Robert Herzhoff
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View article: Dynamics of disorder in mixed ionic–electronic transport in cross-linked non-conjugated redox polymers
Dynamics of disorder in mixed ionic–electronic transport in cross-linked non-conjugated redox polymers Open
The coupled electronic and ionic transport mechanisms in organic mixed ionic–electronic conductors (OMIECs) remain elusive to rationalize.
View article: Thiolate-CLPG (chemiluminescent protecting groups) based on coumaranone thiolcarbamates
Thiolate-CLPG (chemiluminescent protecting groups) based on coumaranone thiolcarbamates Open
Coumaranone thiolcarbamates release thiolates with concomitant and long-lasting blue-green chemiluminescence and are excellent examples of chemiluminescent protecting groups (CLPG) that can be detected until complete conversion.
View article: Impact of static and dynamic disorder effects on the charge transport properties of merocyanine single crystals
Impact of static and dynamic disorder effects on the charge transport properties of merocyanine single crystals Open
Static and dynamic disorder effects impact the charge transport properties of merocyanine single crystals. While thermal disorder enhances the hole transfer rates, polarization phenomena lower the hole mobility and modify the transport top…
View article: 5-Chlorocoumaranone-Conjugates as Chemiluminescent Protecting Groups (CLPG) and Precursors to Fluorescent Protecting Groups (FPG)
5-Chlorocoumaranone-Conjugates as Chemiluminescent Protecting Groups (CLPG) and Precursors to Fluorescent Protecting Groups (FPG) Open
The introduction and cleavage of protecting groups and the subsequent release of protected molecules is an important tool in synthetic organic chemistry. When polyfunctionalized substrates are involved, the reactivity of similar functional…
View article: Revealing the interplay between the structural complexity of triphenylamine redox derivatives and their charge transport processes <i>via</i> computational modeling
Revealing the interplay between the structural complexity of triphenylamine redox derivatives and their charge transport processes <i>via</i> computational modeling Open
Triphenylamine derivatives (TPAs) are known for their semiconducting charge transport and redox properties. We explore computationally the charge transport processes in amorphous and single crystalline phases of four different TPAs.