R. Bruce King
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View article: Changes to care delivery at nine international pediatric diabetes clinics in response to the COVID‐19 global pandemic
Changes to care delivery at nine international pediatric diabetes clinics in response to the COVID‐19 global pandemic Open
BACKGROUND: Pediatric diabetes clinics around the world rapidly adapted care in response to COVID-19. We explored provider perceptions of care delivery adaptations and challenges for providers and patients across nine international pediatr…
View article: High-spin face-capped deltahedra in divanadadicarbaboranes are very different from the singlet structures of chromium analogues
High-spin face-capped deltahedra in divanadadicarbaboranes are very different from the singlet structures of chromium analogues Open
The low-energy structures of divanadadicarbaboranes Cp 2 V 2 C 2 B n −4 H n −2 have triplet or quintet spin states in contrast to the singlet low-energy structures of dichromadicarbaboranes Cp 2 Cr 2 C 2 B n −4 H n −2 .
View article: Alkyne dichotomy and hydrogen migration in binuclear cyclopentadienylmetal alkyne complexes
Alkyne dichotomy and hydrogen migration in binuclear cyclopentadienylmetal alkyne complexes Open
Low-energy (Me 2 N) 2 C 2 M 2 (C 5 H 5 ) 2 (M = Ni, Co, Fe) structures have central Mn 2 C 2 tetrahedrane units or separate bridging Me 2 NC carbyne units. However, low-energy (Me 2 NC 2 Me)M 2 (C 5 H 5 ) 2 and Me 2 C 2 M 2 (C 5 H 5 ) 2 st…
View article: Ring Size Effects on the Structures of Sandwich Compounds with a Stoichiometry of C<sub>12</sub>H<sub>12</sub>M (M = Ti–Ni)
Ring Size Effects on the Structures of Sandwich Compounds with a Stoichiometry of C<sub>12</sub>H<sub>12</sub>M (M = Ti–Ni) Open
Ring size effects on geometries and electronic structures were investigated for the (C n H n )M(C m H m ) (n = 4, 5, or 6; m = 8, 7, or 6; m + n = 12; M = Ti-Ni) systems using density functional theory. The lowest-energy C12H12M structures…
View article: Iron Carbonyl Complexes of [2.2.2]Hericene as a Rigid Tris(1,3-diene) Ligand
Iron Carbonyl Complexes of [2.2.2]Hericene as a Rigid Tris(1,3-diene) Ligand Open
Hericene is an unusual hexaolefin consisting of three 1,3-diene units located on a rigid bicyclo [2.2.2]octane framework that restricts the geometrical relationships of metal atoms bonded to these olefinic units. In order to explore possib…
View article: Trinuclear and Tetranuclear Ruthenium Carbonyl Nitrosyls: Oxidation of a Carbonyl Ligand by an Adjacent Nitrosyl Ligand
Trinuclear and Tetranuclear Ruthenium Carbonyl Nitrosyls: Oxidation of a Carbonyl Ligand by an Adjacent Nitrosyl Ligand Open
Trinuclear and tetranuclear ruthenium carbonyls of the types Ru3(CO)n(NO)2, Ru3(N)(CO)n(NO), Ru3(N)2(CO)n, Ru3(N)(CO)n(NCO), Ru3(CO)n(NCO)(NO), Ru4(N)(CO)n(NO), Ru4(N)(CO)n(NCO), and Ru4(N)2(CO)n related to species observed experimentally …
View article: Decarbonylation Products of Binuclear Methylphosphinidene Complexes of Cyclopentadienyliron Carbonyls: Triplet and Quintet Structures Are Favored Energetically over Singlet Structures with Iron–Iron Multiple Bonding
Decarbonylation Products of Binuclear Methylphosphinidene Complexes of Cyclopentadienyliron Carbonyls: Triplet and Quintet Structures Are Favored Energetically over Singlet Structures with Iron–Iron Multiple Bonding Open
The structures, energetics, and energetically preferred spin states of methylphosphinidene-bridged binuclear cyclopentadienyliron carbonyl complexes MePFe2(CO)nCp2 (n = 4, 3, 2, and 1) related to the experimentally known (μ-RP)Fe2(μ-CO)(CO…
View article: Binuclear methylphosphinidine complexes of cyclopentadienylruthenium carbonyls: effects of the higher ligand field strength of ruthenium derivatives relative to iron derivatives
Binuclear methylphosphinidine complexes of cyclopentadienylruthenium carbonyls: effects of the higher ligand field strength of ruthenium derivatives relative to iron derivatives Open
The structures and energetics of the binuclear methylphosphinidene complexes of cyclopentadienylruthenium carbonyls of the type [MePRu 2 (CO) n Cp 2 ] ( n = 4, 3, 2, 1) have been investigated for comparison with their previously studied ir…
View article: Systematics of stable copper and silver clusters protected by small bite chelating bidentate sulfur and selenium ligands related to their polyhedral cavities: analogies to aliphatic compounds and three-dimensional spherical aromatic systems
Systematics of stable copper and silver clusters protected by small bite chelating bidentate sulfur and selenium ligands related to their polyhedral cavities: analogies to aliphatic compounds and three-dimensional spherical aromatic systems Open
Silver clusters composed exclusively of fused tetrahedra are analogous to simple saturated organic compounds. Copper clusters with central cuboctahedra and silver clusters with central icosahedra having interstitial metal atoms provide exa…
View article: Unraveling the Major Differences between the Trinuclear Cyclopentadienylmetal Carbonyl Chemistry of Cobalt and That of Nickel─A Theoretical Study
Unraveling the Major Differences between the Trinuclear Cyclopentadienylmetal Carbonyl Chemistry of Cobalt and That of Nickel─A Theoretical Study Open
The geometries and energetics of the trinuclear cyclopentadienylmetal carbonyls Cp3M3(CO)n (Cp = η5-C5H5); M = Co, Ni; n = 3, 2, 1, 0) have been investigated by density functional theory. The cobalt and nickel systems are found to be rathe…
View article: PACT Perovskite PV Module Outdoor Test Protocol (Version 0.1)
PACT Perovskite PV Module Outdoor Test Protocol (Version 0.1) Open
The purpose of this protocol is to define procedures and practices to be used by the PACT center for field testing of metal halide perovskite (MHP) photovoltaic (PV) modules. The protocol defines the physical, electrical, and analytical co…
View article: Polyhedral Dicobaltadithiaboranes and Dicobaltdiselenaboranes as Examples of Bimetallic Nido Structures without Bridging Hydrogens
Polyhedral Dicobaltadithiaboranes and Dicobaltdiselenaboranes as Examples of Bimetallic Nido Structures without Bridging Hydrogens Open
The geometries and energetics of the n-vertex polyhedral dicobaltadithiaboranes and dicobaltadiselenaboranes Cp2Co2E2Bn−4Hn−4 (E = S, Se; n = 8 to 12) have been investigated via the density functional theory. Most of the lowest-energy stru…
View article: Chemical Bonding Topology of Metal-Centered Polygonal Wheels: Two-Dimensional Analogues of Metallaboranes Related to Benzene and Cyclopentadienide
Chemical Bonding Topology of Metal-Centered Polygonal Wheels: Two-Dimensional Analogues of Metallaboranes Related to Benzene and Cyclopentadienide Open
The anion [Au@Ru5(CO)15(μ-CO)4]- has a pentagonal wheel structure that can be derived from a hypothetical pentagonal ruthenium carbonyl cluster Ru5(CO)20 by insertion of a gold atom in the center, thereby splitting the original Ru5 pentago…
View article: Trivalent Polyhedra as Duals of Borane Deltahedra: From Molecular Endohedral Germanium Clusters to the Smallest Fullerenes
Trivalent Polyhedra as Duals of Borane Deltahedra: From Molecular Endohedral Germanium Clusters to the Smallest Fullerenes Open
The duals of the most spherical closo borane deltahedra having from 6 to 16 vertices form a series of homologous spherical trivalent polyhedra with even numbers of vertices from 8 to 28. This series of homologous polyhedra is found in endo…
View article: Effective Irradiance Monitoring Using Reference Modules.
Effective Irradiance Monitoring Using Reference Modules. Open
the convolution of spectral response with solar irradiance are considered. The second is the most accurate technique.
View article: PACT Module Preconditioning Protocol (V.0.1)
PACT Module Preconditioning Protocol (V.0.1) Open
The purpose of this protocol is to bring metal halide perovskite (MHP) modules to a repeatable and relevant state prior to making a performance measurement. Performance measurements are made before and after a stressor has been applied to …
View article: A Randomized Crossover Trial Comparing Glucose Control During Moderate-Intensity, High-Intensity, and Resistance Exercise With Hybrid Closed-Loop Insulin Delivery While Profiling Potential Additional Signals in Adults With Type 1 Diabetes
A Randomized Crossover Trial Comparing Glucose Control During Moderate-Intensity, High-Intensity, and Resistance Exercise With Hybrid Closed-Loop Insulin Delivery While Profiling Potential Additional Signals in Adults With Type 1 Diabetes Open
Objective: To compare glucose control with hybrid closed loop (HCL) when challenged by moderate-intensity exercise (MIE), high-intensity intermittent exercise (HIE) and resistance exercise (RE) while profiling counter-regulatory hormones, …
View article: A Randomized Crossover Trial Comparing Glucose Control During Moderate-Intensity, High-Intensity, and Resistance Exercise With Hybrid Closed-Loop Insulin Delivery While Profiling Potential Additional Signals in Adults With Type 1 Diabetes
A Randomized Crossover Trial Comparing Glucose Control During Moderate-Intensity, High-Intensity, and Resistance Exercise With Hybrid Closed-Loop Insulin Delivery While Profiling Potential Additional Signals in Adults With Type 1 Diabetes Open
Objective: To compare glucose control with hybrid closed loop (HCL) when challenged by moderate-intensity exercise (MIE), high-intensity intermittent exercise (HIE) and resistance exercise (RE) while profiling counter-regulatory hormones, …
View article: Tris(Butadiene) Compounds versus Butadiene Oligomerization in Second-Row Transition Metal Chemistry: Effects of Increased Ligand Fields
Tris(Butadiene) Compounds versus Butadiene Oligomerization in Second-Row Transition Metal Chemistry: Effects of Increased Ligand Fields Open
The geometries, energetics, and preferred spin states of the second-row transition metal tris(butadiene) complexes (C4H6)3M (M = Zr–Pd) and their isomers, including the experimentally known very stable molybdenum derivative (C4H6)3Mo, have…
View article: Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of f Orbitals
Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of f Orbitals Open
The combination of atomic orbitals to form hybrid orbitals of special symmetries can be related to the individual orbital polynomials. Using this approach, 8-orbital cubic hybridization can be shown to be sp3d3f requiring an f orbital, and…
View article: Digital Life Norway AS IS Report
Digital Life Norway AS IS Report Open
This is the first report in a project called “A roadmap for academic research-intensive innovation”, commissioned on behalf of the Digital Life Norway (DLN) project by the University of Oslo. The project is in three parts. This report disc…
View article: An ultrasound-guided fascia iliaca catheter technique does not impair ambulatory ability within a clinical pathway for total hip arthroplasty
An ultrasound-guided fascia iliaca catheter technique does not impair ambulatory ability within a clinical pathway for total hip arthroplasty Open
This corrects the article "An ultrasound-guided fascia iliaca catheter technique does not impair ambulatory ability within a clinical pathway for total hip arthroplasty" on page 368.
View article: Neutral Rhenadicarbaboranes with Re(CO)2(NO) Vertices: A Theoretical Study of Building Blocks for Rhenacarborane-Based Drug Delivery Agents
Neutral Rhenadicarbaboranes with Re(CO)2(NO) Vertices: A Theoretical Study of Building Blocks for Rhenacarborane-Based Drug Delivery Agents Open
The rhenadicarbaborane carbonyl nitrosyls (C2Bn−3Hn−1)Re(CO)2(NO), (n = 8 to 12), of interest in drug delivery agents based on the experimentally known C2B9H11Re(CO)2(NO) and related species, have been investigated by density functional th…
View article: Heterobimetallic Chromium Manganese Carbonyl Nitrosyls: Comparison with Isoelectronic Homometallic Binuclear Chromium Carbonyl Nitrosyls and Manganese Carbonyls
Heterobimetallic Chromium Manganese Carbonyl Nitrosyls: Comparison with Isoelectronic Homometallic Binuclear Chromium Carbonyl Nitrosyls and Manganese Carbonyls Open
The heterometallic chromium-manganese carbonyl nitrosyls CrMn(NO)(CO)n (n = 9, 8) have been investigated by density functional theory. The lowest energy CrMn(NO)(CO)9 structures have unbridged staggered conformations with a ~2.99 Å Cr–Mn s…