Moritz Bernhardt
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View article: Orientation-Driven Large Magnetic Hysteresis of Er(III) Cyclooctatetraenide-Based Single-Ion Magnets Adsorbed on Ag(100)
Orientation-Driven Large Magnetic Hysteresis of Er(III) Cyclooctatetraenide-Based Single-Ion Magnets Adsorbed on Ag(100) Open
The molecular self-assembly and the magnetic properties of two cyclooctatetraenide (COT) - based single-ion magnets (SIM) adsorbed on Ag(100) in the sub-monolayer range are reported. Our study combines scanning-tunneling microscopy, X-ray …
View article: Orientation‐Driven Large Magnetic Hysteresis of Er(III) Cyclooctatetraenide‐Based Single‐Ion Magnets Adsorbed on Ag(100)
Orientation‐Driven Large Magnetic Hysteresis of Er(III) Cyclooctatetraenide‐Based Single‐Ion Magnets Adsorbed on Ag(100) Open
The molecular self‐assembly and the magnetic properties of two cyclooctatetraenide (COT)‐based single‐ion magnets (SIM) adsorbed on Ag(100) in the sub‐monolayer (ML) range are reported. Our study combines scanning‐tunneling microscopy, X‐r…
View article: Solid-state 183W NMR spectroscopy as a high-resolution probe of polyoxotungstate structures and dynamics
Solid-state 183W NMR spectroscopy as a high-resolution probe of polyoxotungstate structures and dynamics Open
Polyoxometalates such as ammonium paratungstate (APT) are an important class of metal oxides with applications for catalysis, (opto)electronics, and functional materials. Structural analyses of solid polyoxometalates mostly rely on X-ray o…
View article: Identification of Favorable Silica Surface Sites for Single‐Molecule Magnets
Identification of Favorable Silica Surface Sites for Single‐Molecule Magnets Open
Industrial data storage application based on single‐molecule magnets (SMMs) necessitates not only strong magnetic remanence at high temperatures but also requires the implementation of SMMs into a solid material to increase their durabilit…
View article: Tailored Lewis Acid Sites for High-Temperature Supported Single-Molecule Magnetism
Tailored Lewis Acid Sites for High-Temperature Supported Single-Molecule Magnetism Open
Generating or even retaining slow magnetic relaxation in surface immobilized single-molecule magnets (SMMs) from promising molecular precursors remains a great challenge. Illustrative examples are organolanthanide compounds that show promi…
View article: Tailored Lewis Acid Sites for High-Temperature Supported Single-Molecule Magnetism
Tailored Lewis Acid Sites for High-Temperature Supported Single-Molecule Magnetism Open
Generating or even retaining slow magnetic relaxation in surface immobilized single-molecule magnets (SMMs) from promising molecular precursors remains a great challenge. Illustrative examples are organolanthanide compounds that show promi…
View article: Tailored Lewis Acid Sites for High-Temperature Supported Single-Molecule Magnetism
Tailored Lewis Acid Sites for High-Temperature Supported Single-Molecule Magnetism Open
Generating or even retaining slow magnetic relaxation in surface immobilized single-molecule magnets (SMMs) from promising molecular precursors remains a great challenge. Illustrative examples are organolanthanide compounds that show promi…
View article: CCDC 2170525: Experimental Crystal Structure Determination
CCDC 2170525: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2170517: Experimental Crystal Structure Determination
CCDC 2170517: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2170516: Experimental Crystal Structure Determination
CCDC 2170516: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2170514: Experimental Crystal Structure Determination
CCDC 2170514: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2170518: Experimental Crystal Structure Determination
CCDC 2170518: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2170515: Experimental Crystal Structure Determination
CCDC 2170515: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Cyclooctatetraenide-Based Single-Ion Magnets Featuring Bulky Cyclopentadienyl Ligand
Cyclooctatetraenide-Based Single-Ion Magnets Featuring Bulky Cyclopentadienyl Ligand Open
We report a family of organometallic rare-earth complexes with the general formula (COT)M(Cpttt) (where (COT)2– = cyclooctatetraenide, (Cpttt)– = 1,2,4-tri(tert-butyl)cyclopentadienide, M = Y(III), Nd(III), Dy(III) and Er(III)). Similarly …
View article: Olefin-Surface Interactions: A Key Activity Parameter in Silica-Supported Olefin Metathesis Catalysts
Olefin-Surface Interactions: A Key Activity Parameter in Silica-Supported Olefin Metathesis Catalysts Open
Molecularly defined and classical heterogeneous Mo-based metathesis catalysts are shown to display distinct and unexpected reactivity patterns for the metathesis of long-chain α-olefins at low temperatures (<100 °C). Catalysts based on sup…
View article: Olefin-surface interactions: a key activity parameter in silica-supported olefin metathesis catalysts
Olefin-surface interactions: a key activity parameter in silica-supported olefin metathesis catalysts Open
Molecularly defined and classical heterogenous Mo-based metathesis catalysts are shown to display dis-tinct and unexpected reactivity patterns for the metathesis of long-chain α-olefins at low temperatures (< 100 °C). Namely, catalysts bas…
View article: Olefin-surface interactions: a key activity parameter in silica-supported olefin metathesis catalysts
Olefin-surface interactions: a key activity parameter in silica-supported olefin metathesis catalysts Open
Molecularly defined and classical heterogenous Mo-based metathesis catalysts are shown to display dis-tinct and unexpected reactivity patterns for the metathesis of long-chain α-olefins at low temperatures (< 100 °C). Namely, catalysts bas…
View article: Cyclooctatetraenide-based single-ion magnets featuring bulky cyclopentadienyl ligand
Cyclooctatetraenide-based single-ion magnets featuring bulky cyclopentadienyl ligand Open
Application of steric control principles allows for simplification of the magnetic behavior of an iconic single-ion magnet architecture as well as the preparation of its previously inaccessible representative.
View article: Olefin-surface interactions modulate the activity of silica-supported Mo-based olefin metathesis catalysts
Olefin-surface interactions modulate the activity of silica-supported Mo-based olefin metathesis catalysts Open
Molecularly defined and classical heterogenous Mo-based metathesis catalysts are shown to display distinct and unexpected reactivity patterns for the metathesis of long-chain α-olefins at low temperatures (< 100 °C). Namely, catalysts base…
View article: Olefin-surface interactions modulate the activity of silica-supported Mo-based olefin metathesis catalysts
Olefin-surface interactions modulate the activity of silica-supported Mo-based olefin metathesis catalysts Open
Molecularly defined and classical heterogenous Mo-based metathesis catalysts are shown to display distinct and unexpected reactivity patterns for the metathesis of long-chain α-olefins at low temperatures (< 100 °C). Namely, catalysts base…
View article: CCDC 1911667: Experimental Crystal Structure Determination
CCDC 1911667: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1911668: Experimental Crystal Structure Determination
CCDC 1911668: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1832814: Experimental Crystal Structure Determination
CCDC 1832814: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1832816: Experimental Crystal Structure Determination
CCDC 1832816: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1832815: Experimental Crystal Structure Determination
CCDC 1832815: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1832813: Experimental Crystal Structure Determination
CCDC 1832813: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …