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Reactivity of Phenylacetylene toward Unsymmetrical Disilenes: Regiodivergent [2+2] Cycloaddition vs. CH Addition Open
We report the regiodivergent reaction of phenylacetylene with a selection of disilenes Tip 2 Si=SiTipR as well as bridged tetrasiladienes Tip 2 Si=SiTip−LU−SiTip=SiTip 2 (Tip=2,4,6‐ i Pr 3 C 6 H 2 , R=aryl groups; LU=arylene linkers). The …
Dialumenes – aryl<i>vs.</i>silyl stabilisation for small molecule activation and catalysis Open
Ligand controlled reactivity: atrans-bent and twisted geometry enables dihydrogen activation and enhanced catalytic activity for NHC-stabilised dialumenes.
CO<sub>2</sub>Fixation and Catalytic Reduction by a Neutral Aluminum Double Bond Open
CO 2 fixation and reduction to value‐added products is of utmost importance in the battle against rising CO 2 levels in the Earth's atmosphere. An organoaluminum complex containing a formal aluminum double bond (dialumene), and thus an alk…
CO<sub>2</sub>Fixation and Catalytic Reduction by a Neutral Aluminum Double Bond Open
CO 2 fixation and reduction to value‐added products is of utmost importance in the battle against rising CO 2 levels in the Earth's atmosphere. An organoaluminum complex containing a formal aluminum double bond (dialumene), and thus an alk…
View article: NHCs in Main Group Chemistry
NHCs in Main Group Chemistry Open
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the 1990s, these divalent carbon species have become a common and available class of compounds, which have found numerous applications in academic and…
A Stable Neutral Compound with an Aluminum–Aluminum Double Bond Open
Homodinuclear multiple-bonded neutral Al compounds, aluminum analogues of alkenes, have been a notoriously difficult synthetic target over the past several decades. Herein, we report the isolation of a stable neutral compound featuring an …
Front Cover: Heterometallic [Cu<sub>2</sub>Ln<sub>3</sub>] (Ln = Dy<sup>III</sup>, Gd<sup>III</sup> and Ho<sup>III</sup>) and [Cu<sub>4</sub>Ln<sub>2</sub>] (Ln = Dy<sup>III</sup> and Ho<sup>III</sup>) Compounds: Synthesis, Structure, and Magnetism (Eur. J. Inorg. Chem. 8/2017) Open
The cover picture shows a pentanuclear and a hexanuclear complex based on Cu/Ln metal ions and the frequency dependence of their out-of-phase signals at various temperatures in the absence of a static bias dc field. These complexes were pr…
Heterometallic [Cu<sub>2</sub>Ln<sub>3</sub>] (Ln = Dy<sup>III</sup>, Gd<sup>III</sup> and Ho<sup>III</sup>) and [Cu<sub>4</sub>Ln<sub>2</sub>] (Ln = Dy<sup>III</sup> and Ho<sup>III</sup>) Compounds: Synthesis, Structure, and Magnetism Open
Invited for the cover of this issue is the group of Vadapalli Chandrasekhar from the Indian Institute of Technology Kanpur, India, in collaboration with the group of Paul Kögerler from RWTH Aachen University, Germany. The cover image shows…
CCDC 1463180: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1564060: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1564056: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1463869: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1564059: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1463172: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …