanes offer unique opportunities for studying and modulating charge separation and energy transfer, because the mechanical bond allows the robust, yet spatially dynamic tethering of photoactive groups. In this work, we synthesized […
View article: Nanohoops Favour Light‐Induced Energy Transfer over Charge Separation in Porphyrin/[10]CPP/Fullerene Rotaxanes
Nanohoops Favour Light‐Induced Energy Transfer over Charge Separation in Porphyrin/[10]CPP/Fullerene Rotaxanes Open
[2]Rotaxanes offer unique opportunities for studying and modulating charge separation and energy transfer, because the mechanical bond allows the robust, yet spatially dynamic tethering of photoactive groups. In this work, we synthesized […
View article: A Chiral Nanohoop as Highly Efficient Asymmetric Organocatalyst
A Chiral Nanohoop as Highly Efficient Asymmetric Organocatalyst Open
Chiral phosphoric acids are privileged organocatalysts that have been shown to facilitate a large variety of asymmetric transformations. In recent years, the BINOL scaffold has been equipped with large aromatic groups and transformed into …
View article: A Chiral Nanohoop as Highly Efficient Asymmetric Organocatalyst
A Chiral Nanohoop as Highly Efficient Asymmetric Organocatalyst Open
Chiral phosphoric acids are privileged organocatalysts that have been shown to facilitate a large variety of asymmetric transformations. In recent years, the BINOL scaffold has been equipped with large aromatic groups and transformed into …
View article: Screening Cobalt-based Catalysts on Multicomponent CdSe@CdS Nanorods for Photocatalytic Hydrogen Evolution in Aqueous Media
Screening Cobalt-based Catalysts on Multicomponent CdSe@CdS Nanorods for Photocatalytic Hydrogen Evolution in Aqueous Media Open
We present CdSe@CdS nanorods coated with a redox-active polydopamine (PDA) layer functionalized with cobaloxime-derived photocatalysts for efficient solar-driven hydrogen evolution in aqueous environments. The PDA-coating provides reactive…
View article: A Stable Chichibabin Diradicaloid with Near‐Infrared Emission
A Stable Chichibabin Diradicaloid with Near‐Infrared Emission Open
Conjugated molecules with multiple radical centers such as the iconic Chichibabin diradicaloid hold promise as building blocks in materials for quantum sensing and quantum information processing. However, it is a considerable challenge to …
View article: Ein Stabiles Chichibabin Diradikaloid mit Nahinfraroter Emission
Ein Stabiles Chichibabin Diradikaloid mit Nahinfraroter Emission Open
Konjugierte Moleküle mit mehreren Radikalzentren, wie das ikonische Chichibabin‐Diradikaloid, sind vielversprechende Bausteine für Materialien für die Quantensensorik und Quanteninformationsverarbeitung. Jedoch stellt es eine große Herausf…
View article: Simultaneous Inside and Outside Functionalization of Single‐Walled Carbon Nanotubes
Simultaneous Inside and Outside Functionalization of Single‐Walled Carbon Nanotubes Open
Functionalizing single‐walled carbon nanotubes (SWCNTs) in a robust way that does not affect the sp 2 carbon framework is a considerable research challenge. Here we describe how triiodide salts of positively charged macrocycles can be used…
View article: Simultane Funktionalisierung von Einwandigen Kohlenstoff‐Nanoröhren von Innen und Außen
Simultane Funktionalisierung von Einwandigen Kohlenstoff‐Nanoröhren von Innen und Außen Open
Die Funktionalisierung einwandiger Kohlenstoff‐Nanoröhren (SWCNTs) auf eine robuste Weise, die das sp 2 Kohlenstoffgerüst nicht beeinträchtigt ist in der aktuellen Forschung eine große Herausforderung. Hier beschreiben wir, wie Triiodidsal…
View article: Regioswitchable Bingel Bis-Functionalization of Fullerene C<sub>70</sub> via Supramolecular Masks
Regioswitchable Bingel Bis-Functionalization of Fullerene C<sub>70</sub> via Supramolecular Masks Open
Isomer-pure functionalized fullerenes are required to boost the development of fullerene chemistry in any field, but their multiple functionalization renders a mixture of regioisomers that are very difficult to purify by chromatography. Fo…
View article: An Algebraic Blueprint for Predicting Turnover Numbers and Endpoints in Photocatalysis
An Algebraic Blueprint for Predicting Turnover Numbers and Endpoints in Photocatalysis Open
The front cover artwork is provided by the Institute of Analytical and Bioanalytical Chemistry and the Institute of Inorganic Chemistry I at Ulm University within the Collaborative Research Center TRR 234 CataLight . The image shows an alg…
View article: Front Cover: An Algebraic Blueprint for Predicting Turnover Numbers and Endpoints in Photocatalysis (ChemPhysChem 3/2024)
Front Cover: An Algebraic Blueprint for Predicting Turnover Numbers and Endpoints in Photocatalysis (ChemPhysChem 3/2024) Open
Graphical Abstract The Front Cover illustrates an algebraic approach using defined boundary conditions based on a partial least squares regression model to generically calculate and predict the turnover number (TON) and the endpoint of a p…
View article: The Dynamic Chemistry of Orthoesters and Trialkoxysilanes: Making Supramolecular Hosts Adaptive, Fluxional, and Degradable
The Dynamic Chemistry of Orthoesters and Trialkoxysilanes: Making Supramolecular Hosts Adaptive, Fluxional, and Degradable Open
ConspectusThe encapsulation of ions into macro(bi)cyclic hosts lies at the core of supramolecular chemistry. While chemically inert hosts such as crown ethers (synthesis) and cyclodextrins (Febreze) have enabled real-world applications, th…
View article: Acylphosphates as versatile transient species in reaction networks and optical catalyst screenings
Acylphosphates as versatile transient species in reaction networks and optical catalyst screenings Open
Chemically driven reaction cycles are prevalent in nature; yet, artificial examples are still rare and often lack robustness or versatility. In this study, we introduce acylphosphate steady states that can be accessed from a wide range of …
View article: CCDC 2306058: Experimental Crystal Structure Determination
CCDC 2306058: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …