Philip Boehm
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View article: Coupling of unactivated alkyl electrophiles using frustrated ion pairs
Coupling of unactivated alkyl electrophiles using frustrated ion pairs Open
View article: Shuttle HAT for mild alkene transfer hydrofunctionalization
Shuttle HAT for mild alkene transfer hydrofunctionalization Open
Hydrogen atom transfer (HAT) from a metal-hydride is a reliable and powerful method for functionalizing unsaturated C–C bonds in organic synthesis. Cobalt hydrides (Co–H) have garnered significant attention in this field, where the weak Co…
View article: Shuttle HAT for mild alkene transfer hydrofunctionalization
Shuttle HAT for mild alkene transfer hydrofunctionalization Open
Hydrogen atom transfer (HAT) from a metal-hydride is a reliable and powerful method for functionalizing unsaturated C–C bonds in organic synthesis. Cobalt hydrides (Co–H) have garnered significant attention in this field, where the weak Co…
View article: Frustrated Ion Pair-Enabled Cross-Electrophile Coupling of Unactivated Alkyl Electrophiles
Frustrated Ion Pair-Enabled Cross-Electrophile Coupling of Unactivated Alkyl Electrophiles Open
Cross-electrophile coupling reactions have evolved into a major strategy for rapidly assembling important molecules, yet challenges remain for the formation of C(sp3)–C(sp3) bonds that form the core of nearly all organic compounds. Herein,…
View article: CCDC 2254109: Experimental Crystal Structure Determination
CCDC 2254109: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2254108: Experimental Crystal Structure Determination
CCDC 2254108: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Intermolecular Pauson–Khand-Type Reaction of Vinyl Iodides with Alkynes and a CO Surrogate
Intermolecular Pauson–Khand-Type Reaction of Vinyl Iodides with Alkynes and a CO Surrogate Open
A strategy for the palladium-catalyzed intermolecular synthesis of polysubstituted cyclopentenones is reported. The three-component reaction utilizes vinyl iodides and internal alkynes to form the carbon framework of the cyclopentenone wit…
View article: Rhodium‐katalysierte Anti‐Markovnikov Hydroiodierung von Terminalen Alkinen**
Rhodium‐katalysierte Anti‐Markovnikov Hydroiodierung von Terminalen Alkinen** Open
Wir beschreiben eine Rhodium‐katalysierte anti‐Markovnikov Hydroiodierung von terminalen aromatischen und aliphatischen Alkinen. Je nach Wahl des Liganden und Substrats werden entweder ( E )‐ oder ( Z )‐konfigurierte Alkenyliodide mit hohe…
View article: Rhodium‐Catalyzed Anti‐Markovnikov Transfer Hydroiodination of Terminal Alkynes**
Rhodium‐Catalyzed Anti‐Markovnikov Transfer Hydroiodination of Terminal Alkynes** Open
A rhodium‐catalyzed anti‐Markovnikov hydroiodination of aromatic and aliphatic terminal alkynes is reported. Depending on the choice of ligand and substrate, either ( E )‐ or ( Z )‐configured alkenyl iodides are obtained in high to exclusi…
View article: Rhodium-catalyzed Anti-Markovnikov Transfer Hydroiodination of Terminal Alkynes
Rhodium-catalyzed Anti-Markovnikov Transfer Hydroiodination of Terminal Alkynes Open
A rhodium-catalyzed anti-Markovnikov hydroiodination of aromatic and aliphatic terminal alkynes is reported. Depending on the choice of ligand and substrate, either (E)- or (Z)-configured alkenyl iodides are obtained in high to exclusive i…
View article: CCDC 2127249: Experimental Crystal Structure Determination
CCDC 2127249: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127259: Experimental Crystal Structure Determination
CCDC 2127259: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127257: Experimental Crystal Structure Determination
CCDC 2127257: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127272: Experimental Crystal Structure Determination
CCDC 2127272: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127254: Experimental Crystal Structure Determination
CCDC 2127254: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127247: Experimental Crystal Structure Determination
CCDC 2127247: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127253: Experimental Crystal Structure Determination
CCDC 2127253: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127271: Experimental Crystal Structure Determination
CCDC 2127271: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127252: Experimental Crystal Structure Determination
CCDC 2127252: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127255: Experimental Crystal Structure Determination
CCDC 2127255: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127256: Experimental Crystal Structure Determination
CCDC 2127256: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127245: Experimental Crystal Structure Determination
CCDC 2127245: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127266: Experimental Crystal Structure Determination
CCDC 2127266: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127248: Experimental Crystal Structure Determination
CCDC 2127248: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127269: Experimental Crystal Structure Determination
CCDC 2127269: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127263: Experimental Crystal Structure Determination
CCDC 2127263: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127250: Experimental Crystal Structure Determination
CCDC 2127250: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127267: Experimental Crystal Structure Determination
CCDC 2127267: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127258: Experimental Crystal Structure Determination
CCDC 2127258: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2127244: Experimental Crystal Structure Determination
CCDC 2127244: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …