R. Bruce King
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View article: Changes to care delivery at nine international pediatric diabetes clinics in response to the COVID‐19 global pandemic
Changes to care delivery at nine international pediatric diabetes clinics in response to the COVID‐19 global pandemic Open
BACKGROUND: Pediatric diabetes clinics around the world rapidly adapted care in response to COVID-19. We explored provider perceptions of care delivery adaptations and challenges for providers and patients across nine international pediatr…
View article: Design of Binuclear Complexes M2z2 of All First Row Transition Metals (M = Sc to Zn) with a Cyclic N4-Tetradentate Ligand [Z = (C4h6n4)2-]: Sandwiches Mimicking Paddlewheel Complexes
Design of Binuclear Complexes M2z2 of All First Row Transition Metals (M = Sc to Zn) with a Cyclic N4-Tetradentate Ligand [Z = (C4h6n4)2-]: Sandwiches Mimicking Paddlewheel Complexes Open
View article: Alkyne dichotomy and hydrogen migration in binuclear cyclopentadienylmetal alkyne complexes
Alkyne dichotomy and hydrogen migration in binuclear cyclopentadienylmetal alkyne complexes Open
Low-energy (Me 2 N) 2 C 2 M 2 (C 5 H 5 ) 2 (M = Ni, Co, Fe) structures have central Mn 2 C 2 tetrahedrane units or separate bridging Me 2 NC carbyne units. However, low-energy (Me 2 NC 2 Me)M 2 (C 5 H 5 ) 2 and Me 2 C 2 M 2 (C 5 H 5 ) 2 st…
View article: Comparison of Gallium Cluster Polyhedra with Those of the Most Spherical Deltahedra: Effects of Bulky External Groups and Local Surface Curvature
Comparison of Gallium Cluster Polyhedra with Those of the Most Spherical Deltahedra: Effects of Bulky External Groups and Local Surface Curvature Open
Experimentally accessible stable polyhedral clusters of gallium differ from clusters of its lighter homologue boron by having sterically demanding external groups such as tBu3Si, (Me3Si)3Si, (Me3Si)3C, (Me3Si)2N, and fluorenyl. This restri…
View article: Ring Size Effects on the Structures of Sandwich Compounds with a Stoichiometry of C<sub>12</sub>H<sub>12</sub>M (M = Ti–Ni)
Ring Size Effects on the Structures of Sandwich Compounds with a Stoichiometry of C<sub>12</sub>H<sub>12</sub>M (M = Ti–Ni) Open
Ring size effects on geometries and electronic structures were investigated for the (C n H n )M(C m H m ) (n = 4, 5, or 6; m = 8, 7, or 6; m + …
View article: Iron Carbonyl Complexes of [2.2.2]Hericene as a Rigid Tris(1,3-diene) Ligand
Iron Carbonyl Complexes of [2.2.2]Hericene as a Rigid Tris(1,3-diene) Ligand Open
Hericene is an unusual hexaolefin consisting of three 1,3-diene units located on a rigid bicyclo [2.2.2]octane framework that restricts the geometrical relationships of metal atoms bonded to these olefinic units. In order to explore possib…
View article: Trinuclear and Tetranuclear Ruthenium Carbonyl Nitrosyls: Oxidation of a Carbonyl Ligand by an Adjacent Nitrosyl Ligand
Trinuclear and Tetranuclear Ruthenium Carbonyl Nitrosyls: Oxidation of a Carbonyl Ligand by an Adjacent Nitrosyl Ligand Open
Trinuclear and tetranuclear ruthenium carbonyls of the types Ru3(CO)n(NO)2, Ru3(N)(CO)n(NO), Ru3(N)2(CO)n, Ru3(N)(CO)n(NCO), Ru3(CO)n(NCO)(NO), Ru4(N)(CO)n(NO), Ru4(N)(CO)n(NCO), and Ru4(N)2(CO)n related to species observed experimentally …
View article: Nitrous oxide and dinitrogen complexes as intermediates in the decomposition of metal carbonyl nitrosyls: The triruthenium system
Nitrous oxide and dinitrogen complexes as intermediates in the decomposition of metal carbonyl nitrosyls: The triruthenium system Open
View article: Decarbonylation Products of Binuclear Methylphosphinidene Complexes of Cyclopentadienyliron Carbonyls: Triplet and Quintet Structures Are Favored Energetically over Singlet Structures with Iron–Iron Multiple Bonding
Decarbonylation Products of Binuclear Methylphosphinidene Complexes of Cyclopentadienyliron Carbonyls: Triplet and Quintet Structures Are Favored Energetically over Singlet Structures with Iron–Iron Multiple Bonding Open
The structures, energetics, and energetically preferred spin states of methylphosphinidene-bridged binuclear cyclopentadienyliron carbonyl complexes MePFe2(CO)nCp2 (n = 4, 3, 2, and 1) related…
View article: Binuclear methylphosphinidine complexes of cyclopentadienylruthenium carbonyls: effects of the higher ligand field strength of ruthenium derivatives relative to iron derivatives
Binuclear methylphosphinidine complexes of cyclopentadienylruthenium carbonyls: effects of the higher ligand field strength of ruthenium derivatives relative to iron derivatives Open
The structures and energetics of the binuclear methylphosphinidene complexes of cyclopentadienylruthenium carbonyls of the type [MePRu 2 (CO) n Cp 2 ] ( n = 4, 3, 2, 1) have been investigated for comparison with their previously studied ir…
View article: Systematics of stable copper and silver clusters protected by small bite chelating bidentate sulfur and selenium ligands related to their polyhedral cavities: analogies to aliphatic compounds and three-dimensional spherical aromatic systems
Systematics of stable copper and silver clusters protected by small bite chelating bidentate sulfur and selenium ligands related to their polyhedral cavities: analogies to aliphatic compounds and three-dimensional spherical aromatic systems Open
Silver clusters composed exclusively of fused tetrahedra are analogous to simple saturated organic compounds. Copper clusters with central cuboctahedra and silver clusters with central icosahedra having interstitial metal atoms provide exa…
View article: Polyhedral Ferraboranes with Iron Carbonyl Vertices: Carbonyl Migration Processes in the Iron Tetracarbonyl Derivatives
Polyhedral Ferraboranes with Iron Carbonyl Vertices: Carbonyl Migration Processes in the Iron Tetracarbonyl Derivatives Open
The structures and energetics of the neutral Bn-1Hn-1Fe(CO)x (x = 4, 3) and the dianions [Bn-1Hn-1Fe(CO)3]2- (…
View article: Unraveling the Major Differences between the Trinuclear Cyclopentadienylmetal Carbonyl Chemistry of Cobalt and That of Nickel─A Theoretical Study
Unraveling the Major Differences between the Trinuclear Cyclopentadienylmetal Carbonyl Chemistry of Cobalt and That of Nickel─A Theoretical Study Open
The geometries and energetics of the trinuclear cyclopentadienylmetal carbonyls Cp3M3(CO)n (Cp = η5-C5H5); M = Co, Ni; n = 3, 2, 1, 0) have been investigated b…
View article: PACT Perovskite PV Module Outdoor Test Protocol (Version 0.1)
PACT Perovskite PV Module Outdoor Test Protocol (Version 0.1) Open
The purpose of this protocol is to define procedures and practices to be used by the PACT center for field testing of metal halide perovskite (MHP) photovoltaic (PV) modules. The protocol defines the physical, electrical, and analytical co…
View article: Polyhedral Dicobaltadithiaboranes and Dicobaltdiselenaboranes as Examples of Bimetallic Nido Structures without Bridging Hydrogens
Polyhedral Dicobaltadithiaboranes and Dicobaltdiselenaboranes as Examples of Bimetallic Nido Structures without Bridging Hydrogens Open
The geometries and energetics of the n-vertex polyhedral dicobaltadithiaboranes and dicobaltadiselenaboranes Cp2Co2E2Bn−4Hn−4 (E = S, Se; n = 8 to 12) have been investigated via the density functional theory. Most of the lowest-energy stru…
View article: Chemical Bonding Topology of Metal-Centered Polygonal Wheels: Two-Dimensional Analogues of Metallaboranes Related to Benzene and Cyclopentadienide
Chemical Bonding Topology of Metal-Centered Polygonal Wheels: Two-Dimensional Analogues of Metallaboranes Related to Benzene and Cyclopentadienide Open
The anion [Au@Ru5(CO)15(μ-CO)4]- has a pentagonal wheel structure that can be derived from a hypothetical pentagonal ruthenium carbonyl cluster Ru5(CO)20 by insertion of a g…
View article: Trivalent Polyhedra as Duals of Borane Deltahedra: From Molecular Endohedral Germanium Clusters to the Smallest Fullerenes
Trivalent Polyhedra as Duals of Borane Deltahedra: From Molecular Endohedral Germanium Clusters to the Smallest Fullerenes Open
The duals of the most spherical closo borane deltahedra having from 6 to 16 vertices form a series of homologous spherical trivalent polyhedra with even numbers of vertices from 8 to 28. This series of homologous polyhedra is found in endo…
View article: Effect of Phosphorus and Nitrogen Heteroatoms on Pentahapto Coordination of Diazaphospholyl Ligands in Binuclear Ruthenium and Iron Carbonyl Derivatives
Effect of Phosphorus and Nitrogen Heteroatoms on Pentahapto Coordination of Diazaphospholyl Ligands in Binuclear Ruthenium and Iron Carbonyl Derivatives Open
View article: Irradiance Monitoring and Capacity Testing of Bifacial PV Systems using Reference Modules .
Irradiance Monitoring and Capacity Testing of Bifacial PV Systems using Reference Modules . Open
View article: Perovskite PV Accelerator for Commercializing Technology (PACT).
Perovskite PV Accelerator for Commercializing Technology (PACT). Open
View article: Effective Irradiance Monitoring Using Reference Modules.
Effective Irradiance Monitoring Using Reference Modules. Open
the convolution of spectral response with solar irradiance are considered. The second is the most accurate technique.
View article: PACT Module Preconditioning Protocol (V.0.1)
PACT Module Preconditioning Protocol (V.0.1) Open
The purpose of this protocol is to bring metal halide perovskite (MHP) modules to a repeatable and relevant state prior to making a performance measurement. Performance measurements are made before and after a stressor has been applied to …
View article: A Randomized Crossover Trial Comparing Glucose Control During Moderate-Intensity, High-Intensity, and Resistance Exercise With Hybrid Closed-Loop Insulin Delivery While Profiling Potential Additional Signals in Adults With Type 1 Diabetes
A Randomized Crossover Trial Comparing Glucose Control During Moderate-Intensity, High-Intensity, and Resistance Exercise With Hybrid Closed-Loop Insulin Delivery While Profiling Potential Additional Signals in Adults With Type 1 Diabetes Open
Objective: To compare glucose control with hybrid closed loop (HCL) when challenged by moderate-intensity exercise (MIE), high-intensity intermittent exercise (HIE) and resistance exercise (RE) while profiling counter-regulatory hor…
View article: A Randomized Crossover Trial Comparing Glucose Control During Moderate-Intensity, High-Intensity, and Resistance Exercise With Hybrid Closed-Loop Insulin Delivery While Profiling Potential Additional Signals in Adults With Type 1 Diabetes
A Randomized Crossover Trial Comparing Glucose Control During Moderate-Intensity, High-Intensity, and Resistance Exercise With Hybrid Closed-Loop Insulin Delivery While Profiling Potential Additional Signals in Adults With Type 1 Diabetes Open
Objective: To compare glucose control with hybrid closed loop (HCL) when challenged by moderate-intensity exercise (MIE), high-intensity intermittent exercise (HIE) and resistance exercise (RE) while profiling counter-regulatory hor…
View article: BACKFLIP: A Comparison of Emerging Non-Fluoropolymer-Based, Co-Extruded PV Backsheets to Industry-Benchmark Technologies
BACKFLIP: A Comparison of Emerging Non-Fluoropolymer-Based, Co-Extruded PV Backsheets to Industry-Benchmark Technologies Open
As the photovoltaic (PV) industry is rapidly expanding around the world, there has been an increasing interest in extending the lifespan of PV modules. Concern has also emerged regarding the recyclability of modules and their component mat…
View article: Effects of Solar Angle of Incidence on Intramodular Photovoltaic Irradiance Uniformity.
Effects of Solar Angle of Incidence on Intramodular Photovoltaic Irradiance Uniformity. Open
View article: Tris(Butadiene) Compounds versus Butadiene Oligomerization in Second-Row Transition Metal Chemistry: Effects of Increased Ligand Fields
Tris(Butadiene) Compounds versus Butadiene Oligomerization in Second-Row Transition Metal Chemistry: Effects of Increased Ligand Fields Open
The geometries, energetics, and preferred spin states of the second-row transition metal tris(butadiene) complexes (C4H6)3M (M = Zr–Pd) and their isomers, including the experimentally known very stable molybdenum derivative (C4H6)3Mo, have…
View article: DuraMAT Fielded Module Study.
DuraMAT Fielded Module Study. Open
View article: Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of f Orbitals
Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of f Orbitals Open
The combination of atomic orbitals to form hybrid orbitals of special symmetries can be related to the individual orbital polynomials. Using this approach, 8-orbital cubic hybridization can be shown to be sp3d3f requiring an f orbital, and…
View article: Digital Life Norway AS IS Report
Digital Life Norway AS IS Report Open
This is the first report in a project called “A roadmap for academic research-intensive innovation”, commissioned on behalf of the Digital Life Norway (DLN) project by the University of Oslo. The project is in three parts. This report disc…