Miguel Clemente‐León
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View article: Spin-Crossover Nanoparticles in Electrospun Polymers: A Route to Bistable Materials for Smart Textiles
Spin-Crossover Nanoparticles in Electrospun Polymers: A Route to Bistable Materials for Smart Textiles Open
Developing strategies that transform crystalline molecular materials into processable forms is crucial for enabling their manipulation and integration into devices. This challenge is particularly relevant for bistable systems such as spin-…
View article: Thermally Stable Anilate-Based 3D CPs/MOFs
Thermally Stable Anilate-Based 3D CPs/MOFs Open
The synthesis and characterization of two novel redox-active MOFs/CPs based on 3d transition metal ions and 3,6-ditriazolyl-2,5-dihydroxybenzoquinone (trz2An) are reported herein. By combining trz2An with NiII and MnII ions via the hydroth…
View article: Stepwise Spin Transitions of Spin-Crossover Complexes Based in 3-(2-Pyridyl)-1,2,4-triazole Ligands Associated with Symmetry Change in Hydrogen Bonding Interactions
Stepwise Spin Transitions of Spin-Crossover Complexes Based in 3-(2-Pyridyl)-1,2,4-triazole Ligands Associated with Symmetry Change in Hydrogen Bonding Interactions Open
Iron(II) compounds of a family of 3-(2-pyridyl)-1,2,4-triazole ligands with aliphatic substituents of different lengths and branching have been prepared and characterized together with the benzyl derivative with formula [Fe(L)3][X]2·(solv)…
View article: Spin liquid properties of the kagome material Cu$_3$(HOTP)$_2$
Spin liquid properties of the kagome material Cu$_3$(HOTP)$_2$ Open
The metal-organic-framework (MOF) compound Cu$_3$(HOTP)$_2$, a.k.a. Cu$_3$(HHTP)$_2$, is a small-gap semiconductor containing a kagome lattice of antiferromagnetically coupled $S$=1/2 Cu$^\mathrm{II}$ spins with intra-layer nearest-neighbo…
View article: A Novel Banana‐Shaped Mixed‐Metal Co/Fe Polyoxometalate Cluster
A Novel Banana‐Shaped Mixed‐Metal Co/Fe Polyoxometalate Cluster Open
The synthesis and characterization of a Co/Fe mixed‐metal banana‐shaped polyoxometalate with the formula [(Co 2.5 Fe 0.5 (H 2 O)PW 9 O 34 ) 2 (PW 6 O 26 )] 16− ( Co 5 Fe ) is reported. This transition‐metal‐substituted polyoxometalate read…
View article: Electronic structure and spin dynamics of the metal-organic-framework kagome spin liquid Cu3(HOTP)2
Electronic structure and spin dynamics of the metal-organic-framework kagome spin liquid Cu3(HOTP)2 Open
The metal-organic-framework (MOF) compound Cu$_3$(HOTP)$_2$ is a small-gap semiconductor containing a kagome lattice of antiferromagnetically coupled $S$=1/2 Cu$^\mathrm{II}$ spins with exchange coupling of order 2 K. First principles spin…
View article: Chiral spin-crossover complexes based on an enantiopure Schiff base ligand with three chiral carbon centers
Chiral spin-crossover complexes based on an enantiopure Schiff base ligand with three chiral carbon centers Open
Four enantiopure spin-crossover complexes have been prepared in which the unexpected incorporation of acetone leads to an additional chiral center.
View article: Tunable SIM properties in a family of 3D anilato-based lanthanide-MOFs
Tunable SIM properties in a family of 3D anilato-based lanthanide-MOFs Open
By reacting, for the first time, the H 2 trz 2 An anilate linker, bearing triazole substituents, with Dy III , Tb III and Ho III nodes, a novel family of 3D anilato-based lanthanide-MOFs/CPs, showing SIM properties, have been obtained.
View article: CCDC 2305594: Experimental Crystal Structure Determination
CCDC 2305594: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2299140: Experimental Crystal Structure Determination
CCDC 2299140: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2299138: Experimental Crystal Structure Determination
CCDC 2299138: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2299139: Experimental Crystal Structure Determination
CCDC 2299139: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2299137: Experimental Crystal Structure Determination
CCDC 2299137: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Spin-crossover tuning of the luminescence in 2D Hofmann-type compounds in bulk and exfoliated flakes
Spin-crossover tuning of the luminescence in 2D Hofmann-type compounds in bulk and exfoliated flakes Open
Two Hofmann-type multifunctional materials are reported, displaying a tuning of the luminescence properties by the spin-crossover, and have exfoliated by in nanometric flakes by the Scotch-tape method.
View article: Spin‐Crossover Grafted Monolayer of a Co(II) Terpyridine Derivative Functionalized with Carboxylic Acid Groups
Spin‐Crossover Grafted Monolayer of a Co(II) Terpyridine Derivative Functionalized with Carboxylic Acid Groups Open
The synthesis and characterization of a new Co(II) spin‐crossover (SCO) complex based on 4′‐(4‐carboxyphenyl)−2,2′:6′,2″‐terpyridine ligand are reported. This complex can be successfully grafted on silver surface maintaining the SCO behavi…
View article: CCDC 2230345: Experimental Crystal Structure Determination
CCDC 2230345: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2230346: Experimental Crystal Structure Determination
CCDC 2230346: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2230342: Experimental Crystal Structure Determination
CCDC 2230342: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2230352: Experimental Crystal Structure Determination
CCDC 2230352: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2230349: Experimental Crystal Structure Determination
CCDC 2230349: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2230351: Experimental Crystal Structure Determination
CCDC 2230351: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2230344: Experimental Crystal Structure Determination
CCDC 2230344: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2230343: Experimental Crystal Structure Determination
CCDC 2230343: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2230350: Experimental Crystal Structure Determination
CCDC 2230350: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2230348: Experimental Crystal Structure Determination
CCDC 2230348: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2230347: Experimental Crystal Structure Determination
CCDC 2230347: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Iron(II) Complexes of 2,6-Di[4-(ethylcarboxy)pyrazol-1-yl]pyridine with Reversible Guest-Modulated Spin-Crossover Behavior
Iron(II) Complexes of 2,6-Di[4-(ethylcarboxy)pyrazol-1-yl]pyridine with Reversible Guest-Modulated Spin-Crossover Behavior Open
Three solvatomorphs of the iron(II) complex of 2,6-di[4-(ethylcarboxy)pyrazol-1-yl]pyridine (bpCOOEt2p) of formulas [Fe(bpCOOEt2p)2](ClO4)2·1.5MeNO2 (1), [Fe(bpCOOEt2p)2](ClO4)2·MeNO2 (2), and [Fe(bpCOOEt2p)2](ClO4)2·2MeNO2 (3) have been p…
View article: CCDC 2213982: Experimental Crystal Structure Determination
CCDC 2213982: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2213983: Experimental Crystal Structure Determination
CCDC 2213983: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2213981: Experimental Crystal Structure Determination
CCDC 2213981: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …