Pingyun Feng
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View article: Prussian Blue Analogues and Their Derivatives for the Oxygen Evolution Reaction: A Review on Active Site Engineering Strategies
Prussian Blue Analogues and Their Derivatives for the Oxygen Evolution Reaction: A Review on Active Site Engineering Strategies Open
The oxygen evolution reaction (OER) is a kinetic bottleneck in electrochemical water splitting, creating an urgent need for the development of efficient electrocatalysts. Prussian blue analogues (PBAs), a significant class of inorganic coo…
Isoreticular Tolerance and Phase Selection in the Synthesis of Multi‐Module Metal–Organic Frameworks for Gas Separation and Electrocatalytic OER Open
Although metal–organic frameworks are coordination‐driven assemblies, the structural prediction and design using metal‐ligand interactions can be unreliable due to other competing interactions. Leveraging non‐coordination interactions to d…
Isoreticular Tolerance and Phase Selection in the Synthesis of Multi‐Module Metal–Organic Frameworks for Gas Separation and Electrocatalytic OER Open
Although metal–organic frameworks are coordination‐driven assemblies, the structural prediction and design using metal‐ligand interactions can be unreliable due to other competing interactions. Leveraging non‐coordination interactions to d…
Ligand Circuit Concept for Developing Gas Separation Materials from Pore‐Space‐Partitioned Metal‐Organic Frameworks Open
Isoreticular chemistry is among the most powerful strategies for designing novel materials with optimizable pore geometry and properties. Of great significance to the further advance of isoreticular chemistry is the development of broadly …
Multi‐Stage Optimization of Pore Size and Shape in Pore‐Space‐Partitioned Metal–Organic Frameworks for Highly Selective and Sensitive Benzene Capture Open
Compared to exploratory development of new structure types, pushing the limits of isoreticular synthesis on a high‐performance MOF platform may have higher probability of achieving targeted properties. Multi‐modular MOF platforms could off…
Multi‐Stage Optimization of Pore Size and Shape in Pore‐Space‐Partitioned Metal–Organic Frameworks for Highly Selective and Sensitive Benzene Capture Open
Compared to exploratory development of new structure types, pushing the limits of isoreticular synthesis on a high‐performance MOF platform may have higher probability of achieving targeted properties. Multi‐modular MOF platforms could off…
Ultrastable Carboxyl‐Functionalized Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation Open
Isoreticular chemistry, which enables property optimization by changing compositions without changing topology, is a powerful synthetic strategy. One of the biggest challenges facing isoreticular chemistry is to extend it to ligands with s…
Advancing Pore‐Space‐Partitioned Metal–Organic Frameworks with Isoreticular Cluster Concept Open
Trigonal planar M 3 (O/OH) trimers are among the most important clusters in inorganic chemistry and are the foundational features of multiple high‐impact MOF platforms. Here we introduce a concept called isoreticular cluster series and dem…
Tailorable Multi‐Modular Pore‐Space‐Partitioned Vanadium Metal‐Organic Frameworks for Gas Separation Open
Currently, few porous vanadium metal‐organic frameworks (V‐MOFs) are known and even fewer are obtainable as single crystals, resulting in limited information on their structures and properties. Here this work demonstrates remarkable promis…
View article: Cyclobutanedicarboxylate Metal–Organic Frameworks as a Platform for Dramatic Amplification of Pore Partition Effect
Cyclobutanedicarboxylate Metal–Organic Frameworks as a Platform for Dramatic Amplification of Pore Partition Effect Open
Ultrafine tuning of MOF structures at subangstrom or picometer levels can help improve separation selectivity for gases with subtle differences. However, for MOFs with a large enough pore size, the effect from ultrafine tuning on sorption …
View article: Multi‐Modular Design of Stable Pore‐Space‐Partitioned Metal–Organic Frameworks for Gas Separation Applications
Multi‐Modular Design of Stable Pore‐Space‐Partitioned Metal–Organic Frameworks for Gas Separation Applications Open
Pore space partition (PSP) is an effective materials design method for developing high‐performance small‐pore materials for storage and separation of gas molecules. The continued success of PSP depends on broad availability and judicious c…
View article: CCDC 2192230: Experimental Crystal Structure Determination
CCDC 2192230: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2210354: Experimental Crystal Structure Determination
CCDC 2210354: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2210327: Experimental Crystal Structure Determination
CCDC 2210327: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2192229: Experimental Crystal Structure Determination
CCDC 2192229: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2209904: Experimental Crystal Structure Determination
CCDC 2209904: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2255573: Experimental Crystal Structure Determination
CCDC 2255573: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2257299: Experimental Crystal Structure Determination
CCDC 2257299: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Simultaneous Control of Flexibility and Rigidity in Pore-Space-Partitioned Metal–Organic Frameworks
Simultaneous Control of Flexibility and Rigidity in Pore-Space-Partitioned Metal–Organic Frameworks Open
Flexi-MOFs are typically limited to low-connected (pacs (partitioned acs net) platform allows us to introduce flexibility as well as to simultaneously impose high rigidity in a tunable module-specific fashion. The inter-modular synergy has…
Highly Stable Fe/Co-TPY-MIL-88(NH<sub>2</sub>) Metal–Organic Framework (MOF) in Enzymatic Cascade Reactions for Chemiluminescence-Based Detection of Extracellular Vesicles Open
Metal-Organic Frameworks (MOFs) can deliver many advantages when acting as enzyme mimics to assist with signal amplification in molecular detection: they have abundant active catalytic sites per unit volume of the material; their structure…
Solvent‐free Synthesis of Multi‐Module Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation Open
Multi‐module design of framework materials with multiple distinct building blocks has attracted much attention because such materials are more amenable to compositional and geometrical tuning and thus offer more opportunities for property …
Solvent‐free Synthesis of Multi‐Module Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation Open
Multi‐module design of framework materials with multiple distinct building blocks has attracted much attention because such materials are more amenable to compositional and geometrical tuning and thus offer more opportunities for property …
View article: CCDC 2192231: Experimental Crystal Structure Determination
CCDC 2192231: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Concurrent Enhancement of Acetylene Uptake Capacity and Selectivity by Progressive Core Expansion and Extra‐Framework Anions in Pore‐Space‐Partitioned Metal–Organic Frameworks
Concurrent Enhancement of Acetylene Uptake Capacity and Selectivity by Progressive Core Expansion and Extra‐Framework Anions in Pore‐Space‐Partitioned Metal–Organic Frameworks Open
A multi‐stage core‐expansion method is proposed here as one component of the integrative binding‐site/extender/core‐expansion ( BEC ) strategy. The conceptual deconstruction of the partitioning ligand into three editable parts draws our fo…
View article: Developing Water‐Stable Pore‐Partitioned Metal‐Organic Frameworks with Multi‐Level Symmetry for High‐Performance Sorption Applications
Developing Water‐Stable Pore‐Partitioned Metal‐Organic Frameworks with Multi‐Level Symmetry for High‐Performance Sorption Applications Open
A new perspective is proposed in the design of pore‐space‐partitioned MOFs that is focused on ligand symmetry properties sub‐divided here into three hierarchical levels: 1) overall ligand, 2) ligand substructure such as backbone or core, a…
View article: CCDC 2159094: Experimental Crystal Structure Determination
CCDC 2159094: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2159092: Experimental Crystal Structure Determination
CCDC 2159092: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2159093: Experimental Crystal Structure Determination
CCDC 2159093: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2159091: Experimental Crystal Structure Determination
CCDC 2159091: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …