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View article: Turning the Tables: Ligand-Centered Hydride Shuttling in Organometallic BIP–Al Systems
Turning the Tables: Ligand-Centered Hydride Shuttling in Organometallic BIP–Al Systems Open
The reversible storage and release of hydride equivalents remains a central challenge in the design of biomimetic redox systems. Cationic 2,6-bis(imino)pyridine organoaluminum complexes [(4-R-BIP)AlR2]+ (where R = H; R' = Me, 1a; R' = Et, …
View article: A Comparison of β–Phenyl Elimination in Nickel and Palladium Alkyl Complexes: A Potentially Relevant Process in the Mizoroki–Heck Reaction
A Comparison of β–Phenyl Elimination in Nickel and Palladium Alkyl Complexes: A Potentially Relevant Process in the Mizoroki–Heck Reaction Open
There is currently much interest in avoiding precious metals in catalysis. The development of nickel catalysts to replace palladium in the Mizoroki–Heck reaction is a relevant case in this line of research, since both elements share many c…
View article: A Comparison of Beta-Phenyl elimination in Nickel and Palladium Alkyl Complexes, a Potentially Relevant Process in the Mizoroki-Heck Reaction
A Comparison of Beta-Phenyl elimination in Nickel and Palladium Alkyl Complexes, a Potentially Relevant Process in the Mizoroki-Heck Reaction Open
There is currently much interest in avoiding precious metals in Catalysis. The devel-opment of nickel catalysts to replace palladium in the Mizoroki-Heck reaction is a relevant case in this line of research since both elements share many c…
View article: CCDC 2078309: Experimental Crystal Structure Determination
CCDC 2078309: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Nucleophilic Nickel and Palladium Pincer Hydroxides: A Study of Their Reactions with Dimethyl Carbonate and Other Non‐Alkylating Organic Electrophiles
Nucleophilic Nickel and Palladium Pincer Hydroxides: A Study of Their Reactions with Dimethyl Carbonate and Other Non‐Alkylating Organic Electrophiles Open
The reactions of the pincer hydroxide complexes [( iPr PCP)M(OH)] (M=Ni, Pd) with dimethyl carbonate (DMC), and a set of organic electrophiles including benzaldehyde have been investigated in the context of our ongoing investigation on the…
View article: CCDC 1944624: Experimental Crystal Structure Determination
CCDC 1944624: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1944621: Experimental Crystal Structure Determination
CCDC 1944621: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1944622: Experimental Crystal Structure Determination
CCDC 1944622: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1944623: Experimental Crystal Structure Determination
CCDC 1944623: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Neutral, cationic and anionic organonickel and -palladium complexes supported by iminophosphine/phosphinoenaminato ligands
Neutral, cationic and anionic organonickel and -palladium complexes supported by iminophosphine/phosphinoenaminato ligands Open
Ligand exchange and oxidative addition reactions allow the synthesis of Ni(ii) and Pd(ii) complexes with deprotonable iminophosphine ligands. The acid–base behavior of iminophosphine ligands coordinated to organometallic Ni(ii) fragments i…
View article: Aluminium(<scp>iii</scp>) dialkyl 2,6-bisimino-4<i>R</i>-dihydropyridinates(−1): selective synthesis, structure and controlled dimerization
Aluminium(<span>iii</span>) dialkyl 2,6-bisimino-4<i>R</i>-dihydropyridinates(−1): selective synthesis, structure and controlled dimerization Open
2,6-Bisimino-4-alkyl-1,4-dihydropyridines provide access to dihydropyridinate(−1) aluminium(iii) dialkyls, their double cycloaddition dimerization products and metal free ditopic ligands after controlled methanolysis.
View article: Monomeric alkoxide and alkylcarbonate complexes of nickel and palladium stabilized with the <sup>iPr</sup>PCP pincer ligand: a model for the catalytic carboxylation of alcohols to alkyl carbonates
Monomeric alkoxide and alkylcarbonate complexes of nickel and palladium stabilized with the <sup>iPr</sup>PCP pincer ligand: a model for the catalytic carboxylation of alcohols to alkyl carbonates Open
Monomeric nickel and palladium alkoxides stabilized with pincer ligands provide a model for the study of key steps in the catalytic synthesis of organic carbonates from alcohols and CO2.
View article: Neutral Bis(imino)-1,4-dihydropyridinate and Cationic Bis(imino)pyridine σ-Alkylzinc(II) Complexes as Hydride Exchange Systems: Classic Organometallic Chemistry Meets Ligand-Centered, Biomimetic Reactivity
Neutral Bis(imino)-1,4-dihydropyridinate and Cationic Bis(imino)pyridine σ-Alkylzinc(II) Complexes as Hydride Exchange Systems: Classic Organometallic Chemistry Meets Ligand-Centered, Biomimetic Reactivity Open
The 1,4-dihydropyridinate complex [(4-Bn-HBIP)Zn(Bn)], readily available through the highly selective reaction of a 2,6-bis(imino)pyridine ligand with dibenzylzinc, contains two distinct reactive centers. One of them is the σ-organometalli…
View article: CCDC 1869188: Experimental Crystal Structure Determination
CCDC 1869188: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1869190: Experimental Crystal Structure Determination
CCDC 1869190: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1869191: Experimental Crystal Structure Determination
CCDC 1869191: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1566705: Experimental Crystal Structure Determination
CCDC 1566705: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1869189: Experimental Crystal Structure Determination
CCDC 1869189: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1566704: Experimental Crystal Structure Determination
CCDC 1566704: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Nickel Pincer Complexes with Frequent Aliphatic Alkoxo Ligands [(<sup>iPr</sup>PCP)Ni-OR] (R = Et, <i>n</i>Bu, <i>i</i>Pr, 2-hydroxyethyl). An Assessment of the Hydrolytic Stability of Nickel and Palladium Alkoxides
Nickel Pincer Complexes with Frequent Aliphatic Alkoxo Ligands [(<sup>iPr</sup>PCP)Ni-OR] (R = Et, <i>n</i>Bu, <i>i</i>Pr, 2-hydroxyethyl). An Assessment of the Hydrolytic Stability of Nickel and Palladium Alkoxides Open
A series of nickel pincer complexes with terminal alkoxo ligands [(iPrPCP)Ni-OR] (R = Et, nBu, iPr, CH2CH2OH; iPrPCP is the 2,6-bis(diisopropylphosphinomethyl)phenyl pincer ligand) was synthesized and fully characterized. Together with the…
View article: CCDC 1541333: Experimental Crystal Structure Determination
CCDC 1541333: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1541332: Experimental Crystal Structure Determination
CCDC 1541332: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1541334: Experimental Crystal Structure Determination
CCDC 1541334: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1541335: Experimental Crystal Structure Determination
CCDC 1541335: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1456484: Experimental Crystal Structure Determination
CCDC 1456484: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1456485: Experimental Crystal Structure Determination
CCDC 1456485: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …