Forrest E. Michael
YOU?
Author Swipe
View article: C−H Functionalization and Allylic Amination for Post‐Polymerization Modification of Polynorbornenes
C−H Functionalization and Allylic Amination for Post‐Polymerization Modification of Polynorbornenes Open
Post‐polymerization modification (PPM) via direct C−H functionalization is a powerful synthetic strategy to convert polymer feed‐stocks into value‐added products. We found that a metal‐free, Se‐catalyzed allylic C−H amination provided an e…
View article: C−H Functionalization and Allylic Amination for Post‐Polymerization Modification of Polynorbornenes
C−H Functionalization and Allylic Amination for Post‐Polymerization Modification of Polynorbornenes Open
Post‐polymerization modification (PPM) via direct C−H functionalization is a powerful synthetic strategy to convert polymer feed‐stocks into value‐added products. We found that a metal‐free, Se‐catalyzed allylic C−H amination provided an e…
View article: Upcycling of Polybutadiene Facilitated by Selenium‐Mediated Allylic Amination
Upcycling of Polybutadiene Facilitated by Selenium‐Mediated Allylic Amination Open
Accumulation of end‐of‐life plastics presents ongoing environmental concerns. One strategy to solve this grand challenge is to invent new techniques that modify post‐consumer waste and impart new functionality. While promising approaches f…
View article: Diastereoconvergent synthesis of <i>anti</i>-1,2-amino alcohols with N-containing quaternary stereocenters <i>via</i> selenium-catalyzed intermolecular C–H amination
Diastereoconvergent synthesis of <i>anti</i>-1,2-amino alcohols with N-containing quaternary stereocenters <i>via</i> selenium-catalyzed intermolecular C–H amination Open
We report a diastereoconvergent synthesis of anti -1,2-amino alcohols bearing N-containing quaternary stereocenters using an intermolecular direct C–H amination of homoallylic alcohol derivatives catalyzed by a phosphine selenide.
View article: Stereoretentive and regioselective selenium-catalyzed intermolecular propargylic C–H amination of alkynes
Stereoretentive and regioselective selenium-catalyzed intermolecular propargylic C–H amination of alkynes Open
Selenium catalysis enables a general intermolecular propargylic C–H amination of alkynes. The concerted mechanism gives rise to high regioselectivity for the more electron-rich end of the alkyne and retention of the C–H propargylic stereoc…
View article: Selenophosphoramide-catalyzed diamination and oxyamination of alkenes
Selenophosphoramide-catalyzed diamination and oxyamination of alkenes Open
Scavenging fluoride from a selenophosphoramide-catalyzed alkene oxidation reaction suppresses the known syn-elimination pathway, enabling alkene diamination/oxyamination reactions via substitution.
View article: CCDC 1527484: Experimental Crystal Structure Determination
CCDC 1527484: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1037742: Experimental Crystal Structure Determination
CCDC 1037742: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …