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View article: Regioregular Poly(<i>p</i>‐phenylene iminoborane): A Strictly Alternating BN‐Isostere of Poly(<i>p</i>‐phenylene vinylene) with Stimuli‐Responsive Behavior
Regioregular Poly(<i>p</i>‐phenylene iminoborane): A Strictly Alternating BN‐Isostere of Poly(<i>p</i>‐phenylene vinylene) with Stimuli‐Responsive Behavior Open
Incorporation of BN units into π‐conjugated organic compounds, as substitutes for specific CC couples, often leads to new hybrid materials with modified physical and chemical properties. Poly( p ‐phenylene iminoborane)s are derived from we…
View article: Regioregular Poly( <i>p</i> ‐phenylene iminoborane): A Strictly Alternating BN‐Isostere of Poly( <i>p</i> ‐phenylene vinylene) with Stimuli‐Responsive Behavior
Regioregular Poly( <i>p</i> ‐phenylene iminoborane): A Strictly Alternating BN‐Isostere of Poly( <i>p</i> ‐phenylene vinylene) with Stimuli‐Responsive Behavior Open
Incorporation of BN units into π‐conjugated organic compounds, as substitutes for specific CC couples, often leads to new hybrid materials with modified physical and chemical properties. Poly( p ‐phenylene iminoborane)s are derived from we…
View article: Poly(thiophene iminoborane): A Poly(thiophene vinylene) (PTV) Analogue with a Fully BN‐Doped Backbone
Poly(thiophene iminoborane): A Poly(thiophene vinylene) (PTV) Analogue with a Fully BN‐Doped Backbone Open
An unprecedented poly(thiophene iminoborane)—a boron–nitrogen analogue of the well‐established conjugated organic polymer poly(thiophene vinylene)—is presented. The polymer synthesis is achieved by selective Si/B exchange polycondensation …
View article: CCDC 2128817: Experimental Crystal Structure Determination
CCDC 2128817: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2128819: Experimental Crystal Structure Determination
CCDC 2128819: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2128818: Experimental Crystal Structure Determination
CCDC 2128818: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2128821: Experimental Crystal Structure Determination
CCDC 2128821: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2128820: Experimental Crystal Structure Determination
CCDC 2128820: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2128816: Experimental Crystal Structure Determination
CCDC 2128816: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Modulation of the Naked‐Eye and Fluorescence Color of a Protonated Boron‐Doped Thiazolothiazole by Anion‐Dependent Hydrogen Bonding
Modulation of the Naked‐Eye and Fluorescence Color of a Protonated Boron‐Doped Thiazolothiazole by Anion‐Dependent Hydrogen Bonding Open
The reaction of a cyclic alkyl(amino)carbene (CAAC)‐stabilized thiazaborolo[5,4‐ d ]thiazaborole (TzbTzb) with strong Brønsted acids, such as HCl, HOTf (Tf=O 2 SCF 3 ) and [H(OEt 2 ) 2 ][BAr F 4 ] (Ar F =3,5‐(CF 3 ) 2 C 6 H 3 ), results in…
View article: Thermodynamic equilibrium between locally excited and charge-transfer states through thermally activated charge transfer in 1-(pyren-2′-yl)-<i>o</i>-carborane
Thermodynamic equilibrium between locally excited and charge-transfer states through thermally activated charge transfer in 1-(pyren-2′-yl)-<i>o</i>-carborane Open
Reversible conversion between excited-states is key to many photophysical phenomena. We studied the equilibrium between LE and CT states by time-resolved and temperature-dependent fluorescence, fs- and ns-transient absorption, and LR-TDDFT…
View article: Diboramacrocycles: reversible borole dimerisation–dissociation systems
Diboramacrocycles: reversible borole dimerisation–dissociation systems Open
Diboramacrocycles are a new form of borole dimers, participating in various addition reactions as “masked” boroles. The reaction of a less crowded diboramacrocycle with organic azides affords unprecedented complex heteropropellanes.