Ying‐Feng Han
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View article: Stable π‐Stacked Perylenediimide Radical Dimers for Efficient Photothermal Therapy
Stable π‐Stacked Perylenediimide Radical Dimers for Efficient Photothermal Therapy Open
Comprehensive Summary Perylenediimide (PDI) radical anions have been extensively investigated and applied in photothermal therapy. However, the current PDI radical anions show poor photothermal conversion efficiency owing to the intrinsic …
View article: Crystalline 90°‐Twisted Carbon‐Centered Non‐Kekulé Diradical Derived from N‐Heterocyclic Carbene
Crystalline 90°‐Twisted Carbon‐Centered Non‐Kekulé Diradical Derived from N‐Heterocyclic Carbene Open
Diradicals, molecules with two unpaired electrons, are crucial for understanding chemical reaction mechanisms, bond formation, and bond dissociation. Beyond their fundamental importance, they are increasingly studied for potential applicat…
View article: Hierarchical, Template‐Controlled Self‐Assembly of Two Different Organometallic Capsules from a Tetrakisimidazolium Salt
Hierarchical, Template‐Controlled Self‐Assembly of Two Different Organometallic Capsules from a Tetrakisimidazolium Salt Open
Controlling the assembly of molecular nanocapsules through metal‐carbon bonds constitutes a major challenge in the field of supramolecular organometallic chemistry. Here, we demonstrate the construction of two nanosized dodecanuclear organ…
View article: <i>Endo</i>-functionalization of tailored-adaptive nanospace for efficient binding of organic molecules in non-aqueous media
<i>Endo</i>-functionalization of tailored-adaptive nanospace for efficient binding of organic molecules in non-aqueous media Open
Precision in controlling the microenvironment of nanospaces is a potent strategy for exploring architecture‒function relationships. Herein, a face-capped tetrahedral cage, featuring Pd‒Pd-bonded vertices, with a tailored nanospace surround…
View article: Study on the Impact of Intellectual Property Law Differences on Chinese Infrastructure Enterprises along the "Belt and Road" Route
Study on the Impact of Intellectual Property Law Differences on Chinese Infrastructure Enterprises along the "Belt and Road" Route Open
This paper studies the impact of the differences in intellectual property laws of countries along the "Belt and Road" on the internationalization of Chinese infrastructure enterprises. Firstly, it discusses the intellectual property challe…
View article: Achieving a Record Photoluminescence Quantum Yield in Green Light‐Emitting Carbon‐Centered Radicals with Nanosecond Emission Lifetimes
Achieving a Record Photoluminescence Quantum Yield in Green Light‐Emitting Carbon‐Centered Radicals with Nanosecond Emission Lifetimes Open
Organic luminescent radicals possess considerable potential for applications in organic light‐emitting diodes (OLEDs)‐based visible light communication owing to their intrinsic advantages of nanosecond emission lifetimes and spin‐allowed r…
View article: China's Full Liberalization of the Three-child Legal System: From the Perspective of Women's Basic Rights
China's Full Liberalization of the Three-child Legal System: From the Perspective of Women's Basic Rights Open
With the increasing aging of China's society, the proportion of labor force population has declined, and the burden of social pension has increased, posing challenges to sustainable economic and social development. Therefore, the country h…
View article: Sensitivity Analysis of Influencing Factors of Vertical Bearing Capacity of Rock-Socketed Piles Based on Orthogonal Test
Sensitivity Analysis of Influencing Factors of Vertical Bearing Capacity of Rock-Socketed Piles Based on Orthogonal Test Open
In order to investigate the sensitivity of influencing factors of rock-socketed piles’ vertical bearing capability. The field static load test of embedded rock piles was performed in the article, and the pile-soil interaction model was bui…
View article: Stimuli-Responsive Interconversion between Poly-NHC-Based Organometallic Assemblies and Their Self-Aggregated Dimers
Stimuli-Responsive Interconversion between Poly-NHC-Based Organometallic Assemblies and Their Self-Aggregated Dimers Open
Poly-NHC-based organometallic assemblies 3-PF6, 3-SbF6 and 3-OTf were obtained and verified by NMR spectroscopy, ESI mass spec-trometry and single-crystal X-ray diffraction analyses. Controllable structural interconversion was observed bet…
View article: Prediction of ultimate bearing capacity of rock-socketed piles based on GWO-SVR algorithm
Prediction of ultimate bearing capacity of rock-socketed piles based on GWO-SVR algorithm Open
The application of rock-socketed pile in engineering is becoming ever more common. Finding the ultimate bearing capacity of rock-socketed piles with a high-performance ratio and precision is an important area of research. The rock-socketed…
View article: CCDC 2264412: Experimental Crystal Structure Determination
CCDC 2264412: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Unravelling the Roles of Solvophobic Effects and π⋅⋅⋅π Stacking Interactions in the Formation of [2]Catenanes Featuring Di‐(N‐Heterocyclic Carbene) Building Blocks
Unravelling the Roles of Solvophobic Effects and π⋅⋅⋅π Stacking Interactions in the Formation of [2]Catenanes Featuring Di‐(N‐Heterocyclic Carbene) Building Blocks Open
A series of [2]catenanes has been prepared from di‐NHC building blocks by utilizing solvophobic effects and/or π⋅⋅⋅π stacking interactions. The dinickel naphthobiscarbene complex syn ‐[ 1 ] and the kinked biphenyl‐bridged bipyridyl ligand …
View article: Unravelling the Roles of Solvophobic Effects and π⋅⋅⋅π Stacking Interactions in the Formation of [2]Catenanes Featuring Di‐(N‐Heterocyclic Carbene) Building Blocks
Unravelling the Roles of Solvophobic Effects and π⋅⋅⋅π Stacking Interactions in the Formation of [2]Catenanes Featuring Di‐(N‐Heterocyclic Carbene) Building Blocks Open
A series of [2]catenanes has been prepared from di‐NHC building blocks by utilizing solvophobic effects and/or π⋅⋅⋅π stacking interactions. The dinickel naphthobiscarbene complex syn ‐[ 1 ] and the kinked biphenyl‐bridged bipyridyl ligand …
View article: CCDC 2241329: Experimental Crystal Structure Determination
CCDC 2241329: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2241332: Experimental Crystal Structure Determination
CCDC 2241332: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2241330: Experimental Crystal Structure Determination
CCDC 2241330: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2241331: Experimental Crystal Structure Determination
CCDC 2241331: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2241328: Experimental Crystal Structure Determination
CCDC 2241328: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2114574: Experimental Crystal Structure Determination
CCDC 2114574: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2114572: Experimental Crystal Structure Determination
CCDC 2114572: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Highly Efficient Circularly Polarized Luminescence from Chiral Au<sub>13</sub> Clusters Stabilized by Enantiopure Monodentate NHC Ligands
Highly Efficient Circularly Polarized Luminescence from Chiral Au<sub>13</sub> Clusters Stabilized by Enantiopure Monodentate NHC Ligands Open
Chiral Au nanoclusters have promising application prospects in chiral sensing, asymmetric catalysis, and chiroptics. However, enantiopure superatomic homogold clusters with crystallographic structures emitting bright circularly polarized l…
View article: CCDC 1976920: Experimental Crystal Structure Determination
CCDC 1976920: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis of triarylborane-centered N-heterocyclic carbene cages with tunable photophysical properties
Synthesis of triarylborane-centered N-heterocyclic carbene cages with tunable photophysical properties Open
A discrete hexacarbene cage [Au 3 (1) 2 ](PF 6 ) 3 containing Lewis acidic triarylborane-bridged NHC ligands was synthesized, which shows reversible binding of fluorides.
View article: Synthesis and Optical Property Studies of Blue-Light Organic Radicals Based on N-Heterocyclic Carbenes<sup>★</sup>
Synthesis and Optical Property Studies of Blue-Light Organic Radicals Based on N-Heterocyclic Carbenes<sup>★</sup> Open
摘要 发光自由基因同时具有发光、导电、顺磁、可逆的氧化还原等特性, 使其在有机光电领域具有广阔的应用前景.然而, 目前已报道的发光自由基通常具有窄的最高占据轨道(HOMO)-单电子占据轨道(SOMO)能隙且分子结构单一, 因此发光颜色主要集中在橙色、红色等可见光的长波范围, 难以获得具有蓝色发射的自由基.为进一步丰富发光自由 基的种类、拓宽自由基的发光范围
View article: CCDC 2156771: Experimental Crystal Structure Determination
CCDC 2156771: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …