Philipp Boos
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View article: Synthesis and Structure of Titanium Imido Complexes With Bi‐ and Tridentate PN and PNP Ligands
Synthesis and Structure of Titanium Imido Complexes With Bi‐ and Tridentate PN and PNP Ligands Open
We report the synthesis of alkyl and aryl imido titanium(IV) complexes supported by bi‐ or tridentate PN Mes and PNP ligands (PN Mes = (2‐(diisopropylphosphanyl)‐4‐methylphenyl)( N ‐mesityl)‐anilide, PNP = bis(2‐(diisopropylphosphanyl)‐4‐m…
View article: Stereocontrolled Construction of Multi-Chiral [2.2]Paracyclophanes via Cobaltaphotoredox Dual Catalysis
Stereocontrolled Construction of Multi-Chiral [2.2]Paracyclophanes via Cobaltaphotoredox Dual Catalysis Open
Ortho-/pseudo-disubstituted multichiral [2.2]-paracyclophanes (PCPs) represent privileged scaffolds for asymmetric catalysis, finding extensive applications as chiral ligands in organic synthesis and functional materials. However, enantios…
View article: Stereocontrolled Construction of Multi-Chiral [2.2]Paracyclophanes via Cobaltaphotoredox Dual Catalysis
Stereocontrolled Construction of Multi-Chiral [2.2]Paracyclophanes via Cobaltaphotoredox Dual Catalysis Open
Ortho-/pseudo-Disubstituted multi-chiral [2.2]paracyclophanes (PCPs) represent privileged scaffolds for asymmetric catalysis, finding extensive applications as chiral ligands in organic synthesis and functional materials. However, enantios…
View article: Multiple Atropo Selectivity by <i>κ</i> <sup> <i>2</i> </sup> ‐ <i>N</i> , <i>O</i> ‐Oxazoline Urea Ligands in Cobaltaelectro‐Catalyzed C─H Activations: Decoding Selectivity with Data Science Integration
Multiple Atropo Selectivity by <i>κ</i> <sup> <i>2</i> </sup> ‐ <i>N</i> , <i>O</i> ‐Oxazoline Urea Ligands in Cobaltaelectro‐Catalyzed C─H Activations: Decoding Selectivity with Data Science Integration Open
Enantioselective catalysis is one of the most prominent strategies in organic synthesis to access chiral bioactive compounds and advanced organic materials. Particularly, the development of chiral ligands has significantly advanced the eff…
View article: Enantioselective C–H annulations enabled by either nickel- or cobalt-electrocatalysed C–H activation for catalyst-controlled chemodivergence
Enantioselective C–H annulations enabled by either nickel- or cobalt-electrocatalysed C–H activation for catalyst-controlled chemodivergence Open
Enantioselective electrocatalysis shows unique potential for the sustainable assembly of enantiomerically enriched molecules. This approach allows electro-oxidative C–H activation to be performed paired to the hydrogen evolution reaction. …
View article: Parametrization of κ <sup>2</sup> - <i>N</i> , <i>O</i> -Oxazoline Preligands for Enantioselective Cobaltaelectro-Catalyzed C–H Activations
Parametrization of κ <sup>2</sup> - <i>N</i> , <i>O</i> -Oxazoline Preligands for Enantioselective Cobaltaelectro-Catalyzed C–H Activations Open
Enantioselective electrocatalyzed C-H activations have emerged as a transformative platform for the assembly of value-added chiral organic molecules. Despite the recent progress, the construction of multiple C(sp3)-stereogenic centers via …
View article: Parametrization of κ2-N,O-Oxazoline Preligands for Enantioselective Cobaltaelectro-catalyzed C−H Activations
Parametrization of κ2-N,O-Oxazoline Preligands for Enantioselective Cobaltaelectro-catalyzed C−H Activations Open
Enantioselective electrocatalyzed C−H activations have emerged as a transformative platform for the assembly of value-added chiral organic molecules. Despite the recent progress, the construction of multiple C(sp3)-stereogenic centers via …
View article: Multiple Atropo Selectivity by κ2-N,O-Oxazoline Urea Ligands in Cobaltaelectro-Catalyzed C–H Activations: Decoding Selectivity with Data Science Integration
Multiple Atropo Selectivity by κ2-N,O-Oxazoline Urea Ligands in Cobaltaelectro-Catalyzed C–H Activations: Decoding Selectivity with Data Science Integration Open
Enantioselective catalysis is one of the most prominent strategies in organic synthesis to access chiral bioactive compounds and advanced organic materials. Particularly the development of chiral ligands has significantly advanced the effi…
View article: Probing the influence of imidazolylidene- and triazolylidene-based carbenes on the catalytic potential of dioxomolybdenum and dioxotungsten complexes in deoxygenation catalysis
Probing the influence of imidazolylidene- and triazolylidene-based carbenes on the catalytic potential of dioxomolybdenum and dioxotungsten complexes in deoxygenation catalysis Open
We report the synthesis of molydenum and tungsten NHC and MIC complexes with the general formula (OCO)MO 2 (OCO = bis-phenolate NHC/MIC; M = Mo, W) and their utility in the catalytic deoxygenation of nitroarenes.
View article: Iron-catalyzed stereoselective C–H alkylation for simultaneous construction of C–N axial and C-central chirality
Iron-catalyzed stereoselective C–H alkylation for simultaneous construction of C–N axial and C-central chirality Open
The assembly of chiral molecules with multiple stereogenic elements is challenging, and, despite of indisputable advances, largely limited to toxic, cost-intensive and precious metal catalysts. In sharp contrast, we herein disclose a versa…
View article: Nickel-electrocatalyzed enantioselective C–H activations for chemo-divergence
Nickel-electrocatalyzed enantioselective C–H activations for chemo-divergence Open
Enantioselective electrocatalysis bears unique potential for the sustainable assembly of enantiomerically enriched molecules1–7. This approach allows electro-oxidative C–H activation to be performed paired to the hydrogen evolution reactio…
View article: CCDC 2253011: Experimental Crystal Structure Determination
CCDC 2253011: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …