Robert A. Binstead
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View article: Base-enhanced catalytic water oxidation by a carboxylate–bipyridine Ru(II) complex
Base-enhanced catalytic water oxidation by a carboxylate–bipyridine Ru(II) complex Open
Development of rapid, robust water oxidation catalysts remains an essential element in solar water splitting by artificial photosynthesis. We report here dramatic rate enhancements with added buffer bases for a robust Ru(II) polypyridyl ca…
View article: Pathways Following Electron Injection: Medium Effects and Cross-Surface Electron Transfer in a Ruthenium-Based, Chromophore–Catalyst Assembly on TiO<sub>2</sub>
Pathways Following Electron Injection: Medium Effects and Cross-Surface Electron Transfer in a Ruthenium-Based, Chromophore–Catalyst Assembly on TiO<sub>2</sub> Open
Interfacial dynamics following photoexcitation of the water oxidation assembly [((PO3H2)2bpy)2RuII(bpy-bimpy)RuII(tpy)(OH2)]4+, -[RuaII–RubII–OH2]4+, on nanocrystalline TiO2 electrodes, starting from either -[RuaII–RubII–OH2]4+ or -[RuaII–…
View article: Visible Photoelectrochemical Water Splitting Based on a Ru(II) Polypyridyl Chromophore and Iridium Oxide Nanoparticle Catalyst
Visible Photoelectrochemical Water Splitting Based on a Ru(II) Polypyridyl Chromophore and Iridium Oxide Nanoparticle Catalyst Open
Preparation of Ru(II) polypyridyl-iridium oxide nanoparticle (IrOX NP) chromophore-catalyst assemblies on an FTO$|nano$ITO$|$TiO2 core/shell by a layer-bylayer procedure is described for application in dye-sensitized photoelectrosynthesis …
View article: Base-enhanced catalytic water oxidation by a carboxylate–bipyridine Ru(II) complex
Base-enhanced catalytic water oxidation by a carboxylate–bipyridine Ru(II) complex Open
Significance Development of rapid, robust water oxidation catalysts remains an essential element in solar water splitting by artificial photosynthesis. We report here dramatic rate enhancements with added buffer bases for a robust Ru(II) p…