Patrick Pale
YOU?
Author Swipe
View article: Synergistic Gold‐Silicon Catalysis: Unravelling Alkynyl Gold Reactivity and Application to the High‐Performance C‐Alkynylation of Glycals
Synergistic Gold‐Silicon Catalysis: Unravelling Alkynyl Gold Reactivity and Application to the High‐Performance C‐Alkynylation of Glycals Open
Within the synergistic gold‐silicon catalysis concept, we have reported here the efficient and highly α‐stereoselective Au‐Si‐catalyzed alkyne transfer from 1‐trimethylsilylalkynes to glycals, at room temperature and at low loading (0.2–1 …
View article: Chalcogen Bonding with Telluronium Cations: toward Selective Population of Tellurium σ-Holes by Lewis Bases
Chalcogen Bonding with Telluronium Cations: toward Selective Population of Tellurium σ-Holes by Lewis Bases Open
The reaction of tris[3,5-bis(trifluoromethyl)phenyl]telluronium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (BArF-) salt with phosphine oxides OPR3 in 1,2-dichloroethane is exothermic and leads to the population of the three Te σ-holes.…
View article: Chiral <i>N</i>‐Alkylfluorenyl‐Substituted N‐Heterocyclic Carbenes in the Gold(I)‐Catalyzed Enantioselective Cycloisomerization of 1,6‐Enynes
Chiral <i>N</i>‐Alkylfluorenyl‐Substituted N‐Heterocyclic Carbenes in the Gold(I)‐Catalyzed Enantioselective Cycloisomerization of 1,6‐Enynes Open
A series of chiral A * Flu ‐NHC‐gold(I) complexes, where A * Flu ‐NHC is an N‐heterocyclic carbene (imidazolin‐2‐ylidene or benzimidazolin‐2‐ylidene) bearing a chiral 9‐alkyl‐9‐fluorenyl N ‐substituent and a 2,6‐diisopropylphenyl or benzyl…
View article: CuI-Zeolite Catalysis for Biaryl Synthesis via Homocoupling Reactions of Phenols or Aryl Boronic Acids
CuI-Zeolite Catalysis for Biaryl Synthesis via Homocoupling Reactions of Phenols or Aryl Boronic Acids Open
Due to the importance of biaryls as natural products, drugs, agrochemicals, dyes, or organic electronic materials, a green alternative biaryl synthesis has been developed based on easy-to-prepare and cheap copper(I)-exchanged zeolite catal…
View article: Chiral N-Alkylfluorenyl-Substituted N-Heterocyclic Carbenes in Gold(I)-Catalyzed Enantioselective Cycloisomerization of 1,6-Enynes
Chiral N-Alkylfluorenyl-Substituted N-Heterocyclic Carbenes in Gold(I)-Catalyzed Enantioselective Cycloisomerization of 1,6-Enynes Open
A series of chiral A*Flu-NHC-gold(I) complexes, where A*Flu-NHC is an N-heterocyclic carbene (imidazolin-2-ylidene or benzimidazolin-2-ylidene) bearing a chiral 9-alkyl-9-fluorenyl N-substituent and a 2,6-diisopropylphenyl or benzyl N’-sub…
View article: Gold(I)-Catalyzed Access to 1-Alkynyl <i>C</i>-Glycosides from 1-Silylated Alkynes: An Alternative Paradigm for the Direct and α-Stereoselective Alkynylation of Glycosides
Gold(I)-Catalyzed Access to 1-Alkynyl <i>C</i>-Glycosides from 1-Silylated Alkynes: An Alternative Paradigm for the Direct and α-Stereoselective Alkynylation of Glycosides Open
International audience
View article: Telluronium‐Catalyzed Halogenation Reactions: Chalcogen‐Bond Activation of <i>N</i>‐Halosuccinimides and Catalysis
Telluronium‐Catalyzed Halogenation Reactions: Chalcogen‐Bond Activation of <i>N</i>‐Halosuccinimides and Catalysis Open
The ability of triaryltelluronium salts to interact with N ‐halosuccinimides (NXS) through chalcogen bonding (ChB) in the solid state and in solution is demonstrated herein. Cocrystals of the triaryltelluronium bearing two CF 3 electron‐wi…
View article: Phytochemical Profiles and Biological Activities of Frankenia Species: A Review
Phytochemical Profiles and Biological Activities of Frankenia Species: A Review Open
The relatively small Frankeniaceae family is represented by halophyte plants, growing in arid and semi-arid climates in saline, alkaline or calcareous soils. Due to their living conditions, they usually produce a large diversity of compoun…
View article: CCDC 2271920: Experimental Crystal Structure Determination
CCDC 2271920: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271919: Experimental Crystal Structure Determination
CCDC 2271919: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271915: Experimental Crystal Structure Determination
CCDC 2271915: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271914: Experimental Crystal Structure Determination
CCDC 2271914: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271922: Experimental Crystal Structure Determination
CCDC 2271922: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271928: Experimental Crystal Structure Determination
CCDC 2271928: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271930: Experimental Crystal Structure Determination
CCDC 2271930: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271924: Experimental Crystal Structure Determination
CCDC 2271924: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271926: Experimental Crystal Structure Determination
CCDC 2271926: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271929: Experimental Crystal Structure Determination
CCDC 2271929: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271912: Experimental Crystal Structure Determination
CCDC 2271912: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271927: Experimental Crystal Structure Determination
CCDC 2271927: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271918: Experimental Crystal Structure Determination
CCDC 2271918: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271923: Experimental Crystal Structure Determination
CCDC 2271923: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271917: Experimental Crystal Structure Determination
CCDC 2271917: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271913: Experimental Crystal Structure Determination
CCDC 2271913: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271925: Experimental Crystal Structure Determination
CCDC 2271925: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271911: Experimental Crystal Structure Determination
CCDC 2271911: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2271916: Experimental Crystal Structure Determination
CCDC 2271916: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Affinity of Telluronium Chalcogen Bond Donors for Lewis Bases in Solution: A Critical Experimental‐Theoretical Joint Study
Affinity of Telluronium Chalcogen Bond Donors for Lewis Bases in Solution: A Critical Experimental‐Theoretical Joint Study Open
Telluronium salts [Ar 2 MeTe]X were synthesized, and their Lewis acidic properties towards a number of Lewis bases were addressed in solution by physical and theoretical means. Structural X‐ray diffraction analysis of 21 different salts re…
View article: CCDC 2247486: Experimental Crystal Structure Determination
CCDC 2247486: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Chalcogen Bonding Catalysis: Tellurium, the Last Frontier?
Chalcogen Bonding Catalysis: Tellurium, the Last Frontier? Open
Chalcogen bonding (ChB) is the non‐covalent interaction occurring between chalcogen atoms as Lewis acid sites and atoms or groups of atoms able to behave as Lewis bases through their lone pair or π electrons. Analogously to its sister halo…