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View article: Selective H/D Exchange in E–H (E = Si, Ge, Sn) Bonds Catalyzed by 1,2,3-Triazolylidene-Stabilized Nickel Nanoparticles
Selective H/D Exchange in E–H (E = Si, Ge, Sn) Bonds Catalyzed by 1,2,3-Triazolylidene-Stabilized Nickel Nanoparticles Open
Nickel nanoparticles (Ni·MIC) stabilized with mesoionic 1,2,3-triazolylidene (MIC) ligands were prepared via decomposition of the [Ni(COD)2] (COD = 1,5-cyclooctadiene) complex with H2 (3 bar) in the presence of 0.2 or…
View article: Bimetallic Ru/Co nanoparticles stabilized by N-heterocyclic carbenes as catalysts for H/D exchange in N-heterocycles with deuterium gas
Bimetallic Ru/Co nanoparticles stabilized by N-heterocyclic carbenes as catalysts for H/D exchange in N-heterocycles with deuterium gas Open
H/D exchange in N-heterocycles with D 2 gas was investigated using ultrasmall Ru/Co nanoparticles stabilized by NHC ligands. Catalytic performance is governed by both nanoparticle composition and substrate nature.
View article: Finely Tunable Carbon Nanofiber Catalysts for the Efficient Production of HMF in Biphasic MIBK/H2O Systems
Finely Tunable Carbon Nanofiber Catalysts for the Efficient Production of HMF in Biphasic MIBK/H2O Systems Open
This work proposes catalytic systems for fructose dehydration to 5-hydroxymethylfurfural using a series of functionalized carbon nanofibers. The catalysts were synthesized via finely selected covalent grafting in order to include a variety…
View article: CCDC 2299059: Experimental Crystal Structure Determination
CCDC 2299059: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2299058: Experimental Crystal Structure Determination
CCDC 2299058: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Nitrous oxide activation by picoline-derived Ni–CNP hydrides
Nitrous oxide activation by picoline-derived Ni–CNP hydrides Open
Picoline-derived Ni–CNP hydride complexes activate N 2 O upon base activation, and catalyse the reduction of N 2 O with pinacolborane.
View article: Alkane metathesis over immobilized pincer-ligated iridium complexes: Effect of support nature
Alkane metathesis over immobilized pincer-ligated iridium complexes: Effect of support nature Open
In this work, catalytic alkane metathesis has been evaluated as a suitable approach to upcycle hydrocarbons (polyolefins) at moderate temperatures. To this end, a pincer-ligated iridium complex (dehydrogenation catalyst) has been combined …
View article: Selective hydrodeoxygenation of levulinic acid to γ-valerolactone over Ru supported on functionalized carbon nanofibers
Selective hydrodeoxygenation of levulinic acid to γ-valerolactone over Ru supported on functionalized carbon nanofibers Open
In this work, carbon nanofibers (CNFs) have been successfully functionalized by using different approaches and finally used for the preparation of Ru based catalysts.
View article: Ruthenium nanoparticles stabilized by 1,2,3-triazolylidene ligands in the hydrogen isotope exchange of E–H bonds (E = B, Si, Ge, Sn) using deuterium gas
Ruthenium nanoparticles stabilized by 1,2,3-triazolylidene ligands in the hydrogen isotope exchange of E–H bonds (E = B, Si, Ge, Sn) using deuterium gas Open
Selective hydrogen isotope exchange of E–H (E = B, Si, Ge, Sn) bonds has been accomplished using ruthenium nanoparticles stabilized with different mesoionic carbenes (MICs).
View article: CCDC 2114715: Experimental Crystal Structure Determination
CCDC 2114715: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Catalytic Nitrous Oxide Reduction with H<sub>2</sub> Mediated by Pincer Ir Complexes
Catalytic Nitrous Oxide Reduction with H<sub>2</sub> Mediated by Pincer Ir Complexes Open
Reduction of nitrous oxide (N2O) with H2 to N2 and water is an attractive process for the decomposition of this greenhouse gas to environmentally benign species. Herein, a series of iridium complexes based …
View article: Reduction of N<sub>2</sub>O with hydrosilanes catalysed by RuSNS nanoparticles
Reduction of N<sub>2</sub>O with hydrosilanes catalysed by RuSNS nanoparticles Open
RuSNS nanoparticles promote the conversion of the greenhouse gas N 2 O to non-harmful species.
View article: CCDC 2113025: Experimental Crystal Structure Determination
CCDC 2113025: Experimental Crystal Structure Determination Open
View article: CCDC 2113024: Experimental Crystal Structure Determination
CCDC 2113024: Experimental Crystal Structure Determination Open
View article: CCDC 2113023: Experimental Crystal Structure Determination
CCDC 2113023: Experimental Crystal Structure Determination Open
View article: Ammonia–Borane Dehydrogenation Catalyzed by Dual-Mode Proton-Responsive Ir-CNN<sup>H</sup> Complexes
Ammonia–Borane Dehydrogenation Catalyzed by Dual-Mode Proton-Responsive Ir-CNN<sup>H</sup> Complexes Open
Metal complexes incorporating proton-responsive ligands have been proved to be superior catalysts in reactions involving the H2 molecule. In this contribution, a series of IrIII complexes based on lutidine-derived CNN…
View article: CCDC 2064073: Experimental Crystal Structure Determination
CCDC 2064073: Experimental Crystal Structure Determination Open
View article: CCDC 2064072: Experimental Crystal Structure Determination
CCDC 2064072: Experimental Crystal Structure Determination Open
View article: CCDC 2064071: Experimental Crystal Structure Determination
CCDC 2064071: Experimental Crystal Structure Determination Open
View article: Selective, Base-Free Hydrogenation of Aldehydes Catalyzed by Ir Complexes Based on Proton-Responsive Lutidine-Derived CNP Ligands
Selective, Base-Free Hydrogenation of Aldehydes Catalyzed by Ir Complexes Based on Proton-Responsive Lutidine-Derived CNP Ligands Open
Metal catalysts based on ligands containing proton-responsive sites have found widespread applications in the hydrogenation of polar unsaturated substrates. In this contribution, Ir complexes incorporating lutidine-derived CNP (C = N-heter…
View article: CCDC 1944657: Experimental Crystal Structure Determination
CCDC 1944657: Experimental Crystal Structure Determination Open
View article: CCDC 1581044: Experimental Crystal Structure Determination
CCDC 1581044: Experimental Crystal Structure Determination Open
View article: CCDC 1944659: Experimental Crystal Structure Determination
CCDC 1944659: Experimental Crystal Structure Determination Open
View article: CCDC 1944658: Experimental Crystal Structure Determination
CCDC 1944658: Experimental Crystal Structure Determination Open
View article: CCDC 1968868: Experimental Crystal Structure Determination
CCDC 1968868: Experimental Crystal Structure Determination Open
View article: CCDC 1968869: Experimental Crystal Structure Determination
CCDC 1968869: Experimental Crystal Structure Determination Open
View article: Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands Open
Ru-CNN(H) complexes are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Under basic conditions, these derivatives lead to the formation of Ru(0) species that are observed under catalytic conditions.
View article: CCDC 1918694: Experimental Crystal Structure Determination
CCDC 1918694: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1918693: Experimental Crystal Structure Determination
CCDC 1918693: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1581043: Experimental Crystal Structure Determination
CCDC 1581043: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …