Patrick Pröhm
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View article: Synthesis and Characterization of the μ<sub>6</sub>-F Compounds [NEt<sub>4</sub>][F(Cl<sub>2</sub>)<sub>3</sub>] and [NEt<sub>4</sub>][F(Br<sub>2</sub>)<sub>3</sub>]
Synthesis and Characterization of the μ<sub>6</sub>-F Compounds [NEt<sub>4</sub>][F(Cl<sub>2</sub>)<sub>3</sub>] and [NEt<sub>4</sub>][F(Br<sub>2</sub>)<sub>3</sub>] Open
The reaction of tetraethylammonium polychlorides or polybromides in propionitrile with substoichiometric amounts of diluted fluorine at low temperatures leads to the non-classical interhalogen compounds [NEt4]-[F-(X2)…
View article: Precise cooperative sulfur placement leads to semi-crystallinity and selective depolymerisability in CS2/oxetane copolymers
Precise cooperative sulfur placement leads to semi-crystallinity and selective depolymerisability in CS2/oxetane copolymers Open
CS 2 promises easy access to degradable sulfur-rich polymers and insights into how main-group derivatisation affects polymer formation and properties, though its ring-opening copolymerisation is plagued by low linkage selectivity and small…
View article: Cooperative taming of CS2/oxetane copolymerisation: Consequences of main-chain sulfuration on polymer properties and catalysis
Cooperative taming of CS2/oxetane copolymerisation: Consequences of main-chain sulfuration on polymer properties and catalysis Open
CS2 promises easy access to degradable sulfur-rich polymers and insights into how main-group derivatisation affects polymer formation and properties, though its ring-opening copolymerisation is plagued by low linkage selectivity and small-…
View article: Cooperative taming of CS2/oxetane copolymerisation: Consequences of main-chain sulfuration on polymer properties and catalysis
Cooperative taming of CS2/oxetane copolymerisation: Consequences of main-chain sulfuration on polymer properties and catalysis Open
CS2 promises easy access to degradable sulfur-rich polymers and insights into how main-group derivatisation affects polymer formation and properties, though its ring-opening copolymerisation is plagued by low linkage selectivity and small-…
View article: CCDC 2223431: Experimental Crystal Structure Determination
CCDC 2223431: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CSD 2223439: Experimental Crystal Structure Determination
CSD 2223439: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CCDC 2223425: Experimental Crystal Structure Determination
CCDC 2223425: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2223424: Experimental Crystal Structure Determination
CCDC 2223424: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2223423: Experimental Crystal Structure Determination
CCDC 2223423: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2223421: Experimental Crystal Structure Determination
CCDC 2223421: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: On pyridine chloronium cations
On pyridine chloronium cations Open
The lutidine elephants are pulling apart a dichlorine molecule and stabilizing the corresponding chloronium cation. The remaining chloride forms a trichloride anion. Unsubstituted pyridine, however, only forms a strongly polarized dichlori…
View article: CCDC 2161289: Experimental Crystal Structure Determination
CCDC 2161289: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2161265: Experimental Crystal Structure Determination
CCDC 2161265: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2151056: Experimental Crystal Structure Determination
CCDC 2151056: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Lithium achieves sequence selective ring-opening terpolymerisation (ROTERP) of ternary monomer mixtures
Lithium achieves sequence selective ring-opening terpolymerisation (ROTERP) of ternary monomer mixtures Open
A sequence selective ring-opening terpolymerisation of epoxides with CS 2 and phthalic thioanhydride yielding poly(ester- alt -ester- alt -trithiocarbonates) is reported.
View article: CCDC 2105613: Experimental Crystal Structure Determination
CCDC 2105613: Experimental Crystal Structure Determination Open
View article: Investigation of Bis(Perfluoro‐<i>tert</i>‐Butoxy) Halogenates(I/III)
Investigation of Bis(Perfluoro‐<i>tert</i>‐Butoxy) Halogenates(I/III) Open
A systematic study of halogenate(I/III) anions with polyatomic ligands is presented. The bis(perfluoro‐ tert ‐butoxy) halogenates(I) [X(OC 4 F 9 ) 2 ] − , X=Cl, Br, I, of chlorine, bromine, and iodine are prepared as their tetraethylammoni…
View article: CCDC 2105589: Experimental Crystal Structure Determination
CCDC 2105589: Experimental Crystal Structure Determination Open
View article: CCDC 2105583: Experimental Crystal Structure Determination
CCDC 2105583: Experimental Crystal Structure Determination Open
View article: CCDC 2105587: Experimental Crystal Structure Determination
CCDC 2105587: Experimental Crystal Structure Determination Open
View article: CCDC 2105590: Experimental Crystal Structure Determination
CCDC 2105590: Experimental Crystal Structure Determination Open
View article: CCDC 2105582: Experimental Crystal Structure Determination
CCDC 2105582: Experimental Crystal Structure Determination Open
View article: CCDC 2060326: Experimental Crystal Structure Determination
CCDC 2060326: Experimental Crystal Structure Determination Open
View article: Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)<sub>3</sub>]<sup>−</sup>
Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)<sub>3</sub>]<sup>−</sup> Open
The [F(ClF)3]− anion was synthesized from an organic chloride salt and chlorine monofluoride. Comparison between the [F(ClF)3]− anion and other permutated chlorine fluorine heptahalides reveals t…
View article: CCDC 2015010: Experimental Crystal Structure Determination
CCDC 2015010: Experimental Crystal Structure Determination Open
View article: CCDC 2015012: Experimental Crystal Structure Determination
CCDC 2015012: Experimental Crystal Structure Determination Open
View article: CCDC 2015013: Experimental Crystal Structure Determination
CCDC 2015013: Experimental Crystal Structure Determination Open
View article: CCDC 2015014: Experimental Crystal Structure Determination
CCDC 2015014: Experimental Crystal Structure Determination Open
View article: CCDC 2015008: Experimental Crystal Structure Determination
CCDC 2015008: Experimental Crystal Structure Determination Open
View article: Soluble Fluoridobromates as Well‐Behaved Strong Fluorination Reagents
Soluble Fluoridobromates as Well‐Behaved Strong Fluorination Reagents Open
We present a facile synthesis of the soluble fluoridobromates [NEt 3 Me][BrF 4 ] and [NEt 3 Me][Br 2 F 7 ] via fluorination of the corresponding bromide salts in acetonitrile, propionitrile or bromine. We structurally characterized the [Br…