R. Tucoulou
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View article: From P3 to P2: Synthesis and Role of Morphology in Li-Substituted Layered Oxides for Na-Ion Batteries
From P3 to P2: Synthesis and Role of Morphology in Li-Substituted Layered Oxides for Na-Ion Batteries Open
International audience
View article: The crystalline properties of silica biomorphs vary within and between morphologies
The crystalline properties of silica biomorphs vary within and between morphologies Open
Silica-carbonate biomorphs are a class of emergent materials, i.e. composite microstructures made of nanometric carbonate crystallites surrounded by amorphous silica. They form via a co-precipitation process in an interplay between alkalin…
View article: Deciphering the nature of secondary Ag S species in soils polluted with Ag nanoparticles
Deciphering the nature of secondary Ag S species in soils polluted with Ag nanoparticles Open
International audience
View article: Nanoscale distribution of potentially toxic elements in seaweeds revealed by synchrotron X-ray fluorescence
Nanoscale distribution of potentially toxic elements in seaweeds revealed by synchrotron X-ray fluorescence Open
View article: In Operando Study of Microsupercapacitors with Gel Electrolytes Using Nano‐Beam Synchrotron X‐ray Diffraction
In Operando Study of Microsupercapacitors with Gel Electrolytes Using Nano‐Beam Synchrotron X‐ray Diffraction Open
Synchrotron radiation X‐ray diffraction (XRD) with nanoscale beam size was used here for in situ and in operando study of micro‐supercapacitors (MSC) with gel electrolyte and MXene Ti 3 C 2 T x electrodes. The electrode structure was chara…
View article: Ca-oxalate crystals are involved in cadmium storage in a high Cd accumulating cultivar of cacao
Ca-oxalate crystals are involved in cadmium storage in a high Cd accumulating cultivar of cacao Open
View article: Unraveling the synergistic effects of Cu-Ag tandem catalysts during electrochemical CO2 reduction using nanofocused X-ray probes
Unraveling the synergistic effects of Cu-Ag tandem catalysts during electrochemical CO2 reduction using nanofocused X-ray probes Open
View article: X ray nanoprobe for fault attacks and circuit edits on 28-nm integrated circuits
X ray nanoprobe for fault attacks and circuit edits on 28-nm integrated circuits Open
Ionizing radiations pose risks to Integrated Circuits (ICs) in space devices and nuclear reactors, but their effects are mitigated by specific designs and redundancy. Besides characterizing radiation faults, X-rays can be intentionally use…
View article: Observation of long-range anisotropy in a vapor-deposited metallic glass
Observation of long-range anisotropy in a vapor-deposited metallic glass Open
View article: Deciphering silver nanoparticle fate in liver up to biliary excretion using HepG2/C3A spheroids in scenarios mimicking different exposure pathways
Deciphering silver nanoparticle fate in liver up to biliary excretion using HepG2/C3A spheroids in scenarios mimicking different exposure pathways Open
This study probes the exposure route-dependent fate of silver nanoparticles by using a 3D cell model mimicking the liver. It reveals the cellular trafficking and transformation of silver species, up to their storage in vacuoles or biliary …
View article: Evidence of manganese incorporation and distribution at the nanoscale in coccolithophore calcite
Evidence of manganese incorporation and distribution at the nanoscale in coccolithophore calcite Open
The coccolithophore algae (Calcihaptophycidae) produce an extracellular covering of calcium carbonate plates (coccoliths) and are responsible for up to 10% of global carbon fixation through photosynthesis and biomineralization. Therefore, …
View article: Synchrotron-based characterization of arthroprosthetic CoCrMo particles in human bone marrow
Synchrotron-based characterization of arthroprosthetic CoCrMo particles in human bone marrow Open
Particles released from cobalt-chromium-molybdenum (CoCrMo) alloys are considered common elicitors of chronic inflammatory adverse effects. There is a lack of data demonstrating particle numbers, size distribution and elemental composition…
View article: Chemical analysis of trace elements at the nanoscale in samples recovered from laser-heated diamond anvil cell experiments
Chemical analysis of trace elements at the nanoscale in samples recovered from laser-heated diamond anvil cell experiments Open
View article: Chemical Analysis of Trace Elements at the Nanoscale in Samples Recovered from Laser-Heated Diamond Anvil Cell Experiments
Chemical Analysis of Trace Elements at the Nanoscale in Samples Recovered from Laser-Heated Diamond Anvil Cell Experiments Open
<p>High pressure and high temperature experiments performed with laser-heated diamond anvil cells (LH-DAC) are being extensively used in geosciences in order to study matter at conditions prevailing in planetary interiors. Due to the…
View article: Evidence of high Sr/Ca in a Middle Jurassic murolith coccolith species
Evidence of high Sr/Ca in a Middle Jurassic murolith coccolith species Open
Paleoceanographical reconstructions are often based on microfossil geochemical analyses. Coccoliths are the most ancient, abundant and continuous record of pelagic photic zone calcite producer organisms. Hence, they could be valuable subst…
View article: Development of a multi-method analytical approach based on the combination of synchrotron radiation X-ray micro-analytical techniques and vibrational micro-spectroscopy methods to unveil the causes and mechanism of darkening of “fake-gilded” decorations in a Cimabue painting
Development of a multi-method analytical approach based on the combination of synchrotron radiation X-ray micro-analytical techniques and vibrational micro-spectroscopy methods to unveil the causes and mechanism of darkening of “fake-gilded” decorations in a Cimabue painting Open
Synchrotron radiation X-ray micro-analytical techniques and vibrational micro-spectroscopy methods were used to establish the factors and mechanism of darkening of “fake-gilded” decorations in the Maestà by Cimabue and aged paint mock-ups.
View article: Subcellular architecture and metabolic connection in the planktonic photosymbiosis between Collodaria (radiolarians) and their microalgae
Subcellular architecture and metabolic connection in the planktonic photosymbiosis between Collodaria (radiolarians) and their microalgae Open
Summary Photosymbiosis is widespread and ecologically important in the oceanic plankton but remains poorly studied. Here, we used multimodal subcellular imaging to investigate the photosymbiosis between colonial Collodaria and their microa…
View article: Cellular remains in a ~3.42-billion-year-old subseafloor hydrothermal environment
Cellular remains in a ~3.42-billion-year-old subseafloor hydrothermal environment Open
Oldest microfossils with methane-based metabolism in a subsurface environment expand the frontiers of early Earth habitability.
View article: Correlative transmission electron microscopy and high-resolution hard X-ray fluorescence microscopy of cell sections to measure trace element concentrations at the organelle level
Correlative transmission electron microscopy and high-resolution hard X-ray fluorescence microscopy of cell sections to measure trace element concentrations at the organelle level Open
View article: Adorym: a multi-platform generic X-ray image reconstruction framework based on automatic differentiation
Adorym: a multi-platform generic X-ray image reconstruction framework based on automatic differentiation Open
We describe and demonstrate an optimization-based X-ray image reconstruction framework called Adorym. Our framework provides a generic forward model, allowing one code framework to be used for a wide range of imaging methods ranging from n…
View article: 3D Quantification of Microstructural Properties of LiNi<sub>0.5</sub>Mn<sub>0.3</sub>Co<sub>0.2</sub>O<sub>2</sub> High‐Energy Density Electrodes by X‐Ray Holographic Nano‐Tomography
3D Quantification of Microstructural Properties of LiNi<sub>0.5</sub>Mn<sub>0.3</sub>Co<sub>0.2</sub>O<sub>2</sub> High‐Energy Density Electrodes by X‐Ray Holographic Nano‐Tomography Open
Despite significant progress in the field of tomography, capturing the carbon binder domain (CBD) morphology presented in the Li‐ion electrode remains challenging, due to its low attenuation coefficient. In this work, quantitative phase co…
View article: New results and challenges in Sr/Ca studies on Jurassic coccolithophorids
New results and challenges in Sr/Ca studies on Jurassic coccolithophorids Open
A recommendation of: Suchéras-Marx B, Giraud F, Simionovici A, Tucoulou R, and Daniel I (2020). Evidence of high Sr/Ca in a Middle Jurassic murolith coccolith species. PaleorXiv, dcfuq, version 7, peer-reviewed by PCI Pale…
View article: Relationship Between Hg Speciation and Hg Methylation/Demethylation Processes in the Sulfate-Reducing Bacterium Pseudodesulfovibrio hydrargyri: Evidences From HERFD-XANES and Nano-XRF
Relationship Between Hg Speciation and Hg Methylation/Demethylation Processes in the Sulfate-Reducing Bacterium Pseudodesulfovibrio hydrargyri: Evidences From HERFD-XANES and Nano-XRF Open
Microorganisms are key players in the transformation of mercury into neurotoxic methylmercury (MeHg). Nevertheless, this mechanism and the opposite MeHg demethylation remain poorly understood. Here, we explored the impact of inorganic merc…
View article: Metal‐Specific Biomaterial Accumulation in Human Peri‐Implant Bone and Bone Marrow
Metal‐Specific Biomaterial Accumulation in Human Peri‐Implant Bone and Bone Marrow Open
Metallic implants are frequently used in medicine to support and replace degenerated tissues. Implant loosening due to particle exposure remains a major cause for revision arthroplasty. The exact role of metal debris in sterile peri‐implan…
View article: Evidence of high Sr/Ca in a Middle Jurassic murolith coccolith species
Evidence of high Sr/Ca in a Middle Jurassic murolith coccolith species Open
Paleoceanographical reconstructions are often based on microfossil geochemical analyses. Coccoliths are the most ancient, abundant and continuous record of pelagic photic zone calcite producer organisms. Hence, they could be valuable subst…
View article: Origin of manganese in nannofossil calcite based on synchrotron nanoXRF and XANES
Origin of manganese in nannofossil calcite based on synchrotron nanoXRF and XANES Open
Calcareous nannofossils are micrometric calcite platelets secreted by coccolithophores and incertae sedis photosynthetic algae. Calcareous nannoplankton inhabit the photic zone from coast to open-ocean and have left an abundant fossil reco…
View article: Subcellular Chemical Imaging: New Avenues in Cell Biology
Subcellular Chemical Imaging: New Avenues in Cell Biology Open
View article: Visualization of silver nanoparticle intracellular trafficking revealed nuclear translocation of silver ions leading to nuclear receptor impairment
Visualization of silver nanoparticle intracellular trafficking revealed nuclear translocation of silver ions leading to nuclear receptor impairment Open
The impact on human health of the increasing use of silver nanoparticles (AgNPs) in medical devices remains understudied, even though AgNP-containing dressings are known to release silver in the bloodstream leading to accumulation and slow…
View article: Distribution of nickel and chromium containing particles from tattoo needle wear in humans and its possible impact on allergic reactions
Distribution of nickel and chromium containing particles from tattoo needle wear in humans and its possible impact on allergic reactions Open
Previously, the virtually inevitable nickel contamination of iron pigments was suspected to be responsible for nickel-driven tattoo allergies. The evidence from our study clearly points to an additional entry of nickel to both skin and lym…
View article: Visualization of the Ionome in Planktonic Symbioses
Visualization of the Ionome in Planktonic Symbioses Open
Journal Article Visualization of the Ionome in Planktonic Symbioses Get access Johan Decelle, Johan Decelle Cell and Plant Physiology Laboratory – University of Grenoble Alpes, CNRS, CEA, INRA; Grenoble, France Corresponding author: johan.…