Patrick Endres
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View article: A Missing Member of the Anderson–Evans Family: Synthesis and Characterization of the Trimethylolmethane-Capped {MnMo6O24} Cluster
A Missing Member of the Anderson–Evans Family: Synthesis and Characterization of the Trimethylolmethane-Capped {MnMo6O24} Cluster Open
In this work, the synthesis and structural characterization of the smallest possible member of the family of bis-functionalized {MnMo6O24} Anderson–Evans polyoxometalates (POMs) is reported. The synthesis of the title compound TBA3{[HC(CH2…
View article: bis(2-Phenylpyridinato)-[4,4′-bis(iodoethynyl)-2,2′-bipyridine]-iridium(III) Hexafluorophosphate
bis(2-Phenylpyridinato)-[4,4′-bis(iodoethynyl)-2,2′-bipyridine]-iridium(III) Hexafluorophosphate Open
This work presents the synthesis and structural characterization of a novel type of biscyclometalated Ir(III) complex, which is equipped with two iodoethynyl moieties on its 2,2′-bipyridine (bpy) ligand. Iodoethynyl moieties represent prom…
View article: Automated screening of precipitation polymerizations and evaluation using image recognition for divinylbenzene and methacrylic acid
Automated screening of precipitation polymerizations and evaluation using image recognition for divinylbenzene and methacrylic acid Open
By applying automated high‐throughput experimentation, 63 precipitation polymerizations of divinylbenzene and methacrylic acid were performed with a total of 1638 samples analyzed by gas chromatography (GC), nuclear magnetic resonance (NMR…
View article: Investigation of the cooperative-effects of Lewis- and Brønstedt acids in homogeneously catalyzed OME fuel synthesis by inline-NMR monitoring
Investigation of the cooperative-effects of Lewis- and Brønstedt acids in homogeneously catalyzed OME fuel synthesis by inline-NMR monitoring Open
The cooperative effect of Lewis and Brønsted acids within the OME fuel synthesis was investigated via inline NMR monitoring.
View article: Application of Digital Methods in Polymer Science and Engineering
Application of Digital Methods in Polymer Science and Engineering Open
The development of new polymer materials is an emerging field for more than 100 years. However, it is currently facing major challenges and the application of digital methods can help to develop new processes, discover new materials and, t…
View article: Oxymethylene Ether (OME) Fuel Catalyst Screening Using In Situ NMR Spectroscopy
Oxymethylene Ether (OME) Fuel Catalyst Screening Using In Situ NMR Spectroscopy Open
Online NMR measurements are introduced in the current study as a new analytical setup for investigation of the oxymethylene dimethyl ether (OME) synthesis. For the validation of the setup, the newly established method is compared with stat…
View article: Frontispiece: Two‐Dimensional Photosensitizer Nanosheets via Low‐Energy Electron Beam Induced Cross‐Linking of Self‐Assembled Ru<sup>II</sup> Polypyridine Monolayers
Frontispiece: Two‐Dimensional Photosensitizer Nanosheets via Low‐Energy Electron Beam Induced Cross‐Linking of Self‐Assembled Ru<sup>II</sup> Polypyridine Monolayers Open
Nanomembranes. In their Communication (e202204953), Andrey Turchanin et al. present two concepts to introduce a photoactive Ru(II) polypyridine complex into carbon nanomembranes. The photoactive units are either directly incorporated into …
View article: Frontispiz: Two‐Dimensional Photosensitizer Nanosheets via Low‐Energy Electron Beam Induced Cross‐Linking of Self‐Assembled Ru<sup>II</sup> Polypyridine Monolayers
Frontispiz: Two‐Dimensional Photosensitizer Nanosheets via Low‐Energy Electron Beam Induced Cross‐Linking of Self‐Assembled Ru<sup>II</sup> Polypyridine Monolayers Open
Nanomembranen. Andrey Turchanin et al. präsentieren in ihrer Zuschrift (e202204953) zwei Konzepte für die Einführung eines photoaktiven Ru(II)-Polypyridinkomplexes in Kohlenstoffnanomembranen. Die photoaktiven Einheiten werden entweder dir…
View article: Micro-flow Size-Exclusion Chromatography for enhanced native Mass Spectrometry of proteins and protein complexes
Micro-flow Size-Exclusion Chromatography for enhanced native Mass Spectrometry of proteins and protein complexes Open
Native Size-exclusion chromatography (SEC) employing aqueous mobile phases with volatile salts at neutral pH combined with native mass spectrometry (nMS) is a useful tool for the characterization of proteins in their native state. However,…
View article: Comparing Microwave and Classical Synthesis of Oxymethylene Dimethyl Ethers
Comparing Microwave and Classical Synthesis of Oxymethylene Dimethyl Ethers Open
Polyoxymethylene dimethyl ethers (OME n ) are considered as substituents or additives for fossil diesel fuel. Efficiency of the synthesis is crucial for the development of industrial scale production plants. Therefore, the design of suitab…
View article: Two‐Dimensional Photosensitizer Nanosheets via Low‐Energy Electron Beam Induced Cross‐Linking of Self‐Assembled Ru<sup>II</sup> Polypyridine Monolayers
Two‐Dimensional Photosensitizer Nanosheets via Low‐Energy Electron Beam Induced Cross‐Linking of Self‐Assembled Ru<sup>II</sup> Polypyridine Monolayers Open
Artificial photosynthesis for hydrogen production is an important element in the search for green energy sources. The incorporation of photoactive units into mechanically stable 2D materials paves the way toward the realization of ultrathi…
View article: Two‐Dimensional Photosensitizer Nanosheets via Low‐Energy Electron Beam Induced Cross‐Linking of Self‐Assembled Ru<sup>II</sup> Polypyridine Monolayers
Two‐Dimensional Photosensitizer Nanosheets via Low‐Energy Electron Beam Induced Cross‐Linking of Self‐Assembled Ru<sup>II</sup> Polypyridine Monolayers Open
Artificial photosynthesis for hydrogen production is an important element in the search for green energy sources. The incorporation of photoactive units into mechanically stable 2D materials paves the way toward the realization of ultrathi…
View article: Towards Covalent Photosensitizer-Polyoxometalate Dyads-Bipyridyl-Functionalized Polyoxometalates and Their Transition Metal Complexes
Towards Covalent Photosensitizer-Polyoxometalate Dyads-Bipyridyl-Functionalized Polyoxometalates and Their Transition Metal Complexes Open
A triol-functionalized 2,2′-bipyridine (bpy) derivative has been synthesized and used for the tris-alkoxylation of polyoxometalate (POM) precursors. The resultant POM-bpy conjugates of the Wells–Dawson- and Anderson-type feature a C–C bond…