Patrick Mollik
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View article: Endohedral Coordination of Bulky Substrates in Metalloenzyme‐Like Organometallic Nanotubes
Endohedral Coordination of Bulky Substrates in Metalloenzyme‐Like Organometallic Nanotubes Open
Artificial receptors inspired by metalloenzymes share three key properties: a structurally flexible cavity, substrate binding via metal‐ligand coordination, and metal‐based redox activity. Herein, we report an organometallic nanotube with …
View article: Endohedral Coordination of Bulky Substrates in Metalloenzyme-like Organometallic Nanotubes
Endohedral Coordination of Bulky Substrates in Metalloenzyme-like Organometallic Nanotubes Open
Artificial receptors inspired by metalloenzymes share three key properties: a structurally flexible cavity, substrate binding via metal–ligand coordination, and metal-based redox activity. Herein, we report an organometallic nanotube with …
View article: Electrocatalytic Transfer Hydrogenation of 1‐Octene with [(<sup>tBu</sup>PCP)Ir(H)(Cl)] and Water
Electrocatalytic Transfer Hydrogenation of 1‐Octene with [(<sup>tBu</sup>PCP)Ir(H)(Cl)] and Water Open
Electrocatalytic hydrogenation of 1‐octene as non‐activated model substrate with neutral water as H‐donor is reported, using [( t Bu PCP)Ir(H)(Cl)] ( 1 ) as the catalyst, to form octane with high faradaic efficiency (FE) of 96 % and a k ob…
View article: Electrocatalytic Transfer Hydrogenation of 1‐Octene with [( <sup>tBu</sup> PCP)Ir(H)(Cl)] and Water
Electrocatalytic Transfer Hydrogenation of 1‐Octene with [( <sup>tBu</sup> PCP)Ir(H)(Cl)] and Water Open
Electrocatalytic hydrogenation of 1‐octene as non‐activated model substrate with neutral water as H‐donor is reported, using [( t Bu PCP)Ir(H)(Cl)] ( 1 ) as the catalyst, to form octane with high faradaic efficiency (FE) of 96 % and a k ob…
View article: Construction and Evaluation of Cheap and Robust Miniature Ag/AgCl Reference Electrodes for Aqueous and Organic Electrolytes
Construction and Evaluation of Cheap and Robust Miniature Ag/AgCl Reference Electrodes for Aqueous and Organic Electrolytes Open
Stable reference electrodes (REs) are crucial for reliable voltammetry, controlled potential electrosynthesis, or spectro‐electrochemistry. Yet, inferior pseudo‐REs, such as plain Ag wire are often used, because commercial REs are expensiv…
View article: Electrocatalytic Transfer Hydrogenation of 1-Octene with [(tBuPCP)Ir(H)(Cl)] and Water
Electrocatalytic Transfer Hydrogenation of 1-Octene with [(tBuPCP)Ir(H)(Cl)] and Water Open
Electrocatalytic hydrogenation of 1-octene as nonactivated model substrate with neutral water as H-donor is reported, using [(tBuPCP)Ir(H)(Cl)] (1) as the catalyst, to form octane with high faradaic efficiency (FE) of 96% and a kobs of 87 …
View article: CCDC 2266859: Experimental Crystal Structure Determination
CCDC 2266859: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265895: Experimental Crystal Structure Determination
CCDC 2265895: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265893: Experimental Crystal Structure Determination
CCDC 2265893: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Beyond Metal-Arenes: Monocarbonyl Ruthenium(II) Catalysts for Transfer Hydrogenation Reactions in Cancer Cells
Beyond Metal-Arenes: Monocarbonyl Ruthenium(II) Catalysts for Transfer Hydrogenation Reactions in Cancer Cells Open
With the aim to design new water-soluble organometallic Ru(II) complexes acting as anticancer agents catalysing transfer hydrogenation (TH) reactions with biomolecules, we have synthesized four Ru(II) monocarbonyl complexes (1-4) featuring…
View article: Proton Independent Electrocatalytic Transfer Hydrogenation of Styrene with [(tBuPCP)Ir(H)(Cl)] and Water
Proton Independent Electrocatalytic Transfer Hydrogenation of Styrene with [(tBuPCP)Ir(H)(Cl)] and Water Open
A new pathway of electrocatalytic transfer hydrogenation with neutral water as the H-donor was discovered using [(tBuPCP)Ir(H)(Cl)] (1) as the catalyst and styrene as a model substrate in THF electrolyte. Cyclic voltammetry experiments wit…