Monique A. Van Der Veen
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View article: Capturing CO<sub>2</sub> under Dry and Humid Conditions: When Does the Parent MOF Outperform the MTV MOF?
Capturing CO<sub>2</sub> under Dry and Humid Conditions: When Does the Parent MOF Outperform the MTV MOF? Open
A key challenge in capturing CO2 from postcombustion gases is humidity due to competitive adsorption between CO2 and H2O. Multivariate (MTV) metal-organic frameworks (MOFs) have been considered a promising …
View article: On the Importance of Balancing the p<i>K</i><sub>a</sub> of the Additive in β‐Ketoenamine COF Synthesis
On the Importance of Balancing the p<i>K</i><sub>a</sub> of the Additive in β‐Ketoenamine COF Synthesis Open
Due to the irreversible tautomerization of imine linkages to their corresponding ketoenamines, β‐ketoenamine‐linked Covalent Organic Frameworks (COFs) are a stable type of COF that displays high surface areas. In the solvothermal synthesis…
View article: Amorphous-to-Crystalline Transformation: How Cluster Aggregation Drives the Multistep Nucleation of ZIF-8
Amorphous-to-Crystalline Transformation: How Cluster Aggregation Drives the Multistep Nucleation of ZIF-8 Open
Nucleation, the pivotal first step of crystallization, governs the essential characteristics of crystallization products, including size distribution, morphology, and polymorphism. While understanding this process is paramount to the desig…
View article: Advancements in Inkjet Printing of Metal- and Covalent-Organic Frameworks: Process Design and Ink Optimization
Advancements in Inkjet Printing of Metal- and Covalent-Organic Frameworks: Process Design and Ink Optimization Open
Metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) are highly versatile materials based on inorganic modes connected via organic linkers or purely via the connection of organic building blocks, respectively. This result…
View article: Long-Range and Coupled Rotor Dynamics in NO<sub>2</sub>-MIL-53(Al) by Classical Molecular Dynamics
Long-Range and Coupled Rotor Dynamics in NO<sub>2</sub>-MIL-53(Al) by Classical Molecular Dynamics Open
[Image: see text] By tuning the steric environment and free pore space in metal–organic frameworks, a large variety of rotor dynamics of the organic linkers can appear. Nitrofunctionalized MIL-53 is a terephthalate-linker-based MOF that sh…
View article: Development of a photonic crystal spectrometer for greenhouse gas measurements
Development of a photonic crystal spectrometer for greenhouse gas measurements Open
The need of atmospheric information with a higher spatial and temporal resolution drives the development of small satellites and satellite constellations to complement satellite flagship missions. Since optical systems are a main contribut…
View article: Combining Nickel- and Zinc-Porphyrin Sites via Covalent Organic Frameworks for Electrochemical CO<sub>2</sub> Reduction
Combining Nickel- and Zinc-Porphyrin Sites via Covalent Organic Frameworks for Electrochemical CO<sub>2</sub> Reduction Open
Covalent organic frameworks (COFs) are ideal platforms to spatially control the integration of multiple molecular motifs throughout a single nanoporous framework. Despite this design flexibility, COFs are typically synthesized using only t…
View article: Predicting and Probing the Local Temperature Rise Around Plasmonic Core–Shell Nanoparticles to Study Thermally Activated Processes
Predicting and Probing the Local Temperature Rise Around Plasmonic Core–Shell Nanoparticles to Study Thermally Activated Processes Open
Ultrafast spectroscopy can be used to study dynamic processes on femtosecond to nanosecond timescales, but is typically used for photoinduced processes. Several materials can induce ultrafast temperature rises upon absorption of femtosecon…
View article: Elucidating Structural Disorder in Ultra‐Thin Bi‐Rich Bismuth Oxyhalide Photocatalysts
Elucidating Structural Disorder in Ultra‐Thin Bi‐Rich Bismuth Oxyhalide Photocatalysts Open
Advancing the field of photocatalysis requires the elucidation of structural properties that underpin the photocatalytic properties of promising materials. The focus of the present study is layered, Bi‐rich bismuth oxyhalides, which are wi…
View article: Modelling and advanced characterization of framework materials
Modelling and advanced characterization of framework materials Open
View article: Promoting Photocatalytic Activity of NH<sub>2</sub>-MIL-125(Ti) for H<sub>2</sub> Evolution Reaction through Creation of Ti<sup>III</sup>- and Co<sup>I</sup>-Based Proton Reduction Sites
Promoting Photocatalytic Activity of NH<sub>2</sub>-MIL-125(Ti) for H<sub>2</sub> Evolution Reaction through Creation of Ti<sup>III</sup>- and Co<sup>I</sup>-Based Proton Reduction Sites Open
Titanium-based metal-organic framework, NH2-MIL-125(Ti), has been widely investigated for photocatalytic applications but has low activity in the hydrogen evolution reaction (HER). In this work, we show a one-step low-cost postmodification…
View article: CCDC 2142131: Experimental Crystal Structure Determination
CCDC 2142131: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Competitive and Cooperative CO<sub>2</sub>–H<sub>2</sub>O Adsorption through Humidity Control in a Polyimide Covalent Organic Framework
Competitive and Cooperative CO<sub>2</sub>–H<sub>2</sub>O Adsorption through Humidity Control in a Polyimide Covalent Organic Framework Open
In order to capture and separate CO2 from the air or flue gas streams through nanoporous adsorbents, the influence of the humidity in these streams has to be taken into account as it hampers the capture process in two main ways:…
View article: Confined Water Cluster Formation in Water Harvesting by Metal–Organic Frameworks: CAU‐10‐H versus CAU‐10‐CH<sub>3</sub>
Confined Water Cluster Formation in Water Harvesting by Metal–Organic Frameworks: CAU‐10‐H versus CAU‐10‐CH<sub>3</sub> Open
Several metal–organic frameworks (MOFs) excel in harvesting water from the air or as heat pumps as they show a steep increase in water uptake at 10–30 % relative humidity (RH%). A precise understanding of which structural characteristics g…
View article: Carbon monoxide separation: past, present and future
Carbon monoxide separation: past, present and future Open
This review discusses the developments in CO separation techniques in the last few decades and the gaps in knowledge it leaves, as well as sources of CO, both traditional and emerging, which would benefit from improved CO separation.
View article: Structure–Property Relationship of Piezoelectric Properties in Zeolitic Imidazolate Frameworks: A Computational Study
Structure–Property Relationship of Piezoelectric Properties in Zeolitic Imidazolate Frameworks: A Computational Study Open
Metal-organic frameworks (MOFs) are a class of nanoporous crystalline materials with very high structural tunability. They possess a very low dielectric permittivity εr due to their porosity and hence are favorable for piezoelec…
View article: Impact of flow-induced disturbances during synthesis on the photophysical properties of naphthalene diimide covalent organic frameworks
Impact of flow-induced disturbances during synthesis on the photophysical properties of naphthalene diimide covalent organic frameworks Open
View article: Molecular-level understanding of highly selective heavy rare earth element uptake by organophosphorus modified MIL-101(Cr)
Molecular-level understanding of highly selective heavy rare earth element uptake by organophosphorus modified MIL-101(Cr) Open
View article: Emergence of Coupled Rotor Dynamics in Metal–Organic Frameworks via Tuned Steric Interactions
Emergence of Coupled Rotor Dynamics in Metal–Organic Frameworks via Tuned Steric Interactions Open
The organic components in metal-organic frameworks (MOFs) are unique: they are embedded in a crystalline lattice, yet, as they are separated from each other by tunable free space, a large variety of dynamic behavior can emerge. These rotat…
View article: How Reproducible Are Surface Areas Calculated from the BET Equation?
How Reproducible Are Surface Areas Calculated from the BET Equation? Open
Porosity and surface area analysis play a prominent role in modern materials science, where 123 their determination spans the fields of natural sciences, engineering, geology and medical 124 research. At the heart of this sits the Brunauer…
View article: Synthesis and Structure–Property Relationships of Polyimide Covalent Organic Frameworks for Carbon Dioxide Capture and (Aqueous) Sodium-Ion Batteries
Synthesis and Structure–Property Relationships of Polyimide Covalent Organic Frameworks for Carbon Dioxide Capture and (Aqueous) Sodium-Ion Batteries Open
Covalent organic frameworks (COFs) are an emerging material family having several potential applications. Their porous framework and redox-active centers enable gas/ion adsorption, allowing them to function as safe, cheap, and tunable elec…
View article: Nonlinear optical probes of nucleation and crystal growth: recent progress and future prospects
Nonlinear optical probes of nucleation and crystal growth: recent progress and future prospects Open
Nonlinear optical techniques are emerging as powerful in-situ probes of crystallization processes due to their inherent sensitivity to crystal structure and morphology.
View article: Pillared cobalt metal–organic frameworks act as chromatic polarizers
Pillared cobalt metal–organic frameworks act as chromatic polarizers Open
The anisotropic alignment of chromophores in a cobalt-based metal–organic framework produces a dichromatic dichroic effect, showing a range of colors from blue to yellow depending on the orientation of polarized light relative to the cryst…
View article: Selective recovery and separation of rare earth elements by organophosphorus modified MIL-101(Cr)
Selective recovery and separation of rare earth elements by organophosphorus modified MIL-101(Cr) Open
View article: Emergence of Cooperative Rotor Dynamics in Metal–organic Frameworks via Tuned Steric Interactions
Emergence of Cooperative Rotor Dynamics in Metal–organic Frameworks via Tuned Steric Interactions Open
The organic components in metal-organic frameworks (MOFs) enjoy a unique situation: they are embedded in a crystalline lattice, yet, as they are separated from each other by tunable free space, a large variety of dynamic behavior can emerg…
View article: Emergence of Cooperative Rotor Dynamics in Metal–organic Frameworks via Tuned Steric Interactions
Emergence of Cooperative Rotor Dynamics in Metal–organic Frameworks via Tuned Steric Interactions Open
The organic components in metal-organic frameworks (MOFs) enjoy a unique situation: they are embedded in a crystalline lattice, yet, as they are separated from each other by tunable free space, a large variety of dynamic behavior can emerg…
View article: Emergence of Cooperative Rotor Dynamics in Metal–organic Frameworks via Tuned Steric Interactions
Emergence of Cooperative Rotor Dynamics in Metal–organic Frameworks via Tuned Steric Interactions Open
The organic components in metal-organic frameworks (MOFs) enjoy a unique situation: they are embedded in a crystalline lattice, yet, as they are separated from each other by tunable free space, a large variety of dynamic behavior can emerg…
View article: Overcoming Crystallinity Limitations of Aluminium Metal‐Organic Frameworks by Oxalic Acid Modulated Synthesis
Overcoming Crystallinity Limitations of Aluminium Metal‐Organic Frameworks by Oxalic Acid Modulated Synthesis Open
A modulated synthesis approach based on the chelating properties of oxalic acid (H 2 C 2 O 4 ) is presented as a robust and versatile method to achieve highly crystalline Al‐based metal‐organic frameworks. A comparative study on this metho…
View article: Overcoming Crystallinity Limitations of Aluminium Metal–Organic Frameworks by Oxalic Acid Modulated Synthesis
Overcoming Crystallinity Limitations of Aluminium Metal–Organic Frameworks by Oxalic Acid Modulated Synthesis Open
A modulated synthesis approach based on the chelating properties of oxalic acid (H 2 C 2 O 4 ) is presented as a robust and versatile method to achieve highly crystalline Al-based metal–organic frameworks (MOFs). A comparative study on thi…
View article: Overcoming Crystallinity Limitations of Aluminium Metal–Organic Frameworks by Oxalic Acid Modulated Synthesis
Overcoming Crystallinity Limitations of Aluminium Metal–Organic Frameworks by Oxalic Acid Modulated Synthesis Open
A modulated synthesis approach based on the chelating properties of oxalic acid (H2C2O4) is presented as a robust and versatile method to achieve highly crystalline Al-based metal–organic frameworks (MOFs).…