P. Thuéry
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View article: A Sydnonimine‐based Click‐and‐Release Approach to Cyclic Products
A Sydnonimine‐based Click‐and‐Release Approach to Cyclic Products Open
Herein, we report a general, efficient, and practical methodology for the macrocyclization of compounds based on the combination of a Cu‐catalyzed click‐and‐release reaction and a hydrophobic tag. The procedure allows the preparation of cy…
View article: Protic Oligozwitterions as a Means of Introducing Strong Hydrogen Bonding Interactions in Uranyl Ion Coordination Polymers
Protic Oligozwitterions as a Means of Introducing Strong Hydrogen Bonding Interactions in Uranyl Ion Coordination Polymers Open
The neutral, dizwitterionic dicarboxylate 1,4‐bis(carboxylatomethyl)piperazine (cmpip) is used in the solvohydrothermal synthesis of three uranyl ion complexes. Both [(UO 2 ) 2 Cl 2 (pda)(cmpip) 2 ]·2H 2 O ( 1 ) and [(UO 2 ) 2 Cl 2 (chdc)(…
View article: Mixed-ligand uranyl ion complexes with two flexible, pyridinium-based dicarboxylate zwitterions and simple anionic dicarboxylates
Mixed-ligand uranyl ion complexes with two flexible, pyridinium-based dicarboxylate zwitterions and simple anionic dicarboxylates Open
A series of mixed-ligand uranyl ion complexes involving two new pyridinium-based dizwitterionic dicarboxylates coupled with dianionic dicarboxylates provides mono-, di-, and triperiodic coordination polymers.
View article: Triperiodic frameworks in the uranyl–2,5-thiophenedicarboxylate system: Effect of unidentate auxiliary ligands
Triperiodic frameworks in the uranyl–2,5-thiophenedicarboxylate system: Effect of unidentate auxiliary ligands Open
International audience
View article: (Benzene-1,2,4,5-tetrayl)tetrakis(3-(1-carboxylatomethylpyridinium)), a novel uranyl-complexing tetrazwitterion
(Benzene-1,2,4,5-tetrayl)tetrakis(3-(1-carboxylatomethylpyridinium)), a novel uranyl-complexing tetrazwitterion Open
The tetrazwitterionic, tetracarboxylate (benzene-1,2,4,5-tetrayl)tetrakis(3-(1-carboxylatomethylpyridinium)) (L) has been synthesized and used as a ligand in mixed-ligand complexes of the uranyl cation involving anionic carboxylates. {[(UO…
View article: Synthesis of crystalline uranyl ion coordination polymers with zwitterionic carboxylate ligands: comparing solvothermal and ambient conditions
Synthesis of crystalline uranyl ion coordination polymers with zwitterionic carboxylate ligands: comparing solvothermal and ambient conditions Open
View article: High photoluminescence quantum yield of a uranyl ion complex with the hemi-zwitterion 1,3-bis(carboxylatomethyl)-1H-benzimidazol-3-ium
High photoluminescence quantum yield of a uranyl ion complex with the hemi-zwitterion 1,3-bis(carboxylatomethyl)-1H-benzimidazol-3-ium Open
View article: Pyridine-based strategies towards nitrogen isotope exchange and multiple isotope incorporation
Pyridine-based strategies towards nitrogen isotope exchange and multiple isotope incorporation Open
View article: Perrhenate anion encapsulation in a uranyl ion–zwitterionic dicarboxylate coordination polymer
Perrhenate anion encapsulation in a uranyl ion–zwitterionic dicarboxylate coordination polymer Open
View article: Bifunctional ligands in uranyl chemistry: Metalloligands and zwitterions
Bifunctional ligands in uranyl chemistry: Metalloligands and zwitterions Open
International audience
View article: 1,1ʹ-Dimethyl-4,4ʹ-bipyridinium as a multivalent structure-directing counterion to anionic uranyl ion polycarboxylate complexes
1,1ʹ-Dimethyl-4,4ʹ-bipyridinium as a multivalent structure-directing counterion to anionic uranyl ion polycarboxylate complexes Open
International audience
View article: CCDC 2286472: Experimental Crystal Structure Determination
CCDC 2286472: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Uranyl ion coordination polymers with the dibenzobarrelene-based <i>rac</i>- and (<i>R</i>,<i>R</i>)-<i>trans</i>-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylate ligands
Uranyl ion coordination polymers with the dibenzobarrelene-based <i>rac</i>- and (<i>R</i>,<i>R</i>)-<i>trans</i>-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylate ligands Open
Uranyl ion complexes of a dibenzobarrelene-based dicarboxylate have oligomeric or mono- to triperiodic polymeric arrangements displaying the influence of the interactions of the hydrophobic part of the ligand on the structures formed.
View article: 4-(Ammoniomethyl)benzoate, a protic zwitterionic bifunctional linker in uranyl ion carboxylate complexes
4-(Ammoniomethyl)benzoate, a protic zwitterionic bifunctional linker in uranyl ion carboxylate complexes Open
The zwitterionic 4-(ammoniomethyl)benzoate ligand contains both a metal-coordinating carboxylate and a hydrogen-bond donor, primary ammonium group, which both contribute to the formation and arrangement of oligomeric or polymeric assemblie…
View article: Formoxyboranes as hydroborane surrogates for the catalytic reduction of carbonyls through transfer hydroboration
Formoxyboranes as hydroborane surrogates for the catalytic reduction of carbonyls through transfer hydroboration Open
A new class of Lewis base stabilized formoxyboranes demonstrates the feasibility of catalytic transfer hydroboration.
View article: Synthesis of sydnonimines from sydnones and their use for bioorthogonal release of isocyanates in cells
Synthesis of sydnonimines from sydnones and their use for bioorthogonal release of isocyanates in cells Open
A new synthetic route to sydnonimines allows the preparation of probes to release isocyanates inside living cells.
View article: Fluorophosphoniums as Lewis acids in organometallic catalysis: application to the carbonylation of β-lactones
Fluorophosphoniums as Lewis acids in organometallic catalysis: application to the carbonylation of β-lactones Open
We describe the synthesis, characterisation, and use as carbonylation catalysts of four organic Lewis acids based on fluorophosphoniums, with tetracarbonyl cobaltate as the counter-anion: [R 3 PF] + [Co(CO) 4 ] − (with R = o -Tol, Cy, i Pr…
View article: CCDC 2278959: Experimental Crystal Structure Determination
CCDC 2278959: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306546: Experimental Crystal Structure Determination
CCDC 2306546: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306551: Experimental Crystal Structure Determination
CCDC 2306551: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306547: Experimental Crystal Structure Determination
CCDC 2306547: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306541: Experimental Crystal Structure Determination
CCDC 2306541: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306549: Experimental Crystal Structure Determination
CCDC 2306549: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306550: Experimental Crystal Structure Determination
CCDC 2306550: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306542: Experimental Crystal Structure Determination
CCDC 2306542: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306540: Experimental Crystal Structure Determination
CCDC 2306540: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306539: Experimental Crystal Structure Determination
CCDC 2306539: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306538: Experimental Crystal Structure Determination
CCDC 2306538: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306548: Experimental Crystal Structure Determination
CCDC 2306548: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306543: Experimental Crystal Structure Determination
CCDC 2306543: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …