René Verel
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View article: Controlling the Mechanism of Nucleation and Growth Enables Synthesis of UiO‐66 Metal–Organic Framework with Desired Macroscopic Properties
Controlling the Mechanism of Nucleation and Growth Enables Synthesis of UiO‐66 Metal–Organic Framework with Desired Macroscopic Properties Open
By combining in situ X‐ray diffraction, Zr K‐edge X‐ray absorption spectroscopy and 1 H and 13 C nuclear magnetic resonance (NMR) spectroscopy, we show that the properties of the final MOF are influenced by H 2 O and HCl via affecting the …
View article: (Ph<sub>3</sub>P)<sub>4</sub>C<sub>4</sub>P<sub>4</sub>: Effect of substitution on the Oligomerization of carbon phosphide radicals
(Ph<sub>3</sub>P)<sub>4</sub>C<sub>4</sub>P<sub>4</sub>: Effect of substitution on the Oligomerization of carbon phosphide radicals Open
Dehalogenation of (PBr) 2 C 2 (PPh 3 ) 2 with potassium graphite, KC 8 , leads to C s ‐P 4 C 4 (PPh 3 ) 4 , which can be viewed as a PPh 3 adduct of a C s ‐symmetric P 4 C 4 cage. An isolable intermediate was found and in combination with …
View article: Structural Changes of ZSM-5 Catalysts during Methanol-to-Hydrocarbons Conversion Processes
Structural Changes of ZSM-5 Catalysts during Methanol-to-Hydrocarbons Conversion Processes Open
Industrial methanol-to-hydrocarbons (MTH) conversion processes comprise a series of reaction and regeneration stages performed at elevated temperatures and accompanied by steam generation. Although these conditions contribute to the progre…
View article: Disorder and Halide Distributions in Cesium Lead Halide Nanocrystals as Seen by Colloidal <sup>133</sup>Cs Nuclear Magnetic Resonance Spectroscopy
Disorder and Halide Distributions in Cesium Lead Halide Nanocrystals as Seen by Colloidal <sup>133</sup>Cs Nuclear Magnetic Resonance Spectroscopy Open
Colloidal nuclear magnetic resonance (cNMR) spectroscopy on inorganic cesium lead halide nanocrystals (CsPbX3 NCs) is found to serve for noninvasive characterization and quantification of disorder within these structurally soft and labile …
View article: CCDC 2259923: Experimental Crystal Structure Determination
CCDC 2259923: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2259924: Experimental Crystal Structure Determination
CCDC 2259924: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: 71Ga NMR Signatures of Lewis and Brønsted Acid Sites in Gallium Silicates Evidenced and Deciphered upon Interaction with Probe Molecules
71Ga NMR Signatures of Lewis and Brønsted Acid Sites in Gallium Silicates Evidenced and Deciphered upon Interaction with Probe Molecules Open
Determining the structure of Ga surface sites in Ga-based materials, used in catalysis, is critical for understanding their reactivity. However, obtaining molecular-level insights into their structure remains challenging. Here, using solid…
View article: CCDC 2093071: Experimental Crystal Structure Determination
CCDC 2093071: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2093073: Experimental Crystal Structure Determination
CCDC 2093073: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Selective Oxidative Dehydrogenation of Ethane and Propane over Copper‐Containing Mordenite: Insights into Reaction Mechanism and Product Protection
Selective Oxidative Dehydrogenation of Ethane and Propane over Copper‐Containing Mordenite: Insights into Reaction Mechanism and Product Protection Open
Copper(II)‐containing mordenite (CuMOR) is capable of activation of C−H bonds in C 1 ‐C 3 alkanes, albeit there are remarkable differences between the functionalization of ethane and propane compared to methane. The reaction of ethane and …
View article: Selective Oxidative Dehydrogenation of Ethane and Propane over Copper‐Containing Mordenite: Insights into Reaction Mechanism and Product Protection
Selective Oxidative Dehydrogenation of Ethane and Propane over Copper‐Containing Mordenite: Insights into Reaction Mechanism and Product Protection Open
Copper(II)‐containing mordenite (CuMOR) is capable of activation of C−H bonds in C 1 ‐C 3 alkanes, albeit there are remarkable differences between the functionalization of ethane and propane compared to methane. The reaction of ethane and …
View article: CCDC 2093075: Experimental Crystal Structure Determination
CCDC 2093075: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2093072: Experimental Crystal Structure Determination
CCDC 2093072: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Deciphering the Mechanism of Crystallization of UiO‐66 Metal‐Organic Framework
Deciphering the Mechanism of Crystallization of UiO‐66 Metal‐Organic Framework Open
Zirconium‐containing metal‐organic framework (MOF) with UiO‐66 topology is an extremely versatile material, which finds applications beyond gas separation and catalysis. However, after more than 10 years after the first reports introducing…
View article: 71Ga NMR Signatures of Lewis and Brønsted Acid Sites in Gallium Silicates Evidenced and Deciphered upon Interaction with Probe Molecules
71Ga NMR Signatures of Lewis and Brønsted Acid Sites in Gallium Silicates Evidenced and Deciphered upon Interaction with Probe Molecules Open
Determining the structure of Ga surface sites in Ga-based materials, used in catalysis, is critical for understanding their reactivity. However, obtaining molecular-level insights into their structure remains challenging. Here, using solid…
View article: CCDC 2234735: Experimental Crystal Structure Determination
CCDC 2234735: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2234733: Experimental Crystal Structure Determination
CCDC 2234733: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2234730: Experimental Crystal Structure Determination
CCDC 2234730: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2234731: Experimental Crystal Structure Determination
CCDC 2234731: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2234732: Experimental Crystal Structure Determination
CCDC 2234732: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2234734: Experimental Crystal Structure Determination
CCDC 2234734: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2234729: Experimental Crystal Structure Determination
CCDC 2234729: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: The coordination chemistry of 2,4,6-oxy functionalised 1,3,5-triphosphinines
The coordination chemistry of 2,4,6-oxy functionalised 1,3,5-triphosphinines Open
A comparison of nine stable 2,4,6-oxy functionalised 1,3,5-triphosphinine complexes [M{P 3 C 3 (OX) 3 }(CO) 3 ] with M = Cr(0), Mo(0), W(0) and X = H, SitBuPh 2 , B(ipc) 2 ] allows to investigate the binding properties of these heterocycle…
View article: CCDC 2050091: Experimental Crystal Structure Determination
CCDC 2050091: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2050097: Experimental Crystal Structure Determination
CCDC 2050097: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …