P. Skeldon
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View article: Abrasion resistance of a Nb3Sn magnetron-sputtered coating on copper substrates for radio frequency superconducting cavities
Abrasion resistance of a Nb3Sn magnetron-sputtered coating on copper substrates for radio frequency superconducting cavities Open
The paper presents the first study of the abrasion resistance and degradation processes of magnetron-sputtered Nb3Sn coatings on electropolished (EP) or chemical polished (CP) copper substrates. The coating-substrate system is of interest …
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View article: Communication—Formation of a Superconducting MgB<sub>2</sub>-Containing Coating on Niobium by Plasma Electrolytic Oxidation
Communication—Formation of a Superconducting MgB<sub>2</sub>-Containing Coating on Niobium by Plasma Electrolytic Oxidation Open
The feasibility of generating superconducting coatings on niobium using plasma electrolytic oxidation (PEO) is demonstrated. A silicate-phosphate electrolyte was employed containing MgB2 particles. The coatings were examined by scanning el…
View article: Anodic film growth and silver enrichment during anodizing of an Mg-0.6 at.% Ag alloy in fluoride-containing organic electrolytes
Anodic film growth and silver enrichment during anodizing of an Mg-0.6 at.% Ag alloy in fluoride-containing organic electrolytes Open
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View article: Effect of an Fe(II)-modified trivalent chromium conversion process on Cr(VI) formation during coating of AA 2024 alloy
Effect of an Fe(II)-modified trivalent chromium conversion process on Cr(VI) formation during coating of AA 2024 alloy Open
A trivalent chromium conversion coating formed in an Fe(II)-containing solution on AA2024 alloy has been investigated by high resolution analytical electron microscopy, ion beam analysis, Raman spectroscopy and electrochemical tests. It is…
View article: Vanadate post-treatments of anodised aluminium and AA 2024 T3 alloy for corrosion protection
Vanadate post-treatments of anodised aluminium and AA 2024 T3 alloy for corrosion protection Open
Porous anodic films formed on aluminium in sulphuric acid were post-treated using various double-dip processes that incorporate a sparingly-soluble, vanadate, corrosion inhibitor. The processes were optimised by investigating the effects o…
View article: An Optimized Trivalent Chromium Conversion Coating Process for AA2024-T351 Alloy
An Optimized Trivalent Chromium Conversion Coating Process for AA2024-T351 Alloy Open
In this work, a trivalent chromium conversion coating applied on AA2024-T351 alloy has been optimized for corrosion protection in sodium chloride solutions. Scanning electron microscopy, energy dispersive X-ray spectroscopy and electrochem…
View article: Influence of Fluorozirconic Acid on Sulfuric Acid Anodizing of Aluminum
Influence of Fluorozirconic Acid on Sulfuric Acid Anodizing of Aluminum Open
The effects of additions of fluorozirconic acid to sulphuric acid on the anodizing behaviour of aluminium have been investigated under a constant voltage at temperatures of 0 and 20 °C. The fluoroacid increased the rate of film growth, wit…
View article: Gravimetric Measurement of Oxygen Evolution during Anodizing of Aluminum Alloys
Gravimetric Measurement of Oxygen Evolution during Anodizing of Aluminum Alloys Open
A gravimetric method based on changes in buoyancy force of a submerged gas-collecting container has been optimized to measure the evolution of oxygen during anodizing of an aluminium alloy. Previously, the gravimetric method has been used …
View article: Influence of Copper on Trivalent Chromium Conversion Coating Formation on Aluminum
Influence of Copper on Trivalent Chromium Conversion Coating Formation on Aluminum Open
In the present work, modified copper-containing trivalent chromium conversion (TCC) coating processes for aluminum were investigated. The copper addition to the TCC bath was made for the purposes of reducing the generation of hydrogen pero…
View article: Enriched alloy layer on an Al-Cu alloy studied by cyclic voltammetry
Enriched alloy layer on an Al-Cu alloy studied by cyclic voltammetry Open
The behaviour of enriched Al-0.7at.%Cu alloy is investigated using cyclic voltammetry. Enriched alloy layers at the interface between the alloy/oxide film were developed by alkaline etching at 5mAcm-2 in 0.1M sodium hydroxide solution at 2…
View article: Effect of low levels of sulphate on the current density and film morphology during anodizing of aluminium in chromic acid
Effect of low levels of sulphate on the current density and film morphology during anodizing of aluminium in chromic acid Open
Previous work has shown that a low level of sulphate impurity in chromic acid can significantly change the growth rate and the morphology of porous anodic films formed on aluminium at a constant voltage. The changes were associated with in…
View article: Influence of coating morphology on adhesive bonding of titanium pre-treated by plasma electrolytic oxidation
Influence of coating morphology on adhesive bonding of titanium pre-treated by plasma electrolytic oxidation Open
The effect of plasma electrolytic oxidation (PEO) pre-treatments on the adhesive bonding of titanium is investigated using lap-shear tests. Two pre-treatments are compared, using aluminate-phosphate and silicate-phosphate electrolytes resp…
View article: Characterization of 2024 T3 Aluminum Alloy after Rare Earth Desmutting
Characterization of 2024 T3 Aluminum Alloy after Rare Earth Desmutting Open
The effect of CeCl3 and CeCl3 + H2O2 additions to a nitric acid solution for desmutting of 2024 T3 aluminum alloy has been investigated using scanning electron microscopy and energy dispersive X-ray analysis, potentiodynamic polarization a…
View article: Formation of a Trivalent Chromium Conversion Coating on AA2024-T351 Alloy
Formation of a Trivalent Chromium Conversion Coating on AA2024-T351 Alloy Open
The formation of a trivalent chromium conversion coating on AA2024-T351 aluminum alloy has been studied using electron microscopy, scanning Kelvin probe force microscopy, ion beam analysis and X-ray photoelectron spectroscopy (XPS). The co…
View article: Trivalent chromium conversion coating formation on aluminium
Trivalent chromium conversion coating formation on aluminium Open
The formation of a trivalent conversion coating on aluminium has been investigated using analytical electron microscopy, atomic force microscopy, ion beam analysis, glow discharge optical emission spectroscopy, Raman spectroscopy and X-ray…
View article: Effect of sulphate impurity in chromic acid anodizing of aluminium
Effect of sulphate impurity in chromic acid anodizing of aluminium Open
The formation of porous anodic alumina during potentiostatic anodizing of aluminium for times up to 900 s has been investigated using two grades of chromic oxide reagent. The anodic films were examined by ion beam analysis and scanning and…
View article: Effect of current density and behaviour of second phases in anodizing of a Mg-Zn-RE alloy in a fluoride/glycerol/water electrolyte
Effect of current density and behaviour of second phases in anodizing of a Mg-Zn-RE alloy in a fluoride/glycerol/water electrolyte Open
Anodizing of a Mg-Zn-RE alloy was carried out at constant current densities from 0.1 to 10 mA cm−2 in a fluoride/glycerol/water electrolyte. Rutherford backscattering spectroscopy, nuclear reaction analysis and analytical transmission elec…
View article: Formation of grooved and porous coatings on titanium by plasma electrolytic oxidation in H2SO4/H3PO4 electrolytes and effects of coating morphology on adhesive bonding
Formation of grooved and porous coatings on titanium by plasma electrolytic oxidation in H2SO4/H3PO4 electrolytes and effects of coating morphology on adhesive bonding Open
The paper reports a change in the morphology of coatings formed galvanostatically on titanium by plasma electrolytic oxidation in phosphoric/sulfuric acid mixtures, and investigated using scanning electron microscopy, X-ray diffraction, an…
View article: Scanning transmission electron microscopy technique for morphology analysis of anodic oxide film formed on titanium
Scanning transmission electron microscopy technique for morphology analysis of anodic oxide film formed on titanium Open
The application of scanning transmission electron microscopy for morphological observation of anodic oxide films formed on titanium has been successfully explored. Important details of anodic films are readily recorded from high quality im…