The influence of both the skeleton and substituents of the diphosphane in the photophysical properties of [Cu(NHC)(P^P)]PF₆ TADF-phosphorescent emitters is investigated [NHC = Bz-Im-2-XPy (X = H, Cl)]. The study reveals that optimization of the diphosphane structure can boost quantum yields to as high as 85% using carbenes with simple structural frameworks or substituent wings. Remarkably, the diphosphane skeleton emerges as the most influential factor for controlling the quantum yield (Φ). None of the …

This work aims to amplify the fluorescence of (Z)-4-hetarylidene-5(4H)-oxazolones 1 by suppression of the hula-twist non-radiative deactivation pathway by C^N-orthopalladation of the 4-hetarylidene ring. Different (Z)-4-hetarylidene-2-phenyl-5(4H)-oxazolones, 1a–1c, prepared by the Erlenmeyer–Plöchl method, have been studied. The orthopalladation of (Z)-2-phenyl-4-(5-thiazolylmethylene)-5(4H)-oxazolone (1a) takes place by C-H bond activation of the H4 of the heterocycle and C^N-chelation, giving the dinuclear trif…

Silver bis(carbene) complexes featuring ditopic N-heterocyclic carbene (NHC) ligands have been synthesized which enable the assembly of supramolecular architectures via reaction with silver triflate. Through a systematic exploration of crystal structures and emissive properties, this study investigates the impact of the substituents on the NHC ditopic ligands [R-Im-2-Z-py], where R = Me, benzyl (Bz), or 2-naphthylmethyl (NaphCH₂), and Z = H or Cl in the structural framework and emissive properties obser…

Cationic [Cu(P^P)(Htbz)]PF₆ [P^P = xantphos, dpephos; Htbz = 2-(4-thiazolyl)benzimidazole] and the corresponding neutral complexes [Cu(P^P)(tbz)], obtained through deprotonation of the diimine ligand, have been synthesized with the aim of analyzing the role of the diphosphane and Htbz deprotonation in the emissive properties of these complexes. For the study of the diphosphane effect, the luminescence properties of these compounds have been compared with those of the reported analogous derivatives with …

Weakly fluorescent (<i>Z</i>)-4-arylidene-5-(4<i>H</i>)-oxazolones (<b>1</b>), Φ_PL < 0.1%, containing a variety of conjugated aromatic fragments and/or charged arylidene moieties, have been orthopalladated by reaction with Pd(OAc)₂. The resulting dinuclear complexes (<b>2</b>) have the oxazolone ligands bonded as a C^N-chelate, restricting intramolecular motions involving the oxazolone. From <b>2</b>, a variety of mononuclear derivatives, such as [Pd(C^N-oxazolone)(O₂CCF<sub>3</sub…