Patrick Becker
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View article: Tunable <i>Endo</i>/<i>Exo</i> Selectivity in Direct Catalytic Asymmetric 1,3‐Dipolar Cycloadditions with Polyfunctional Lewis Acid / Azolium–Aryloxide Catalysts
Tunable <i>Endo</i>/<i>Exo</i> Selectivity in Direct Catalytic Asymmetric 1,3‐Dipolar Cycloadditions with Polyfunctional Lewis Acid / Azolium–Aryloxide Catalysts Open
Catalytic asymmetric 1,3‐dipolar cycloadditions (1,3‐DCA) using iminoesters as ylide precursors offer a powerful approach to accessing stereochemically complex, biologically relevant pyrrolidines. Although previous studies have already ach…
View article: Genetic Blueprint for Stringent Response in Betaproteobacterial Aromatoleum/Azoarcus/Thauera Cluster
Genetic Blueprint for Stringent Response in Betaproteobacterial Aromatoleum/Azoarcus/Thauera Cluster Open
Background: The Aromatoleum/Azoarcus/Thauera (AAT) cluster comprises anaerobic degradation specialists (Aromatoleum, Thauera) and N2-fixing endophytes (Azoarcus). Omics-based and genetic studies with associated model strains implicate stri…
View article: Redox−Acid/Base Phase Diagrams as an Entry to Computational Redox Chemistry
Redox−Acid/Base Phase Diagrams as an Entry to Computational Redox Chemistry Open
The rapid depletion of fossil fuels and the change from conventional energy supply to so‐called sustainable and renewable energy sources have led to a renaissance of electrochemical, photochemical, and photoelectrochemical methods for chem…
View article: Modulation of peripheral functional groups for the enhancement of electrochemical HER activity in bimetallic Ni-containing triply-fused porphyrins
Modulation of peripheral functional groups for the enhancement of electrochemical HER activity in bimetallic Ni-containing triply-fused porphyrins Open
We report here nickel(II) complexes (Ni-1 and Ni-2) of triply fused (covalently linked through β–β, meso–meso, β′–β′ linkages) porphyrins functionalized with tert-butyl and O-hexyl chains for the investigation of the electrocatalytic hydro…
View article: Mechanism of substrate binding and transport in BASS transporters
Mechanism of substrate binding and transport in BASS transporters Open
The bile acid sodium symporter (BASS) family transports a wide array of molecules across membranes, including bile acids in humans, and small metabolites in plants. These transporters, many of which are sodium-coupled, have been shown to u…
View article: Reviewer #2 (Public Review): Mechanism of substrate binding and transport in BASS transporters
Reviewer #2 (Public Review): Mechanism of substrate binding and transport in BASS transporters Open
The Bile Acid Sodium Symporter (BASS) family transports a wide array of molecules across membranes, including bile acids in humans, and small metabolites in plants. These transporters, many of which are sodium-coupled, have been shown to u…
View article: Reviewer #1 (Public Review): Mechanism of substrate binding and transport in BASS transporters
Reviewer #1 (Public Review): Mechanism of substrate binding and transport in BASS transporters Open
The Bile Acid Sodium Symporter (BASS) family transports a wide array of molecules across membranes, including bile acids in humans, and small metabolites in plants. These transporters, many of which are sodium-coupled, have been shown to u…
View article: Author Response: Mechanism of substrate binding and transport in BASS transporters
Author Response: Mechanism of substrate binding and transport in BASS transporters Open
The Bile Acid Sodium Symporter (BASS) family transports a wide array of molecules across membranes, including bile acids in humans, and small metabolites in plants. These transporters, many of which are sodium-coupled, have been shown to u…
View article: Mechanism of substrate binding and transport in BASS transporters
Mechanism of substrate binding and transport in BASS transporters Open
The Bile Acid Sodium Symporter (BASS) family transports a wide array of molecules across membranes, including bile acids in humans, and small metabolites in plants. These transporters, many of which are sodium-coupled, have been shown to u…
View article: Reviewer #3 (Public Review): Mechanism of substrate binding and transport in BASS transporters
Reviewer #3 (Public Review): Mechanism of substrate binding and transport in BASS transporters Open
The Bile Acid Sodium Symporter (BASS) family transports a wide array of molecules across membranes, including bile acids in humans, and small metabolites in plants. These transporters, many of which are sodium-coupled, have been shown to u…
View article: CCDC 2195838: Experimental Crystal Structure Determination
CCDC 2195838: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2195836: Experimental Crystal Structure Determination
CCDC 2195836: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2195835: Experimental Crystal Structure Determination
CCDC 2195835: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2253655: Experimental Crystal Structure Determination
CCDC 2253655: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Mechanism of substrate binding and transport in BASS transporters
Mechanism of substrate binding and transport in BASS transporters Open
The bile acid sodium symporter (BASS) family transports a wide array of molecules across membranes, including bile acids in humans, and small metabolites in plants. These transporters, many of which are sodium-coupled, have been shown to u…
View article: Mechanism of substrate binding and transport in BASS transporters
Mechanism of substrate binding and transport in BASS transporters Open
The Bile Acid Sodium Symporter (BASS) family transports a wide array of molecules across membranes, including bile acids in humans, and small metabolites in plants. These transporters, many of which are sodium-coupled, have been shown to u…
View article: Cooperative Lewis Acid‐1,2,3‐Triazolium‐Aryloxide Catalysis: Pyrazolone Addition to Nitroolefins as Entry to Diaminoamides
Cooperative Lewis Acid‐1,2,3‐Triazolium‐Aryloxide Catalysis: Pyrazolone Addition to Nitroolefins as Entry to Diaminoamides Open
Pyrazolones represent an important structural motif in active pharmaceutical ingredients. Their asymmetric synthesis is thus widely studied. Still, a generally highly enantio‐ and diastereoselective 1,4‐addition to nitroolefins providing p…
View article: Mechanism of substrate binding and transport in BASS transporters
Mechanism of substrate binding and transport in BASS transporters Open
The Bile Acid Sodium Symporter (BASS) family transports a wide array of molecules across membranes, including bile acids in humans, and small metabolites in plants. These transporters, many of which are sodium-coupled, have been shown to u…
View article: CCDC 2191346: Experimental Crystal Structure Determination
CCDC 2191346: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191328: Experimental Crystal Structure Determination
CCDC 2191328: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191326: Experimental Crystal Structure Determination
CCDC 2191326: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191320: Experimental Crystal Structure Determination
CCDC 2191320: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191345: Experimental Crystal Structure Determination
CCDC 2191345: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191325: Experimental Crystal Structure Determination
CCDC 2191325: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191343: Experimental Crystal Structure Determination
CCDC 2191343: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191323: Experimental Crystal Structure Determination
CCDC 2191323: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191334: Experimental Crystal Structure Determination
CCDC 2191334: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191344: Experimental Crystal Structure Determination
CCDC 2191344: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …