Mohammad B. Kassim
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View article: Tailoring Transition Intensity of Ruthenium(II) Complexes with π-Elongated Phenyl Ligands: Experimental and Computational Insights
Tailoring Transition Intensity of Ruthenium(II) Complexes with π-Elongated Phenyl Ligands: Experimental and Computational Insights Open
A series of novel ruthenium(II) complexes bearing π -elongated phenyl ligands have been synthesized via a 3-step reaction involving Ru(phen) 2 Cl 2 and functionalised phenanthroline ligands (phen- p -RCA; phen = phena…
View article: Perbandingan Aktiviti Fotoelektrokimia Busa Logam Nikel Selepas Olahan Haba dan Disalut dengan FE2O3 bagi Aplikasi Pembelahan Molekul Air
Perbandingan Aktiviti Fotoelektrokimia Busa Logam Nikel Selepas Olahan Haba dan Disalut dengan FE2O3 bagi Aplikasi Pembelahan Molekul Air Open
Pembelahan air secara fotoelektrokimia menggunakan tenaga cahaya yang diserap oleh fotoelektrod untuk menghasilkan elektron dan lohong yang membelah molekul air kepada hidrogen dan oksigen. Bahan fotoelektrod dalam kajian ini disediakan me…
View article: Photoelectrochemical characterisation of direct and pulse electrodeposited copper on fluorine-doped tin oxide glass
Photoelectrochemical characterisation of direct and pulse electrodeposited copper on fluorine-doped tin oxide glass Open
Electrodeposition (ED) is applied in several applications since it is one of the most user‐friendly and cost-effective techniques. The increasing popularity of this technique is due to its capacity to control the morphology and chemical co…
View article: Nanocellulose-Based Separators in Lithium-Ion Battery
Nanocellulose-Based Separators in Lithium-Ion Battery Open
Lithium-ion batteries are the essential parts of many portable electronic devices. They draw substantial recognition by virtue of their advantages over other batteries. Separators are critical to the working of lithium-ion batteries. The s…
View article: Theoretical Investigation of the Reaction Mechanism for Formation of Pyridinyl Formimidamide Ancillary Ligand in the Synthesis of a New Class of Iridium(Iii) Complexes
Theoretical Investigation of the Reaction Mechanism for Formation of Pyridinyl Formimidamide Ancillary Ligand in the Synthesis of a New Class of Iridium(Iii) Complexes Open
View article: A Coral-Like Mo2C/TiO2 Photoelectrode for Photoelectrochemical Water Splitting
A Coral-Like Mo2C/TiO2 Photoelectrode for Photoelectrochemical Water Splitting Open
Titanium dioxide (TiO2) is one of the most explored photoelectrode materials of water splitting for hydrogen generation. However, TiO2 has a bandgap of 3.2 eV, which restricts its energy absorption to UV light, and the photoexcited electro…
View article: TiO2 Nanotubes Decorated with Mo2C for Enhanced Photoelectrochemical Water-Splitting Properties
TiO2 Nanotubes Decorated with Mo2C for Enhanced Photoelectrochemical Water-Splitting Properties Open
The presence of Ti3+ in the structure of TiO2 nanotube arrays (NTs) has been shown to enhance the photoelectrochemical (PEC) water-splitting performance of these NTs, leading to improved results compared to pristine anatase TiO2 NTs. To fu…
View article: Composite of Titanium Dioxide Nanotube and Cobalt Sulfide for Photoelectrochemical Application
Composite of Titanium Dioxide Nanotube and Cobalt Sulfide for Photoelectrochemical Application Open
TiO2 nanotubes (NT) offer several advantages over other geometries for photoelectrochemical (PEC) applications. However, their performance in PEC water-splitting application has remained unsatisfactory due to its wide bandgap. To address t…
View article: Copper Nanoparticles Coating on FTO with Improved Adhesion Using Direct and Pulse Electrodeposition Techniques from a Simple Copper Sulphate Solution
Copper Nanoparticles Coating on FTO with Improved Adhesion Using Direct and Pulse Electrodeposition Techniques from a Simple Copper Sulphate Solution Open
Copper (Cu) metal nanoparticles were deposited onto FTO glass using the electrodeposition method. The precursor used was CuSO4×5H2O with Na2SO4 as the inorganic additive. The formation of Cu was characterized using field emission scanning …
View article: Hydrogen Production from Water Splitting using TiO2/CoS Composite Photocatalyst
Hydrogen Production from Water Splitting using TiO2/CoS Composite Photocatalyst Open
Photocatalytic water splitting reaction has been considered an ideal method for hydrogen generation. In this study, a composite of TiO2/CoS photocatalyst prepared by hydrothermal synthesis method assisted by ball milling crushing process w…
View article: CCDC 2169203: Experimental Crystal Structure Determination
CCDC 2169203: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Bio-Doped Microbial Nanosilica as Optosensing Biomaterial for Visual Quantitation of Nitrite in Cured Meats
Bio-Doped Microbial Nanosilica as Optosensing Biomaterial for Visual Quantitation of Nitrite in Cured Meats Open
A microbial optosensor for nitrite was constructed based on biomimetic silica nanoparticles, which were doped with R5, a polypeptide component of silaffin, as a robust biosilica immobilization matrix entrapped with Raoultella planticola an…
View article: CCDC 2115338: Experimental Crystal Structure Determination
CCDC 2115338: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Crystal structure of 2-(1<i>H</i>-pyrazol-3-yl-κ<i>N</i>)pyridine-<i>κN</i>-bis(2-(2,4-difluorophenyl)pyridinato-<i>κ</i> <sup>2</sup> <i>C</i>,<i>N</i>)iridium(III) sesquihydrate, C<sub>30</sub>H<sub>18</sub>F<sub>4</sub>IrN<sub>5</sub>·1.5[H<sub>2</sub>O]
Crystal structure of 2-(1<i>H</i>-pyrazol-3-yl-κ<i>N</i>)pyridine-<i>κN</i>-bis(2-(2,4-difluorophenyl)pyridinato-<i>κ</i> <sup>2</sup> <i>C</i>,<i>N</i>)iridium(III) sesquihydrate, C<sub>30</sub>H<sub>18</sub>F<sub>4</sub>IrN<sub>5</sub>·1.5[H<sub>2</sub>O] Open
C 30 H 18 F 4 IrN 5 ·1.5[H 2 O], tetragonal, I 4 1 / a (no. 88), a = 37.5562(5) Å, b = 37.5562(5) Å, c = 9.2031(2) Å, V = 12980.7(4) Å 3 , Z = 16, R gt ( F ) = 0.0312, wR ref ( F 2 ) = 0.1166, T = 300(2) K.
View article: CCDC 1831361: Experimental Crystal Structure Determination
CCDC 1831361: Experimental Crystal Structure Determination Open
View article: CCDC 2057970: Experimental Crystal Structure Determination
CCDC 2057970: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis of Cobalt Oxide on FTO by Hydrothermal Method for Photoelectrochemical Water Splitting Application
Synthesis of Cobalt Oxide on FTO by Hydrothermal Method for Photoelectrochemical Water Splitting Application Open
Cobalt oxide thin films were successfully grown directly on fluorine-doped tin oxide glass substrates through a simple, green, and low-cost hydrothermal method. An investigation into the physicochemical characteristics and photoelectrochem…
View article: Crystal structure of ethyl-2-(3-benzoylthioureido)propanoate, C<sub>13</sub>H<sub>16</sub>N<sub>2</sub>O<sub>3</sub>S
Crystal structure of ethyl-2-(3-benzoylthioureido)propanoate, C<sub>13</sub>H<sub>16</sub>N<sub>2</sub>O<sub>3</sub>S Open
C 13 H 16 N 2 O 3 S, triclinic, P 1 ‾ $P\bar{1}$ (no. 2), a = 8.1998(4) Å, b = 9.1320(4) Å, c = 10.7062(6) Å, α = 106.183(5)°, β = 111.506(5)°, γ = 97.589(4)°, V = 691.27(7) Å 3 , Z = 2, R gt ( F ) = 0.0346, wR ref ( F 2 ) = 0.0957, …
View article: Cobalt Sulfide as Photoelectrode of Photoelectrochemical Hydrogen Generation from Water
Cobalt Sulfide as Photoelectrode of Photoelectrochemical Hydrogen Generation from Water Open
This study aimed to synthesize and characterize cobalt sulfide deposited on FTO by hydrothermal method and investigate its photoelectrochemical (PEC) water splitting performance. Cobalt sulfide thin films were produced by annealing at two …
View article: CCDC 1985469: Experimental Crystal Structure Determination
CCDC 1985469: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1991706: Experimental Crystal Structure Determination
CCDC 1991706: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1991705: Experimental Crystal Structure Determination
CCDC 1991705: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1991707: Experimental Crystal Structure Determination
CCDC 1991707: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Insight into Positional Isomerism of N-(Benzo[d]thiazol-2-yl)-o/m/p-Nitrobenzamide: Crystal Structure, Hirshfeld Surface Analysis and Interaction Energy
Insight into Positional Isomerism of N-(Benzo[d]thiazol-2-yl)-o/m/p-Nitrobenzamide: Crystal Structure, Hirshfeld Surface Analysis and Interaction Energy Open
The functionalization of N-(benzo[d]thiazol-2-yl)benzamide with a nitro (NO2) substituent influences the solid-state arrangement, absorption and fluorescence properties of these compounds. Each of these compounds crystallised in a differen…
View article: Crystal structure of 1-[3-(trifluoromethyl)cinnamoyl]-3-(pyridin-2-yl-κ<i>N</i>)pyrazole-κ<sup>2</sup> <i>N</i>-bis(2-phenylpyridinato-k<sup>2</sup> <i>C</i>,<i>N</i>)iridium(III) hexafluorophosphate complex, [C<sub>40</sub>H<sub>28</sub>F<sub>3</sub>IrN<sub>5</sub>O]PF<sub>6</sub>
Crystal structure of 1-[3-(trifluoromethyl)cinnamoyl]-3-(pyridin-2-yl-κ<i>N</i>)pyrazole-κ<sup>2</sup> <i>N</i>-bis(2-phenylpyridinato-k<sup>2</sup> <i>C</i>,<i>N</i>)iridium(III) hexafluorophosphate complex, [C<sub>40</sub>H<sub>28</sub>F<sub>3</sub>IrN<sub>5</sub>O]PF<sub>6</sub> Open
[C 40 H 28 F 3 IrN 5 O]PF 6 , monoclinic, P 2 1 / c (no. 14), a = 20.2282(19) Å, b = 14.5095(11) Å, c = 12.6091(10) Å, β = 96.937(3)°, V = 3673.7(5) Å 3 , Z = 4, R gt (F) = 0.0498, wR ref (F 2 ) = 0.1250, T = 107(2) K.
View article: Density Functional Theory Study on the Electronic Properties of Doped-Cobalt Oxide (CoO)
Density Functional Theory Study on the Electronic Properties of Doped-Cobalt Oxide (CoO) Open
Cobalt oxide (CoO) has been widely studied for photocatalyst of water splitting and displaying a high-efficiency material. This paper reports a Density Functional Theory (DFT) study on the electronic properties of rock-salt CoO and analyze…
View article: Influence of Cerium on the Reduction Behaviour of Iron Oxide by Using Carbon Monoxide: TPR and Kinetic Studies
Influence of Cerium on the Reduction Behaviour of Iron Oxide by Using Carbon Monoxide: TPR and Kinetic Studies Open
Reduction of iron oxide is one of the most studied topics owing to the importance of iron/steel industry and also has been used as a precursor and active component in a number of important chemical processes. The interaction between iron o…
View article: Optimum Deposition Of Tungsten Oxide On Titania Nanotubular Arrays And Study The Photoactivity Of Nano-Composite Photoanode
Optimum Deposition Of Tungsten Oxide On Titania Nanotubular Arrays And Study The Photoactivity Of Nano-Composite Photoanode Open
This volume contains contributed articles of Track 1, Track 2 & Track 3, presented in the conference CEST-2018, organized by Faculty of Engineering Garaboulli, and Faculty of Engineering, Al-khoms, Elmergib University (Libya) on 25-27 Sept…
View article: Experimental and Theoretical Study of Cu2O Photoelectrode and Cu2O Doped with Ag, Co, Ni and Zn Metals for Water Splitting Application
Experimental and Theoretical Study of Cu2O Photoelectrode and Cu2O Doped with Ag, Co, Ni and Zn Metals for Water Splitting Application Open
View article: Synthesis, Structure and Spectroscopic Properties of Oxovanadium Tris(3,5-dimethylpyrazolyl)borate Aroylthiourea Complexes
Synthesis, Structure and Spectroscopic Properties of Oxovanadium Tris(3,5-dimethylpyrazolyl)borate Aroylthiourea Complexes Open
Aroylthiourea ligands, 1-aroyl-3-cyclohexyl-3-methylthiourea (HL 1 ), 1-(2-chloroaroyl)-3-cyclohexyl-3-methylthiourea (HL 2 ), 1-(3-chloroaroyl)-3-cyclohexyl-3-methylthiourea (HL 3 ) and 1-(4-chloroaroyl)-3-cyclohexyl-3-methylthiourea (HL …