Michael Kaplanis
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View article: Benzothiazole diimine rhenium(I) ‘2 + 1’ complexes: Synthesis, structural characterization and anticancer activity
Benzothiazole diimine rhenium(I) ‘2 + 1’ complexes: Synthesis, structural characterization and anticancer activity Open
In this work, novel '2 + 1' mixed ligand tricarbonyl ReI complexes of the general type fac-[Re(CO)3(NN)X]0/+, where NN is a diimine ligand bearing the anticancer scaffold of 2-(4'-aminophenyl)benzothiazole, and X is Br- (1), Η2Ο (2), pyrid…
View article: Crystal structure of <i>fac</i>-aqua[(<i>E</i>)-4-(benzo[<i>d</i>]thiazol-2-yl)-<i>N</i>-(pyridin-2-ylmethylidene)aniline-κ<sup>2</sup> <i>N</i>,<i>N</i>′]tricarbonylrhenium(I) hexafluoridophosphate methanol monosolvate
Crystal structure of <i>fac</i>-aqua[(<i>E</i>)-4-(benzo[<i>d</i>]thiazol-2-yl)-<i>N</i>-(pyridin-2-ylmethylidene)aniline-κ<sup>2</sup> <i>N</i>,<i>N</i>′]tricarbonylrhenium(I) hexafluoridophosphate methanol monosolvate Open
In the title compound, fac -[Re(C 19 H 13 N 3 S)(CO) 3 (H 2 O)]PF 6 ·CH 3 OH, the coordination environment of the Re I atom is octahedral with a C 3 N 2 O coordination set. In this molecule, the N , N ′ bidentate ligand, ( E )-4-(benzo[ d …