Michael T. Mock
YOU?
Author Swipe
View article: The [4Fe-4S] Cluster of HydF Is Essential for [FeFe]-Hydrogenase Maturation
The [4Fe-4S] Cluster of HydF Is Essential for [FeFe]-Hydrogenase Maturation Open
The organometallic H-cluster of the [FeFe]-hydrogenase is assembled in vivo through a complex process requiring the action of three dedicated maturation enzymes, HydG, HydE, and HydF, as well as the aminomethyl-lipoyl-H-protein (Hmet) of t…
View article: Contents list
Contents list Open
The Royal Society of Chemistry is the world's leading chemistry community.
View article: Halide-free synthesis of metastable graphitic BC <sub>3</sub>
Halide-free synthesis of metastable graphitic BC <sub>3</sub> Open
A halide-free route to the synthesis of graphitic BC 3 was discovered via decomposition temperature matching: benzene (C 6 H 6 ) as the carbon precursor and the borohydride anion (BH 4 − ) as the boron precursor.
View article: CCDC 2206175: Experimental Crystal Structure Determination
CCDC 2206175: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2206177: Experimental Crystal Structure Determination
CCDC 2206177: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2206176: Experimental Crystal Structure Determination
CCDC 2206176: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Corrigendum: Dinitrogen Activation and Functionalization with Chromium
Corrigendum: Dinitrogen Activation and Functionalization with Chromium Open
The authors wish to correct two inadvertent errors in the originally published version of the Minireview entitled "Dinitrogen Activation and Functionalization with Chromium".On page 1366, Figure 17 in the original publication lists the inc…
View article: Semisynthetic maturation of [FeFe]-hydrogenase using [Fe<sub>2</sub>(μ-SH)<sub>2</sub>(CN)<sub>2</sub>(CO)<sub>4</sub>]<sup>2−</sup>: key roles for HydF and GTP
Semisynthetic maturation of [FeFe]-hydrogenase using [Fe<sub>2</sub>(μ-SH)<sub>2</sub>(CN)<sub>2</sub>(CO)<sub>4</sub>]<sup>2−</sup>: key roles for HydF and GTP Open
The [FeFe]-hydrogenase can be matured using a defined semisynthetic approach in which the synthetic complex [2Fe] E bypasses the need for HydE and HydG, and glycine cleavage system components synthesize DTMA on [2Fe] E while it is bound to…
View article: Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex
Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex Open
This is the peer reviewed version of the following article: [Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex. Angewandte Chemie International Edition 62, 1 (2023)], which has been published in final form at https://doi.org/10…
View article: Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex
Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex Open
We report a nickel complex for catalytic oxidation of ammonia to dinitrogen under ambient conditions. Using the aryloxyl radical 2,4,6‐tri‐ tert ‐butylphenoxyl ( t Bu 3 ArO⋅) as a H atom acceptor to cleave the N−H bond of a coordinated NH …
View article: Electronic Supporting Information for Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex
Electronic Supporting Information for Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex Open
The dataset provides electronic supporting information in the format of XYZ molecular files, formatted Gaussian checkpoint files, and cube files for atomic spin density distributions for selected complexes obtained while investigating the …
View article: Electronic Supporting Information for Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex
Electronic Supporting Information for Catalytic Ammonia Oxidation to Dinitrogen by a Nickel Complex Open
The dataset provides electronic supporting information in the format of XYZ molecular files, formatted Gaussian checkpoint files, and cube files for atomic spin density distributions for selected complexes obtained while investigating the …
View article: Cover Feature: Dinitrogen Activation and Functionalization with Chromium (Eur. J. Inorg. Chem. 15‐16/2020)
Cover Feature: Dinitrogen Activation and Functionalization with Chromium (Eur. J. Inorg. Chem. 15‐16/2020) Open
The Cover Feature shows a “chromium cowboy” wrangling dinitrogen in one of the many scenic valleys of Montana, USA. This Minireview provides a comprehensive analysis of dinitrogen coordination chemistry and molecular catalytic systems usin…
View article: Frontispiece: Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction
Frontispiece: Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction Open
Ammonia Oxidation A molecular Ru-based catalyst converts NH3 into N2, as reported by M. T. Mock et al. in their Communication on page 11618. The cleavage of six N−H bonds was achieved by coupling H+ and e− transfers using the tBu3ArO. radi…
View article: Frontispiz: Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction
Frontispiz: Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction Open
Ammoniak-Oxidation Ein molekularer Ru-Katalysator wandelt NH3 in N2 um, wie M. T. Mock et al. in der Zuschrift auf S. 11744 berichten. Die Spaltung von sechs N-H-Bindungen wurde durch die Kopplung von Protonen- und Elektronentransfers unte…
View article: Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction
Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction Open
Catalysts for the oxidation of NH 3 are critical for the utilization of NH 3 as a large‐scale energy carrier. Molecular catalysts capable of oxidizing NH 3 to N 2 are rare. This report describes the use of [Cp*Ru(P t Bu 2 N Ph 2 )( 15 NH 3…
View article: Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction
Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction Open
Catalysts for the oxidation of NH 3 are critical for the utilization of NH 3 as a large‐scale energy carrier. Molecular catalysts capable of oxidizing NH 3 to N 2 are rare. This report describes the use of [Cp*Ru(P t Bu 2 N Ph 2 )( 15 NH 3…
View article: H <sub>2</sub> Binding, Splitting, and Net Hydrogen Atom Transfer at a Paramagnetic Iron Complex
H <sub>2</sub> Binding, Splitting, and Net Hydrogen Atom Transfer at a Paramagnetic Iron Complex Open
While diamagnetic transition metal complexes that bind and split H2 have been extensively studied, paramagnetic complexes that exhibit this behavior remain rare. The square planar S = 1/2 FeI(P4N2)+ cation (FeI+) reversibly binds H2/D2 in …
View article: CCDC 1873139: Experimental Crystal Structure Determination
CCDC 1873139: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1861040: Experimental Crystal Structure Determination
CCDC 1861040: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: H2 Binding, Splitting, and Net Hydrogen Atom Transfer at a Paramagnetic Iron Complex
H2 Binding, Splitting, and Net Hydrogen Atom Transfer at a Paramagnetic Iron Complex Open
The reactivity of H2 with abundant transition metals is crucial for developing catalysts for energy storage in chemical bonds. While diamagnetic transition metal complexes that bind and split H2 have been extensively studied, paramagnetic …
View article: H2 Binding, Splitting, and Net Hydrogen Atom Transfer at a Paramagnetic Iron Complex
H2 Binding, Splitting, and Net Hydrogen Atom Transfer at a Paramagnetic Iron Complex Open
The reactivity of H2 with abundant transition metals is crucial for developing catalysts for energy storage in chemical bonds. While diamagnetic transition metal complexes that bind and split H2 have been extensively studied, paramagnetic …
View article: CCDC 1549162: Experimental Crystal Structure Determination
CCDC 1549162: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …