Philipp Petermeier
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View article: Intensified, Kilogram-Scaled, and Environment-Friendly: Chemoenzymatic Synthesis of Bio-Based Acylated Hydroxystyrenes
Intensified, Kilogram-Scaled, and Environment-Friendly: Chemoenzymatic Synthesis of Bio-Based Acylated Hydroxystyrenes Open
Lignin-derived styrene derivatives are versatile building blocks for the manufacture of biobased polymers. As shown previously, phenol-protected hydroxystyrenes are accessible under industrially sound conditions (>100 g L-1, >95% yield) by…
View article: Integrated Preservation of Water Activity as Key to Intensified Chemoenzymatic Synthesis of Bio-Based Styrene Derivatives
Integrated Preservation of Water Activity as Key to Intensified Chemoenzymatic Synthesis of Bio-Based Styrene Derivatives Open
The valorization of lignin-derived feedstocks by catalytic means enables their defunctionalization and upgrading to valuable products. However, the development of productive, safe, and low-waste processes remains challenging. This paper ex…
View article: Integrated Preservation of Water Activity as Key to Intensified Chemoenzymatic Synthesis of Bio-Based Styrene Derivatives
Integrated Preservation of Water Activity as Key to Intensified Chemoenzymatic Synthesis of Bio-Based Styrene Derivatives Open
The valorization of lignin-derived feedstocks by catalytic means enables their defunctionalization and upgrading to valuable products. However, the development of productive, safe, and low-waste processes remains challenging. This paper ex…
View article: CCDC 2235425: Experimental Crystal Structure Determination
CCDC 2235425: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235424: Experimental Crystal Structure Determination
CCDC 2235424: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235422: Experimental Crystal Structure Determination
CCDC 2235422: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235421: Experimental Crystal Structure Determination
CCDC 2235421: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235423: Experimental Crystal Structure Determination
CCDC 2235423: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235426: Experimental Crystal Structure Determination
CCDC 2235426: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Front Cover Picture: Asymmetric Synthesis of Trisubstituted Piperidines <i>via</i> Biocatalytic Transamination and Diastereoselective Enamine or Imine Reduction (Adv. Synth. Catal. 13/2023)
Front Cover Picture: Asymmetric Synthesis of Trisubstituted Piperidines <i>via</i> Biocatalytic Transamination and Diastereoselective Enamine or Imine Reduction (Adv. Synth. Catal. 13/2023) Open
The front cover picture shows the assembly of a trisubstituted piperidine derivative through the controlled formation of C−N and C−H bonds. Different stereoselective synthetic tools – namely transaminase and IRED enzymes, and platinum(0)-c…
View article: Asymmetric Synthesis of Trisubstituted Piperidines <i>via</i> Biocatalytic Transamination and Diastereoselective Enamine or Imine Reduction
Asymmetric Synthesis of Trisubstituted Piperidines <i>via</i> Biocatalytic Transamination and Diastereoselective Enamine or Imine Reduction Open
Substituted piperidine rings are a common motif in natural products and pharmaceutical drugs. The asymmetric synthesis of piperidines bearing multiple stereocentres remains a challenge, and current approaches often rely on lengthy reaction…
View article: Design of a Green Chemoenzymatic Cascade for Scalable Synthesis of Bio-based Styrene Alternatives
Design of a Green Chemoenzymatic Cascade for Scalable Synthesis of Bio-based Styrene Alternatives Open
As renewable lignin building blocks, hydroxystyrenes are particularly appealing as either a replacement or addition to styrene-based polymer chemistry. These monomers are obtained by decarboxylation of phenolic acids and often subjected to…
View article: Design of a Green Chemoenzymatic Cascade for Scalable Synthesis of Bio-based Styrene Alternatives
Design of a Green Chemoenzymatic Cascade for Scalable Synthesis of Bio-based Styrene Alternatives Open
As renewable lignin building blocks, hydroxystyrenes are particularly appealing as either a replacement or addition to styrene-based polymer chemistry. These monomers are obtained by decarboxylation of phenolic acids and often subjected to…
View article: Design of a green chemoenzymatic cascade for scalable synthesis of bio-based styrene alternatives
Design of a green chemoenzymatic cascade for scalable synthesis of bio-based styrene alternatives Open
We present the strategic development of a synthetic onepot two-step process for the manufacture of acetyl-protected hydroxystyrenes from phenolic acid substrates using environmentally benign (bio)catalysts in an eco-friendly solvent.
View article: Exploring the in Vitro Operating Window of Glycosyltransferase PtUGT1 from Polygonum tinctorium for a Biocatalytic Route to Indigo Dye
Exploring the in Vitro Operating Window of Glycosyltransferase PtUGT1 from Polygonum tinctorium for a Biocatalytic Route to Indigo Dye Open
The eobiotic compound indican lends itself to a compelling biocatalytic dyeing strategy for denim, in which the formation of corrosive byproducts is avoided. However, the efficient and scalable production of indican remains a key bottlenec…
View article: Exploring the in Vitro Operating Window of Glycosyltransferase PtUGT1 from Polygonum tinctorium for a Biocatalytic Route to Indigo Dye
Exploring the in Vitro Operating Window of Glycosyltransferase PtUGT1 from Polygonum tinctorium for a Biocatalytic Route to Indigo Dye Open
The eobiotic compound indican lends itself to a compelling biocatalytic dyeing strategy for denim, in which the formation of corrosive byproducts is avoided. However, the efficient and scalable production of indican remains a key bottlenec…
View article: Exploring the <i>in Vitro</i> Operating Window of Glycosyltransferase <i>Pt</i> UGT1 from <i>Polygonum tinctorium</i> for a Biocatalytic Route to Indigo Dye
Exploring the <i>in Vitro</i> Operating Window of Glycosyltransferase <i>Pt</i> UGT1 from <i>Polygonum tinctorium</i> for a Biocatalytic Route to Indigo Dye Open
The eobiotic compound indican lends itself to a compelling biocatalytic dyeing strategy for denim, in which the formation of corrosive byproducts is avoided. However, the efficient and scalable production of indican remains a key bottlenec…
View article: Exploring the in Vitro Operating Window of Glycosyltransferase PtUGT1 from Polygonum Tinctorium for a Biocatalytic Route to Indigo Dye
Exploring the in Vitro Operating Window of Glycosyltransferase PtUGT1 from Polygonum Tinctorium for a Biocatalytic Route to Indigo Dye Open
The eobiotic compound indican lends itself to a compelling biocatalytic dyeing strategy for denim, in which the formation of corrosive by-products is avoided. However, the efficient and scalable production of indican remains a key bottlene…
View article: Exploring the in Vitro Operating Window of Glycosyltransferase PtUGT1 from Polygonum Tinctorium for a Biocatalytic Route to Indigo Dye
Exploring the in Vitro Operating Window of Glycosyltransferase PtUGT1 from Polygonum Tinctorium for a Biocatalytic Route to Indigo Dye Open
The eobiotic compound indican lends itself to a compelling biocatalytic dyeing strategy for denim, in which the formation of corrosive by-products is avoided. However, the efficient and scalable production of indican remains a key bottlene…
View article: Asymmetric Synthesis of Dihydropinidine Enabled by Concurrent Multienzyme Catalysis and a Biocatalytic Alternative to Krapcho Dealkoxycarbonylation
Asymmetric Synthesis of Dihydropinidine Enabled by Concurrent Multienzyme Catalysis and a Biocatalytic Alternative to Krapcho Dealkoxycarbonylation Open
Dihydropinidine is a piperidine alkaloid found in spruce needles that has shown promising antifeedant activity against the large pine weevil, a widespread and economically relevant pest of coniferous tree plantations. Chemo-enzymatic appro…