Explanipedia

Sequential Infiltration Synthesis of Cadmium Sulfide Discrete Atom Clusters Open

Nuwanthaka P. Jayaweera, Shana Havenridge, Ashley R. Bielinski, Kihoon Kim, Niklas B. Thompson , et al. · 2025

Exposure of soft material templates to alternating volatile chemical precursors can produce inorganic deposition within the permeable template (e.g. a polymer thin film) in a process akin to atomic layer deposition (ALD). While such sequen…

Sequential Infiltration Synthesis of Cadmium Sulfide Discrete Atom Clusters Open

Nuwanthaka P. Jayaweera, Shana Havenridge, Ashley R. Bielinski, Kihoon Kim, Niklas B. Thompson , et al. · 2025

Exposure of soft material templates to alternating volatile chemical precursors can produce inorganic deposition within the permeable template (e.g. a polymer thin film) in a process akin to atomic layer deposition (ALD). While such sequen…

Correction to “Terminal Hydride Complex of High-Spin Mn” Open

Alex Drena, Addison Fraker, Niklas B. Thompson, Peter E. Doan, Brian M. Hoffman , et al. · 2024

Terminal Hydride Complex of High-Spin Mn Open

Alex Drena, Addison Fraker, Niklas B. Thompson, Peter E. Doan, Brian M. Hoffman , et al. · 2024

The iron-molybdenum cofactor of nitrogenase (FeMoco) catalyzes fixation of N₂ via Fe hydride intermediates. Our understanding of these species has relied heavily on the characterization of well-defined 3d metal hydride complexes…

Toward a quantitative description of solvation structure: a framework for differential solution scattering measurements Open

Niklas B. Thompson, Karen L. Mulfort, David M. Tiede · 2024

Appreciating that the role of the solute–solvent and other outer-sphere interactions is essential for understanding chemistry and chemical dynamics in solution, experimental approaches are needed to address the structural consequences of t…

CCDC 2304656: Experimental Crystal Structure Determination Open

Li Gu, Addison Fraker, Niklas B. Thompson, Alex McSkimming · 2024

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 2304659: Experimental Crystal Structure Determination Open

Li Gu, Addison Fraker, Niklas B. Thompson, Alex McSkimming · 2024

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 2304658: Experimental Crystal Structure Determination Open

Li Gu, Addison Fraker, Niklas B. Thompson, Alex McSkimming · 2024

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

Four-Coordinate Co(III) Imide with an Unusually Tilted Terminal Imido Ligand Open

Li Gu, Addison Fraker, Niklas B. Thompson, Alex McSkimming · 2024

We report herein the synthesis and characterization of a terminal Co(III) imido complex supported by an intermediate field N,N,C heteroscorpionate. This chemistry is enabled through the development of an additional member of this ligand ty…

Orientational analysis of atomic pair correlations in nanocrystalline indium oxide thin films Open

Justin M. Hoffman, Niklas B. Thompson, Olaf J. Borkiewicz, Xiang He, Samuel H. Amsterdam , et al. · 2023

The application of grazing-incidence total X-ray scattering (GITXS) for pair distribution function (PDF) analysis using >50 keV X-rays from synchrotron light sources has created new opportunities for structural characterization of supporte…

Denoising total scattering data using Compressed Sensing Open

James Weng, Niklas B. Thompson, Christopher Folmar, James D. Martin, Christina Hoffman · 2023

To obtain the best resolution for any measurement there is an ever-present challenge to achieve maximal differentiation between signal and noise over as fine of sampling dimensions as possible. In diffraction science these issues are parti…

Facile and dynamic cleavage of every iron–sulfide bond in cuboidal iron–sulfur clusters Open

Niklas B. Thompson, Gil Namkoong, Brighton A. Skeel, Daniel L. M. Suess · 2023

Nature employs weak-field metalloclusters to support a wide range of biological processes. The most ubiquitous metalloclusters are the cuboidal Fe–S clusters, which are comprised of Fe sites with locally high-spin electronic configurations…

CCDC 2154157: Experimental Crystal Structure Determination Open

Alex McSkimming, Niklas B. Thompson · 2022

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 2154154: Experimental Crystal Structure Determination Open

Alex McSkimming, Niklas B. Thompson · 2022

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 2154155: Experimental Crystal Structure Determination Open

Alex McSkimming, Niklas B. Thompson · 2022

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 2154156: Experimental Crystal Structure Determination Open

Alex McSkimming, Niklas B. Thompson · 2022

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

Four-Coordinate Fe N2 and Imido Complexes Supported by a Hemilabile NNC Heteroscorpionate Ligand Open

Alex McSkimming, Niklas B. Thompson · 2022

Inspired by mechanistic proposals for N₂ reduction at the nitrogenase FeMo cofactor, we report herein a new, strongly σ-donating heteroscorpionate ligand featuring two weak-field pyrazoles and an alkyl donor. This ligand support…

CCDC 2152882: Experimental Crystal Structure Determination Open

Alexandra C. Brown, Niklas B. Thompson, Daniel L. M. Suess · 2022

Evidence for Low-Valent Electronic Configurations in Iron–Sulfur Clusters Open

Alexandra C. Brown, Niklas B. Thompson, Daniel L. M. Suess · 2022

Although biological iron-sulfur (Fe-S) clusters perform some of the most difficult redox reactions in nature, they are thought to be composed exclusively of Fe²⁺ and Fe³⁺ ions, as well as mixed-valent pairs with avera…

CCDC 2152881: Experimental Crystal Structure Determination Open

Alexandra C. Brown, Niklas B. Thompson, Daniel L. M. Suess · 2022

Evidence for Low-valent Electronic Configurations in Iron–Sulfur Clusters Open

Alexandra C. Brown, Niklas B. Thompson, Daniel L. M. Suess · 2022

Although biological iron-sulfur (Fe–S) clusters perform some of the most difficult redox reactions in Nature, they are thought to be composed exclusively of Fe2+ and Fe3+ ions, as well as mixed-valent pairs with average oxidation states of…

CCDC 2009193: Experimental Crystal Structure Determination Open

Alex McSkimming, Arun Sridharan, Niklas B. Thompson, Péter Müller, Daniel L. M. Suess · 2020

CCDC 2009194: Experimental Crystal Structure Determination Open

Alex McSkimming, Arun Sridharan, Niklas B. Thompson, Péter Müller, Daniel L. M. Suess · 2020

CCDC 2009192: Experimental Crystal Structure Determination Open

Alex McSkimming, Arun Sridharan, Niklas B. Thompson, Péter Müller, Daniel L. M. Suess · 2020

CCDC 2009195: Experimental Crystal Structure Determination Open

Alex McSkimming, Arun Sridharan, Niklas B. Thompson, Péter Müller, Daniel L. M. Suess · 2020

An [Fe4S4]3+–Alkyl Cluster Stabilized by an Expanded Scorpionate Ligand Open

Alex McSkimming, Arun Sridharan, Niklas B. Thompson, Péter Müller, Daniel L. M. Suess · 2020

Alkyl-ligated iron-sulfur clusters in the [Fe₄S₄]³⁺ charge state have been proposed as short-lived intermediates in a number of enzymatic reactions. To better understand the properties of these intermediate…

CCDC 1968329: Experimental Crystal Structure Determination Open

Laura A. Essex, Alex McSkimming, Niklas B. Thompson, Margaret L. Kelty, Ethan A. Hill , et al. · 2020

CCDC 1968328: Experimental Crystal Structure Determination Open

Laura A. Essex, Alex McSkimming, Niklas B. Thompson, Margaret L. Kelty, Ethan A. Hill , et al. · 2020

CCDC 1968327: Experimental Crystal Structure Determination Open

Laura A. Essex, Alex McSkimming, Niklas B. Thompson, Margaret L. Kelty, Ethan A. Hill , et al. · 2020

CCDC 1968325: Experimental Crystal Structure Determination Open

Laura A. Essex, Alex McSkimming, Niklas B. Thompson, Margaret L. Kelty, Ethan A. Hill , et al. · 2020

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