Rambabu Dandela
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View article: Green One‐Pot Strategy for the Direct Synthesis of Benzil
Green One‐Pot Strategy for the Direct Synthesis of Benzil Open
A practical and green methodology has been developed for the direct synthesis of arylated 1,2‐diketones from aldehydes utilizing 4 mol% of N ‐heterocyclic carbenes (NHC) organocatalysts and activated carbon. The design of this method is a …
View article: Self‐Supported CuO/Bi Heterostructure for Electroreduction of CO<sub>2</sub> to Formate by Synergistic Electronic Effects
Self‐Supported CuO/Bi Heterostructure for Electroreduction of CO<sub>2</sub> to Formate by Synergistic Electronic Effects Open
Tuning product distribution in CO 2 electroreduction (CO 2 RR) using Cu–Bi based bimetallic catalysts is a key strategy for enhancing selectivity and reaction kinetics. Notably, self‐supported bimetallic electrocatalysts derived from mesop…
View article: Catalytic Reforming of PET Plastic Waste for Efficient Hydrogen Production Using Bifunctional Ru Catalyst
Catalytic Reforming of PET Plastic Waste for Efficient Hydrogen Production Using Bifunctional Ru Catalyst Open
Emerging strategies for enacting various transformations from plastic waste may enable us to dispose of polyethylene terephthalate (PET) waste sustainably. Realizing the demand for a practical approach to accelerate waste‐to‐fuel conversio…
View article: Advancements in the Synthesis of Oxadiazines, Mechanistic insights and Pathways
Advancements in the Synthesis of Oxadiazines, Mechanistic insights and Pathways Open
Oxadiazine has the distinctive structure of a six‐membered heterocyclic ring with two nitrogen and one oxygen atoms. This molecule has lately gained substantial attention due to its promising uses in several sectors, including medicines, a…
View article: Combating antibiotic resistance: mechanisms, challenges, and innovative approaches in antibacterial drug development
Combating antibiotic resistance: mechanisms, challenges, and innovative approaches in antibacterial drug development Open
Antibiotic resistance is a significant threat to public health and drug development, driven largely by the overuse and misuse of antibiotics in medical and agricultural settings. As bacteria adapt to evade current drugs, managing bacterial…
View article: Novel synthesis and anti-pathogenic properties of ensifentrine and its intermediates against <i>Pseudomonas aeruginosa</i>
Novel synthesis and anti-pathogenic properties of ensifentrine and its intermediates against <i>Pseudomonas aeruginosa</i> Open
Chronic obstructive pulmonary disease (COPD) is a progressive respiratory disorder marked by persistent lung inflammation and airway constriction.
View article: Single step site-selective reaction to construct a Ag <sub>2</sub> Au <sub>2</sub> ← Ag <sub>4</sub> supramolecular assembly from hybrid N-heterocyclic carbene (NHC): synthesis, structures and optoelectronic properties
Single step site-selective reaction to construct a Ag <sub>2</sub> Au <sub>2</sub> ← Ag <sub>4</sub> supramolecular assembly from hybrid N-heterocyclic carbene (NHC): synthesis, structures and optoelectronic properties Open
A novel site-selective transmetallation strategy was developed to convert a Ag 4 metallosupramolecular assembly into an NHC-stabilized Ag 2 Au 2 heterometallic complex. The optoelectronic properties of the resulting complexes were explored.
View article: Boron appended Ru-NHC catalyzed selective deoxygenative hydrogenation of tertiary amides and desulfurization of thioamides
Boron appended Ru-NHC catalyzed selective deoxygenative hydrogenation of tertiary amides and desulfurization of thioamides Open
A Lewis acidic boron arm appended Ru-NHC complex is utilized for the selective deoxygenative hydrogenation of tertiary amides and desulfurization of thioamides to amines using phenylsilane as a reductant.
View article: Iodine/TBHP‐Promoted Cross Coupling of <i>N</i> ‐Hydroxy Aryl Sulfonamides and Disulfides to Synthesize Unsymmetrical Thiosulfonates
Iodine/TBHP‐Promoted Cross Coupling of <i>N</i> ‐Hydroxy Aryl Sulfonamides and Disulfides to Synthesize Unsymmetrical Thiosulfonates Open
An efficient and novel method has been developed for the synthesis of structurally diverse unsymmetrical thiosulfonates via the oxidative coupling reactions of N ‐hydroxy aryl sulfonamides and disulfides. The iodine and TBHP system enables…
View article: Mechanochemical Synthesis of Phosphoryl Amides and Esters from Diphenylphosphoryl Azides Under Mild Conditions
Mechanochemical Synthesis of Phosphoryl Amides and Esters from Diphenylphosphoryl Azides Under Mild Conditions Open
A simple, efficient, and one‐step synthetic procedure to construct phosphoryl amides and esters has been developed applying mechanochemistry. A ball‐milling technique easily facilitated the amination and esterification of diphenylphosphory…
View article: Zinc‐Catalysed (3+2) Cycloaddition of Enaminone with Tosylhydrazide to Synthesise 1<i>H</i>‐Pyrazole via C−N and S−N Bond Cleavage
Zinc‐Catalysed (3+2) Cycloaddition of Enaminone with Tosylhydrazide to Synthesise 1<i>H</i>‐Pyrazole via C−N and S−N Bond Cleavage Open
A novel and practical zinc‐catalysed synthesis of 1 H ‐pyrazole has been developed. The one‐pot protocol enables the cycloaddition of enaminone and tosylhydrazide via C−N and S−N bond breaking process, leading to diverse mono‐substituted p…
View article: New Binary Adducts of Panobinostat with Different Carboxylic Acid Based NSAIDs: Structural Analysis and Physicochemical Properties Investigation
New Binary Adducts of Panobinostat with Different Carboxylic Acid Based NSAIDs: Structural Analysis and Physicochemical Properties Investigation Open
Adoption of multitarget, cost‐effective fixed‐dose medication combinations can help lower the pill load without increasing the risk of adverse events. In this study, three new 1:1 drug‐drug binary solid forms of panobinostat (PNB) and nons…
View article: NaIO4/NH2OH-mediated Efficient Synthesis of Phosphoroamidates from Anilines and Triethyl Phosphite
NaIO4/NH2OH-mediated Efficient Synthesis of Phosphoroamidates from Anilines and Triethyl Phosphite Open
A simple, efficient, and metal-free method was developed for the synthesis of phosphoroamidates. In essence, a mixture of sodium periodate (NaIO4) and hydroxylamine (NH2OH⸱HCl) was used in stoichiometric amounts to execute the phosphoramid…
View article: An alternative synthetic strategy to construct apixaban analogues
An alternative synthetic strategy to construct apixaban analogues Open
An alternate synthetic approach has been described to access novel apixaban analogues.The present strategy offers a practical and cost-effective synthetic procedure to construct the privileged scaffold and its amide derivatives that may ex…
View article: Solar-Assisted Green Synthesis, Molecular Docking, Antibacterial, and Cytotoxicity Studies of Symmetrical N, N’-Alkylidene Bisamides Bearing Lower E-Factors
Solar-Assisted Green Synthesis, Molecular Docking, Antibacterial, and Cytotoxicity Studies of Symmetrical N, N’-Alkylidene Bisamides Bearing Lower E-Factors Open
N, N'-alkylidene bisamides show promise in biological and pharmaceutical uses. Advanced chemistry now explores cleaner and more environmentally friendly methods. One such method involves using concentrated solar radiation (CSR) to fac…
View article: CCDC 2323277: Experimental Crystal Structure Determination
CCDC 2323277: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2323276: Experimental Crystal Structure Determination
CCDC 2323276: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2323273: Experimental Crystal Structure Determination
CCDC 2323273: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2323275: Experimental Crystal Structure Determination
CCDC 2323275: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2201908: Experimental Crystal Structure Determination
CCDC 2201908: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2201907: Experimental Crystal Structure Determination
CCDC 2201907: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2201904: Experimental Crystal Structure Determination
CCDC 2201904: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Mechanical approach for creating different molecular adducts and regulating salt polymorphs: a case study of the anti-inflammatory medication ensifentrine
Mechanical approach for creating different molecular adducts and regulating salt polymorphs: a case study of the anti-inflammatory medication ensifentrine Open
An intriguing technique for crystal engineering is mechanochemistry. In this regard, several novel molecular adducts of ensifentrine with various GRAS co-formers were synthesised for the first time utilising a mechanochemical technique.
View article: CCDC 2271336: Experimental Crystal Structure Determination
CCDC 2271336: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2290962: Experimental Crystal Structure Determination
CCDC 2290962: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Ammonia synthesis by the reductive N–N bond cleavage of hydrazine using an air-stable, phosphine-free ruthenium catalyst
Ammonia synthesis by the reductive N–N bond cleavage of hydrazine using an air-stable, phosphine-free ruthenium catalyst Open
An air-stable, phosphine-free ruthenium-based molecular catalyst is developed for the efficient reduction of hydrazine to ammonia using suitable reductant and proton pairs.