Pieter Mampuys
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View article: CCDC 2180383: Experimental Crystal Structure Determination
CCDC 2180383: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis of Heterocycles <i>via</i> Aerobic Ni-Catalyzed Imidoylation of Aromatic 1,2-Bis-nucleophiles with Isocyanides
Synthesis of Heterocycles <i>via</i> Aerobic Ni-Catalyzed Imidoylation of Aromatic 1,2-Bis-nucleophiles with Isocyanides Open
o-Phenylene N-substituted iminocarbonates have been obtained by aerobic Ni-catalyzed reaction of readily available catechols and isocyanides. The choice of oxidant and absence of base proved crucial to avoid competitive catechol oxidation …
View article: Transition metal-catalysed carbene- and nitrene transfer to carbon monoxide and isocyanides
Transition metal-catalysed carbene- and nitrene transfer to carbon monoxide and isocyanides Open
In this review the transition metal-catalysed carbene- and nitrene transfer to carbon monoxide and isocyanides will be disclosed. The resulting heteroallene allows for in situ transformation towards numerous functional groups and organic c…
View article: Functional regioregular (poly)urethanes from soft nucleophiles and cyclic iminocarbonates
Functional regioregular (poly)urethanes from soft nucleophiles and cyclic iminocarbonates Open
A method with a broad functional group tolerance is reported to produce in an atom economical fashion functional (poly)urethanes from soft (di)nucleophiles and (di)cyclic iminocarbonates, viewed as a masked version of isocyanates.
View article: C(sp<sup>2</sup>)–H functionalization in non-aromatic azomethine-based heterocycles
C(sp<sup>2</sup>)–H functionalization in non-aromatic azomethine-based heterocycles Open
This review highlights the advances in the direct C(sp2)–H functionalization of cyclic aldimines, aldohydrazones, and aldonitrones since 2008.
View article: Thiosulfonylation of Unactivated Alkenes with Visible-Light Organic Photocatalysis
Thiosulfonylation of Unactivated Alkenes with Visible-Light Organic Photocatalysis Open
Origin of the data: Experimental spectroscopic measurements Data Type: experimental measurements, open access supporting information The data are in CSV, DSW and FBSW format. Supporting information are supplied in PDF format. Data generate…
View article: Thiosulfonylation of Unactivated Alkenes with Visible-Light Organic Photocatalysis
Thiosulfonylation of Unactivated Alkenes with Visible-Light Organic Photocatalysis Open
Origin of the data: Experimental spectroscopic measurements Data Type: experimental measurements, open access supporting information The data are in CSV, DSW and FBSW format. Supporting information are supplied in PDF format. Data generate…
View article: Thiosulfonylation of Unactivated Alkenes with Visible-Light Organic Photocatalysis
Thiosulfonylation of Unactivated Alkenes with Visible-Light Organic Photocatalysis Open
A metal-free method for the vicinal thiosulfonylation of unactivated alkenes with thiosulfonates using 9-mesityl-10-methylacridinium perchlorate as the photo-organocatalyst with visible-light irradiation has been developed. The method can …
View article: Synthesis of Densely Functionalized Pyrimidouracils by Nickel(II)-Catalyzed Isocyanide Insertion
Synthesis of Densely Functionalized Pyrimidouracils by Nickel(II)-Catalyzed Isocyanide Insertion Open
A robust nickel-catalyzed oxidative isocyanide insertion/C-H amination by reaction of readily available N-uracil-amidines with isocyanides affording polysubstituted pyrimidouracils has been reported. The reaction proceeds in moderate to qu…
View article: Synthesis of Functionalized Pyrazin-2(1<i>H</i>)-ones via Tele-Nucleophilic Substitution of Hydrogen Involving Grignard Reactants and Electrophiles
Synthesis of Functionalized Pyrazin-2(1<i>H</i>)-ones via Tele-Nucleophilic Substitution of Hydrogen Involving Grignard Reactants and Electrophiles Open
The reaction of 6-chloro-1-methylpyrazin-2(1 H)-one with Grignard reactants followed by quenching with different electrophiles gave access to a variety of 3,6-difunctionalized 1-methylpyrazin-2(1 H)-ones. This regioselective three-componen…
View article: CCDC 1897429: Experimental Crystal Structure Determination
CCDC 1897429: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis of Secondary Amides from Thiocarbamates
Synthesis of Secondary Amides from Thiocarbamates Open
The synthesis of secondary amides from readily accessible and bench-stable substituted S-phenyl thiocarbamates and Grignard reactants is reported. Oxidative workup allows recycling of the thiolate leaving group as diphenyl disulfide. Diphe…
View article: CCDC 1527663: Experimental Crystal Structure Determination
CCDC 1527663: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1527664: Experimental Crystal Structure Determination
CCDC 1527664: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …