Pavel A. Abramov⧫
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View article: [Au(S-C6F5)] and [Au(S-C6F4-CF3)]: reactivity, structural, DSC, and calculations studies
[Au(S-C6F5)] and [Au(S-C6F4-CF3)]: reactivity, structural, DSC, and calculations studies Open
Reactions of HS-Arf (S-Arf = S-C6F5, S-C6F4-CF3) with AuI utilizing a new atom-economy method result in corresponding [Au(S-Arf)]n metal-organic coordination polymers, which were studied by DSC, SEM-EDX, TGA, IR and PL. Treatment of these …
View article: Diamond-like Cage Motifs in {Cu6(StBu)4} Complexes with Pyridines
Diamond-like Cage Motifs in {Cu6(StBu)4} Complexes with Pyridines Open
The reduction of Cu(NO3)2 by HStBu in CH3CN under Ar atmosphere produces a light-yellow solution containing numerous {Cux(StBu)y} species. The addition of different pyridines (py-R) into this solution results in the formation of {Cu6(StBu)…
View article: Strategic Synthesis and Supramolecular Organization of Arylenebis(aryliodonium) Salts
Strategic Synthesis and Supramolecular Organization of Arylenebis(aryliodonium) Salts Open
A comprehensive synthetic toolkit was developed for the preparation of arylenebis(aryliodonium) salts from diiodoarenes via m-CPBA oxidation. The methodology offers versatile approaches that can be adapted based on the solubility of reacti…
View article: Engineering Optical Anisotropy in Paramagnetic Organic Crystals: Dichroism of Nitronyl Nitroxide Radicals
Engineering Optical Anisotropy in Paramagnetic Organic Crystals: Dichroism of Nitronyl Nitroxide Radicals Open
Six aryl- and pyridine-substituted nitronyl-nitroxide radicals were synthesized and characterized to investigate their optical anisotropy properties. Single-crystal X-ray diffraction analysis revealed molecular packing organized either by …
View article: Polymeric lanthanide 2-iodoterephthalates: synthesis and structure
Polymeric lanthanide 2-iodoterephthalates: synthesis and structure Open
Four new heteroligand metal-organic coordination polymers based on lanthanides and 2-iodoterephthalate anions (2-I-BDC) were synthesized — [Sm2(2-I-BDC)3(DMF)2(H2O)2]·6DMF (1), [Sm2(2-I-BDC)3(DMF)2.5(H2O)1.5]·0.5DMF (2), [Eu2(2-I-BDC)3(DMF…
View article: New Catalyst Systems for the Polymerization of Norbornene and Its Derivatives Based on Cationic Palladium Cyclopentadienyl Complexes
New Catalyst Systems for the Polymerization of Norbornene and Its Derivatives Based on Cationic Palladium Cyclopentadienyl Complexes Open
The catalytic properties of systems based on [Pd(Cp)(L)n]m[BF₄]m (where Cp = η5-C5H5; n = 2, m = 1: L = tris(orthomethoxyphenyl)phosphine, triphenylphosphine, tris(2-furyl)phosphine (TFP), n = 1, m = 1: L = 1,1'-bis(diphenylphosphino)ferro…
View article: Key-to-Lock Halogen Bond-Based Tetragonal Pyramidal Association of Iodonium Cations with the Lacune Rims of Beta-Octamolybdate
Key-to-Lock Halogen Bond-Based Tetragonal Pyramidal Association of Iodonium Cations with the Lacune Rims of Beta-Octamolybdate Open
The structure-directing “key-to-lock” interaction of double -(I(III))-hole donating iodonium cations with the O-flanked pseudo-lacune rims of [β-Mo8O26]4– gives halogen-bonded iodonium–beta-octamolybate supramolecular associates. In the oc…
View article: Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate
Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate Open
Iodonium cations recognize the molybdate backbone furnishing “key-to-lock” halogen-bonded supramolecular associates.
View article: CCDC 2258374: Experimental Crystal Structure Determination
CCDC 2258374: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2258372: Experimental Crystal Structure Determination
CCDC 2258372: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2258371: Experimental Crystal Structure Determination
CCDC 2258371: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2236417: Experimental Crystal Structure Determination
CCDC 2236417: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2236419: Experimental Crystal Structure Determination
CCDC 2236419: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2236418: Experimental Crystal Structure Determination
CCDC 2236418: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2226117: Experimental Crystal Structure Determination
CCDC 2226117: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2236420: Experimental Crystal Structure Determination
CCDC 2236420: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2236421: Experimental Crystal Structure Determination
CCDC 2236421: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Pd(II), Pd(III) and Pd(IV) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 44 Years (1980–2023) of NMR and Single Crystal X-ray Studies
Pd(II), Pd(III) and Pd(IV) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 44 Years (1980–2023) of NMR and Single Crystal X-ray Studies Open
In this paper, a review on Pd(II), Pd(III), and Pd(IV) cyclometallated compounds with 2-arylpyridines (2-phenylpyridine, 2-benzylpyridine, 2-benzoylpyridine, 2-phenoxypyridine, 2-phenylsulfanylpyridine, 2-anilinopyridine, 2-(naphth-1-yl)py…
View article: CCDC 2238885: Experimental Crystal Structure Determination
CCDC 2238885: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238890: Experimental Crystal Structure Determination
CCDC 2238890: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238887: Experimental Crystal Structure Determination
CCDC 2238887: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238884: Experimental Crystal Structure Determination
CCDC 2238884: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238888: Experimental Crystal Structure Determination
CCDC 2238888: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238889: Experimental Crystal Structure Determination
CCDC 2238889: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Not So Similar: Different Ways of Nb(V) and Ta(V) Catecholate Complexation
Not So Similar: Different Ways of Nb(V) and Ta(V) Catecholate Complexation Open
The reactions between catechol (H2cat) and niobium(V) or tantalum(V) precursors in basic aqueous solutions lead to the formation of catecholate complexes of different natures. The following complexes were isolated and characterized by sing…
View article: CCDC 2163078: Experimental Crystal Structure Determination
CCDC 2163078: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Iridium Complexes with BIAN-Type Ligands: Synthesis, Structure and Redox Chemistry
Iridium Complexes with BIAN-Type Ligands: Synthesis, Structure and Redox Chemistry Open
A series of iridium complexes with bis(diisopropylphenyl)iminoacenaphtene (dpp-bian) ligands, [Ir(cod)(dpp-bian)Cl] (1), [Ir(cod)(NO)(dpp-bian)](BF4)2 (2) and [Ir(cod)(dpp-bian)](BF4) (3), were prepared and characterized by spectroscopic t…
View article: CCDC 1863357: Experimental Crystal Structure Determination
CCDC 1863357: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1863356: Experimental Crystal Structure Determination
CCDC 1863356: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Novel Route to Cationic Palladium(II)–Cyclopentadienyl Complexes Containing Phosphine Ligands and Their Catalytic Activities
Novel Route to Cationic Palladium(II)–Cyclopentadienyl Complexes Containing Phosphine Ligands and Their Catalytic Activities Open
The Pd(II) complexes [Pd(Cp)(L)n]m[BF4]m were synthesized via the reaction of cationic acetylacetonate complexes with cyclopentadiene in the presence of BF3∙OEt2 (n = 2, m = 1: L = PPh3 (1), P(p-Tol)3, tris(ortho-methoxyphenyl)phosphine (T…