Mitchell Maday
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View article: Syn vs. Anti? What Controls Addition Stereochemistry in Chlorolactonization
Syn vs. Anti? What Controls Addition Stereochemistry in Chlorolactonization Open
The stereochemistry of the uncatalyzed chlorolactonization of 4‐phenylpent‐4‐enoic acid at room temperature was examined to probe the reaction's intrinsic diastereoselectivities as a function of chlorenium ion donor, solvent polarity, and …
View article: Structure Guided Design of VANOL-imidodiphosphorimidate Catalysts for the Catalytic Enantioselective Bromo Spiroketalization Reaction
Structure Guided Design of VANOL-imidodiphosphorimidate Catalysts for the Catalytic Enantioselective Bromo Spiroketalization Reaction Open
This report presents a structure-guided approach for the optimization of VANOL-derived imidodiphosphorimidates as catalysts for the halonium-ion-induced spiroketalization reaction. Fine tuning of the catalyst active site, alongside enhance…