Pierre Mialane
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View article: Boosting effect of encapsulated polyoxometalates in the photocatalytic CO2 reduction by MOF-545
Boosting effect of encapsulated polyoxometalates in the photocatalytic CO2 reduction by MOF-545 Open
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View article: Chemo–Phototherapeutic Effect of Polyoxometalate-Stabilized Gold Nanostars for Cancer Treatment
Chemo–Phototherapeutic Effect of Polyoxometalate-Stabilized Gold Nanostars for Cancer Treatment Open
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View article: Zr-Based MOF-545 Metal–Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO<sub>2</sub> Methanation
Zr-Based MOF-545 Metal–Organic Framework Loaded with Highly Dispersed Small Size Ni Nanoparticles for CO<sub>2</sub> Methanation Open
We report the use of Zr-based metal-organic frameworks (MOFs) MOF-545 and MOF-545(Cu) as supports to prepare catalysts with uniformly and highly dispersed Ni nanoparticles (NPs) for CO2 hydrogenation into CH4. In the first step, we studied…
View article: Tunable ratiometric temperature sensors based on a Zn-MOF material incorporating luminescent polyoxometalates and carbon dots
Tunable ratiometric temperature sensors based on a Zn-MOF material incorporating luminescent polyoxometalates and carbon dots Open
Incorporation of Eu polyoxometalates and carbon dots into a Zn-MOF matrix represents an efficient strategy to build luminescent ratiometric thermometers.
View article: CSD 2268425: Experimental Crystal Structure Determination
CSD 2268425: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2268426: Experimental Crystal Structure Determination
CSD 2268426: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Structure and Electronic Properties of Large Oligomeric Heterometallic 3d/Ce<sup>IV</sup> Polyoxometalates
Structure and Electronic Properties of Large Oligomeric Heterometallic 3d/Ce<sup>IV</sup> Polyoxometalates Open
Merging the rich chemistry of Ce(IV) polyoxometalates (POMs) with that of 3d polyanions remains a challenge due to the strong competition between these highly oxophilic lanthanide cations and 3d metallic ions for coordination to lacunary m…
View article: Shifting from UV to Visible-Light the Activity of Organic Photoinitiators via the Covalent Grafting of Polyoxometalates
Shifting from UV to Visible-Light the Activity of Organic Photoinitiators via the Covalent Grafting of Polyoxometalates Open
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View article: Origin of the Boosting Effect of Polyoxometalates in Photocatalysis: The Case of CO<sub>2</sub> Reduction by a Rh-Containing Metal–Organic Framework
Origin of the Boosting Effect of Polyoxometalates in Photocatalysis: The Case of CO<sub>2</sub> Reduction by a Rh-Containing Metal–Organic Framework Open
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View article: CSD 2111781: Experimental Crystal Structure Determination
CSD 2111781: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CCDC 2111779: Experimental Crystal Structure Determination
CCDC 2111779: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2111780: Experimental Crystal Structure Determination
CCDC 2111780: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Unveiling the mechanism of the photocatalytic reduction of CO<sub>2</sub>to formate promoted by porphyrinic Zr-based metal–organic frameworks
Unveiling the mechanism of the photocatalytic reduction of CO<sub>2</sub>to formate promoted by porphyrinic Zr-based metal–organic frameworks Open
A complete picture of the reaction mechanism driving the photocatalytic reduction of CO 2 into formate promoted by the Zr-based porphyrinic MOF-545 in CH 3 CN/TEOA solutions is provided for the first time by combining experimental and comp…
View article: Heterogenization of molecular cobalt catalysts in robust metal–organic frameworks for efficient photocatalytic CO<sub>2</sub> reduction
Heterogenization of molecular cobalt catalysts in robust metal–organic frameworks for efficient photocatalytic CO<sub>2</sub> reduction Open
Efficient, selective and recyclable heterogeneous catalysts for photocatalytic CO 2 reduction to CO under visible light irradiation are readily prepared by immobilization of cobalt molecular catalysts into Zr( iv )-based MOFs.
View article: Understanding the Photocatalytic Reduction of CO<sub>2</sub>with Heterometallic Molybdenum(V) Phosphate Polyoxometalates in Aqueous Media
Understanding the Photocatalytic Reduction of CO<sub>2</sub>with Heterometallic Molybdenum(V) Phosphate Polyoxometalates in Aqueous Media Open
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View article: Tailoring the Solid-State Fluorescence of BODIPY by Supramolecular Assembly with Polyoxometalates
Tailoring the Solid-State Fluorescence of BODIPY by Supramolecular Assembly with Polyoxometalates Open
A cationic boron dipyrromethene (BODIPY) derivative (1+) has been successfully combined with two polyoxometalates (POMs), the Lindqvist-type [W6O19]2- and the β-[Mo8O26]4- units, into three new supramolecular fluorescent materials (1)2[W6O…
View article: Gold/Polyoxometalate Core/Shell Nanoparticles for Combined Chemotherapy–Photothermal Cancer Therapy
Gold/Polyoxometalate Core/Shell Nanoparticles for Combined Chemotherapy–Photothermal Cancer Therapy Open
We\ndesigned monodisperse and perfectly shaped core/shell AuNP@Mo4Zol2Mn nanohybrids consisting of gold nanoparticles\n(AuNPs) functionalized by an antitumoral polyoxometalate (POM) incorporating\nthe biologically active zoledronate ligand…
View article: Photoactive Organic/Inorganic Hybrid Materials with Nanosegregated Donor–Acceptor Arrays
Photoactive Organic/Inorganic Hybrid Materials with Nanosegregated Donor–Acceptor Arrays Open
The synthesis of the first mesogenic donor‐acceptor polyoxometalate (POM)‐based hybrid is herein described. The structural and electronic properties of the hybrid compound were evaluated through combination of small‐ and wide‐angle X‐ray s…
View article: Temperature sensors based on europium polyoxometalate and mesoporous terbium metal–organic framework
Temperature sensors based on europium polyoxometalate and mesoporous terbium metal–organic framework Open
A temperature sensor based on lanthanide molecular species immobilized in a lanthanide metal–organic framework exhibits high relative thermal sensitivity in the physiological domain.
View article: Heterogenisation of polyoxometalates and other metal-based complexes in metal–organic frameworks: from synthesis to characterisation and applications in catalysis
Heterogenisation of polyoxometalates and other metal-based complexes in metal–organic frameworks: from synthesis to characterisation and applications in catalysis Open
This review provides a thorough overview of composites with molecular catalysts (polyoxometalates, or organometallic or coordination complexes) immobilised into MOFs via non-covalent interactions.
View article: Co-immobilization of a Rh Catalyst and a Keggin Polyoxometalate in the UiO-67 Zr-Based Metal–Organic Framework: In Depth Structural Characterization and Photocatalytic Properties for CO<sub>2</sub> Reduction
Co-immobilization of a Rh Catalyst and a Keggin Polyoxometalate in the UiO-67 Zr-Based Metal–Organic Framework: In Depth Structural Characterization and Photocatalytic Properties for CO<sub>2</sub> Reduction Open
The Keggin-type polyoxometalate (POM) PW12O403- and the catalytic complex Cp*Rh(bpydc)Cl2 (bpydc = 2,2'-bipyridine-5,5'-dicarboxylic acid) were coimmobilized in the Zr(IV) based metal organic framework UiO-67. The POM is encapsulated withi…
View article: Aerobic oxidation catalyzed by polyoxometalates associated to an artificial reductase at room temperature and in water
Aerobic oxidation catalyzed by polyoxometalates associated to an artificial reductase at room temperature and in water Open
Four polyoxometalates (POMs) were combined with an artificial reductase based on polyethyleneimine (PEI) and flavin mononucleotide (FMN) which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide (NA…
View article: Structure-directing role of immobilized polyoxometalates in the synthesis of porphyrinic Zr-based metal–organic frameworks
Structure-directing role of immobilized polyoxometalates in the synthesis of porphyrinic Zr-based metal–organic frameworks Open
We report the templating effect of the PW12 polyoxometalate on the porphyrinic MOF topologies whereby the kinetic phase is favored at high temperature.
View article: Directing the solid-state photochromic and luminescent behaviors of spiromolecules with Dawson and Anderson polyoxometalate units
Directing the solid-state photochromic and luminescent behaviors of spiromolecules with Dawson and Anderson polyoxometalate units Open
We demonstrate that the solid-state luminescence of an organic molecular switch can be governed by its grafting to polyoxometalate units.
View article: Thin Films of Fully Noble Metal-Free POM@MOF for Photocatalytic Water Oxidation
Thin Films of Fully Noble Metal-Free POM@MOF for Photocatalytic Water Oxidation Open
P2W18Co4@MOF-545, which contains the sandwich-type polyoxometalate (POM) [(PW9O34)2Co4(H2O)2]10- (P2W18Co4) immobilized in the porphyrinic metal-organic framework (MOF), MOF-545, is a "three-in-one" (porosity + light capture + catalysis) h…
View article: Photoactive Polyoxometalate/DASA Covalent Hybrids for Photopolymerization in the Visible Range
Photoactive Polyoxometalate/DASA Covalent Hybrids for Photopolymerization in the Visible Range Open
The synthesis of TBA‐DASA‐POM‐DASA , the first photoactive covalent hybrid polyoxometalate (POM) incorporating a donor–acceptor Stenhouse adduct (DASA) reverse photochrome, is presented. It has been evidenced that in solution the equilibri…
View article: One-pot synthesis of a new generation of hybrid bisphosphonate polyoxometalate gold nanoparticles as antibiofilm agents
One-pot synthesis of a new generation of hybrid bisphosphonate polyoxometalate gold nanoparticles as antibiofilm agents Open
A reduced polyoxovanadate functionalized with alendronate molecules was used for the synthesis of gold nanoparticles; these hybrid nanomaterials exhibit high antibiofilm activity.
View article: Correction: One-pot synthesis of a new generation of hybrid bisphosphonate polyoxometalate gold nanoparticles as antibiofilm agents
Correction: One-pot synthesis of a new generation of hybrid bisphosphonate polyoxometalate gold nanoparticles as antibiofilm agents Open
Correction for ‘One-pot synthesis of a new generation of hybrid bisphosphonate polyoxometalate gold nanoparticles as antibiofilm agents’ by S. Tomane et al., Nanoscale Adv., 2019, 1, 3400–3405.