Nicolaas P. van Leest
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View article: CCDC 2277308: Experimental Crystal Structure Determination
CCDC 2277308: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2277307: Experimental Crystal Structure Determination
CCDC 2277307: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2277309: Experimental Crystal Structure Determination
CCDC 2277309: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2277310: Experimental Crystal Structure Determination
CCDC 2277310: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2300376: Experimental Crystal Structure Determination
CCDC 2300376: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: PhenTAA: A Redox-Active N<sub>4</sub>-Macrocyclic Ligand Featuring Donor and Acceptor Moieties
PhenTAA: A Redox-Active N<sub>4</sub>-Macrocyclic Ligand Featuring Donor and Acceptor Moieties Open
Here, we present the development and characterization of the novel PhenTAA macrocycle as well as a series of [Ni(R2PhenTAA)]n complexes featuring two sites for ligand-centered redox-activity. These differ in the subst…
View article: CCDC 2190239: Experimental Crystal Structure Determination
CCDC 2190239: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2190237: Experimental Crystal Structure Determination
CCDC 2190237: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2190238: Experimental Crystal Structure Determination
CCDC 2190238: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Styrene aziridination with [CoIII(TAMLred)]– in water: Understanding and preventing epoxidation via nitrene hydrolysis
Styrene aziridination with [CoIII(TAMLred)]– in water: Understanding and preventing epoxidation via nitrene hydrolysis Open
View article: CCDC 1822348: Experimental Crystal Structure Determination
CCDC 1822348: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Styrene Aziridination with [Co^III(TAML^red)]– in Water; Understanding and Preventing Epoxidation via Nitrene Hydrolysis
Styrene Aziridination with [Co^III(TAML^red)]– in Water; Understanding and Preventing Epoxidation via Nitrene Hydrolysis Open
Enabling (radical-type) nitrene transfer reactions in water can open up a wide range of (novel) applications, such as the in vivo synthesis of medicines. However, these reactions typically suffer from oxygen-containing side-product formati…
View article: Dry reforming of methane over single-atom Rh/Al<sub>2</sub>O<sub>3</sub> catalysts prepared by exsolution
Dry reforming of methane over single-atom Rh/Al<sub>2</sub>O<sub>3</sub> catalysts prepared by exsolution Open
Single-atom catalysts often show exceptionally high performance per metal loading.
View article: Enhancement of London Dispersion in Frustrated Lewis Pairs: Towards a Crystalline Encounter Complex
Enhancement of London Dispersion in Frustrated Lewis Pairs: Towards a Crystalline Encounter Complex Open
The encounter complex, i.e., the pre-organized assembly consisting of a Lewis acid and a Lewis base, is a fundamental concept in frustrated Lewis pair (FLP) chemistry. However, this donor–acceptor complex is challenging to study due to its…
View article: The Role of Vacancies in a Ti<sub>2</sub>CT<sub>x</sub> MXene‐Derived Catalyst for Butane Oxidative Dehydrogenation
The Role of Vacancies in a Ti<sub>2</sub>CT<sub>x</sub> MXene‐Derived Catalyst for Butane Oxidative Dehydrogenation Open
MXenes are a new family of 2D carbides or nitrides that have attracted attention due to their layered structure, tunable surface groups and high electrical conductivity. Here, we report for the first time that the Ti 2 CT x MXene catalyses…
View article: Radical-Type Aziridination with [Co^III(TAML^red)]– in Water; Understanding and Preventing Epoxidation via Nitrene Hydrolysis
Radical-Type Aziridination with [Co^III(TAML^red)]– in Water; Understanding and Preventing Epoxidation via Nitrene Hydrolysis Open
Base-metal catalyzed nitrene transfer reactions in water are challenging, but have the potential to broaden the range of applications. Typically, these reactions suffer from the formation of oxygen containing side-products, of which the or…
View article: CCDC 2110891: Experimental Crystal Structure Determination
CCDC 2110891: Experimental Crystal Structure Determination Open
View article: CCDC 2110888: Experimental Crystal Structure Determination
CCDC 2110888: Experimental Crystal Structure Determination Open
View article: CCDC 2110889: Experimental Crystal Structure Determination
CCDC 2110889: Experimental Crystal Structure Determination Open
View article: CCDC 2110890: Experimental Crystal Structure Determination
CCDC 2110890: Experimental Crystal Structure Determination Open
View article: Combining metal–metal cooperativity, metal–ligand cooperativity and chemical non-innocence in diiron carbonyl complexes
Combining metal–metal cooperativity, metal–ligand cooperativity and chemical non-innocence in diiron carbonyl complexes Open
The PNNP expanded pincer ligand can bind two iron centers in close proximity and display heterolytic and homolytic metal–ligand cooperativity.
View article: Combining Metal-Metal Cooperativity, Metal-Ligand Cooperativity and Chemical Non-Innocence in Diiron Carbonyl Complexes
Combining Metal-Metal Cooperativity, Metal-Ligand Cooperativity and Chemical Non-Innocence in Diiron Carbonyl Complexes Open
Several metalloenzymes, including [FeFe]-hydrogenase, employ cofactors wherein multiple metal atoms work together with surrounding ligands that mediate heterolytic and concerted proton-electron transfer (CPET) bond activation steps. Herein…
View article: Combining Metal-Metal Cooperativity, Metal-Ligand Cooperativity and Chemical Non-Innocence in Diiron Carbonyl Complexes
Combining Metal-Metal Cooperativity, Metal-Ligand Cooperativity and Chemical Non-Innocence in Diiron Carbonyl Complexes Open
Several metalloenzymes, including [FeFe]-hydrogenase, employ cofactors wherein multiple metal atoms work together with surrounding ligands that mediate heterolytic and concerted proton-electron transfer (CPET) bond activation steps. Herein…
View article: CCDC 2101036: Experimental Crystal Structure Determination
CCDC 2101036: Experimental Crystal Structure Determination Open
View article: CCDC 2101037: Experimental Crystal Structure Determination
CCDC 2101037: Experimental Crystal Structure Determination Open
View article: CCDC 2101042: Experimental Crystal Structure Determination
CCDC 2101042: Experimental Crystal Structure Determination Open
View article: CCDC 2101044: Experimental Crystal Structure Determination
CCDC 2101044: Experimental Crystal Structure Determination Open
View article: CCDC 2101039: Experimental Crystal Structure Determination
CCDC 2101039: Experimental Crystal Structure Determination Open
View article: CCDC 2101043: Experimental Crystal Structure Determination
CCDC 2101043: Experimental Crystal Structure Determination Open
View article: CCDC 2101038: Experimental Crystal Structure Determination
CCDC 2101038: Experimental Crystal Structure Determination Open