Noel Israel
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View article: Controlling Magnetic Anisotropy of Endohedral Lanthanide Ions by Carbene Addition: Paramagnetic NMR, Lanthanide Luminescence, and Single-Molecule Magnetism in Adamantylidene Adducts of MSc<sub>2</sub>N@C<sub>80</sub> (M = Nd, Dy)
Controlling Magnetic Anisotropy of Endohedral Lanthanide Ions by Carbene Addition: Paramagnetic NMR, Lanthanide Luminescence, and Single-Molecule Magnetism in Adamantylidene Adducts of MSc<sub>2</sub>N@C<sub>80</sub> (M = Nd, Dy) Open
Metallofullerenes with endohedral lanthanides have emerged as a versatile class of single-molecule magnets owing to strong single-ion magnetic anisotropy, which can be realized in the interior of the fullerene cage. Since exohedral chemica…
View article: Rational Construction of Layered Two-Dimensional Conjugated Metal–Organic Frameworks with Room-Temperature Quantum Coherence
Rational Construction of Layered Two-Dimensional Conjugated Metal–Organic Frameworks with Room-Temperature Quantum Coherence Open
Two-dimensional conjugated metal-organic frameworks (2D c-MOFs) have emerged as an intriguing class of quantum materials due to their high crystallinity, persistent spin centers, and tunable structures and topologies. However, it remains u…
View article: A persistent concealed non-Kekulé nanographene: synthesis and <i>in situ</i> characterization
A persistent concealed non-Kekulé nanographene: synthesis and <i>in situ</i> characterization Open
A persistent concealed non-Kekulé nanographene featuring two phenalene units fused in a cis configuration to a perylene core was successfully synthesized in solution and characterized.
View article: Thirty Years of Hide-and-Seek: Capturing Abundant but Elusive M<sup>III</sup>@<i>C</i><sub>3<i>v</i></sub>(8)-C<sub>82</sub> Isomer, and the Study of Magnetic Anisotropy Induced in Dy<sup>3+</sup> Ion by the Fullerene π-Ligand
Thirty Years of Hide-and-Seek: Capturing Abundant but Elusive M<sup>III</sup>@<i>C</i><sub>3<i>v</i></sub>(8)-C<sub>82</sub> Isomer, and the Study of Magnetic Anisotropy Induced in Dy<sup>3+</sup> Ion by the Fullerene π-Ligand Open
Our knowledge about endohedral metallofullerenes (EMFs) is restricted to the structures with sufficient kinetic stability to be extracted from the arc-discharge soot and processed by chromatographic and structural techniques. For the most …
View article: Corrosion behavior of an oxide nanotube-coated β-type Ti-45Nb implant alloy in a simulated inflammatory solution
Corrosion behavior of an oxide nanotube-coated β-type Ti-45Nb implant alloy in a simulated inflammatory solution Open
Oxide nanotube (ONT) layers were anodically grown on β-type Ti-45Nb and crystallized at 450°C to anatase (Ti,Nb)O2. A corrosion analysis in normal and inflammatory phosphate buffered saline (PBS) comprised electrochemical polarization stud…
View article: Sensitivity of Offline and Inline Indicators for Fiber Stretching in Continuous Polyacrylonitrile Stabilization
Sensitivity of Offline and Inline Indicators for Fiber Stretching in Continuous Polyacrylonitrile Stabilization Open
In carbon fiber (CF) production, the stabilization process step is the most energy- and time-consuming step in comparison with carbonization and graphitization. To develop optimization routes for energy and productivity, the stabilization …
View article: CCDC 2256975: Experimental Crystal Structure Determination
CCDC 2256975: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2256978: Experimental Crystal Structure Determination
CCDC 2256978: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2256977: Experimental Crystal Structure Determination
CCDC 2256977: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2256976: Experimental Crystal Structure Determination
CCDC 2256976: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Dimerisierung eines reaktiven Azaacen Diradikals: Synthese eines kovalenten Azaacen‐Käfigs
Dimerisierung eines reaktiven Azaacen Diradikals: Synthese eines kovalenten Azaacen‐Käfigs Open
Zwei Serien regioisomerer dicyanomethylen‐substituierter Dithienodiazatetracenen mit formalen para ‐ oder ortho ‐Chinodimethan‐Untereinheiten wurden synthetisiert und charakterisiert. Während die para ‐Isomere ( p ‐n, Diradikalindex y 0 =0…
View article: Dimerization of a Reactive Azaacene Diradical: Synthesis of a Covalent Azaacene Cage
Dimerization of a Reactive Azaacene Diradical: Synthesis of a Covalent Azaacene Cage Open
Two series of regioisomeric dicyanomethylene substituted dithienodiazatetracenes with formal para ‐ or ortho ‐quinodimethane subunits were synthesized and characterized. Whereas the para ‐isomers ( p ‐n, diradical index y 0 =0.01) are stab…
View article: CCDC 2111792: Experimental Crystal Structure Determination
CCDC 2111792: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2111791: Experimental Crystal Structure Determination
CCDC 2111791: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2111790: Experimental Crystal Structure Determination
CCDC 2111790: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2158731: Experimental Crystal Structure Determination
CCDC 2158731: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2158730: Experimental Crystal Structure Determination
CCDC 2158730: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2158732: Experimental Crystal Structure Determination
CCDC 2158732: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Electronic Coupling in 1,2,3-Triazole Bridged Ferrocenes and Its Impact on Reactive Oxygen Species Generation and Deleterious Activity in Cancer Cells
Electronic Coupling in 1,2,3-Triazole Bridged Ferrocenes and Its Impact on Reactive Oxygen Species Generation and Deleterious Activity in Cancer Cells Open
Mixed-valence (MV) binuclear ferrocenyl compounds have long been studied as models for testing theories of electron transfer and in attempts to design molecular-scale electronic devices (e.g., molecular wires). In contrary to that, …
View article: Benzo‐Extended Cyclohepta[<i>def</i>]fluorene Derivatives with Very Low‐Lying Triplet States
Benzo‐Extended Cyclohepta[<i>def</i>]fluorene Derivatives with Very Low‐Lying Triplet States Open
Open‐shell non‐alternant polycyclic hydrocarbons (PHs) are attracting increasing attention due to their promising applications in organic spintronics and quantum computing. Herein we report the synthesis of three cyclohepta[ def ]fluorene‐…