Robert Stranger
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View article: Uncovering outer-sphere mechanisms governing chemoselectivity in copper-photocatalyzed ATRA reactions of CF <sub>3</sub> SO <sub>2</sub> Cl with alkenes
Uncovering outer-sphere mechanisms governing chemoselectivity in copper-photocatalyzed ATRA reactions of CF <sub>3</sub> SO <sub>2</sub> Cl with alkenes Open
Cu-photocatalyzed ATRA of CF 3 SO 2 Cl with alkenes proceed via outer-sphere SET pathways. Three distinct mechanisms, S( vi )/S( iv ) redox cycling, 2c–3e Cl-induced SET, and a cationic route, account for the divergent RSO 2 Cl and RCl for…
View article: Gold Is Not Palladium: Linear Selectivity in Gold-Catalyzed Heck-Type Arylation via an Allylic Deprotonation–Coupling (ADC) Mechanism
Gold Is Not Palladium: Linear Selectivity in Gold-Catalyzed Heck-Type Arylation via an Allylic Deprotonation–Coupling (ADC) Mechanism Open
Gold-catalyzed arylation of alkenes has recently been reported by Patil and co-workers as a rare example of a Heck-type reaction exhibiting exclusive linear selectivity. However, no mechanistic rationale was provided for the complete suppr…
View article: The Low Oxidation State Paradigm is More Consistent with XFEL Observations of the S₃ → [S₄] → S₀ Transition in Photosystem II
The Low Oxidation State Paradigm is More Consistent with XFEL Observations of the S₃ → [S₄] → S₀ Transition in Photosystem II Open
Photosynthetic water splitting catalyzed by the Mn 4 CaO 5/6 cluster in the oxygen‐evolving complex (OEC) of photosystem II (PSII) is crucial for sustaining the supply of oxygen on the Earth. A recent serial femtosecond X‐ray crystallograp…
View article: Copper(I)‐Catalyzed Acid‐Controlled Divergent Radical Cyclization of 1,6‐Enynes to Access 1‐Indanones and 1H‐Cyclopropa[<i>b</i>] Naphthalene‐2,7‐diones
Copper(I)‐Catalyzed Acid‐Controlled Divergent Radical Cyclization of 1,6‐Enynes to Access 1‐Indanones and 1H‐Cyclopropa[<i>b</i>] Naphthalene‐2,7‐diones Open
1‐Indanone derivatives are efficiently synthesized via a radical cyclization reaction of 1,6‐enynes, using TBHP as both oxidant and reactant, in the presence of Cu(I) as the catalyst and 4‐methyl benzoic acid as the cocatalyst. Notably, in…
View article: Mechanisms of Mn(V)‐Oxo to Mn(IV)‐Oxyl Conversion: From Closed‐Cubane Photosystem II to Mn(V) Catalysts and the Role of the Entering Ligands
Mechanisms of Mn(V)‐Oxo to Mn(IV)‐Oxyl Conversion: From Closed‐Cubane Photosystem II to Mn(V) Catalysts and the Role of the Entering Ligands Open
The low activation barrier for O−O coupling in the closed‐cubane Oxygen‐Evolving Centre (OEC) of Photosystem II (PSII) requires water coordination with the Mn4 ′dangler′ ion in the Mn(V)‐oxo fragment. This coordination transforms the Mn(V)…
View article: Exchange coupling in A3Mo2X9 complex salts : a magneto-structural, spectroscopic and theoretical investigation
Exchange coupling in A3Mo2X9 complex salts : a magneto-structural, spectroscopic and theoretical investigation Open
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View article: Correction: The prospects of developing a highly energy-efficient water electrolyser by eliminating or mitigating bubble effects
Correction: The prospects of developing a highly energy-efficient water electrolyser by eliminating or mitigating bubble effects Open
Correction for ‘The prospects of developing a highly energy-efficient water electrolyser by eliminating or mitigating bubble effects’ by Gerhard F. Swiegers et al., Sustainable Energy Fuels, 2021, 5, 1280–1310, DOI: 10.1039/D0SE01886D.
View article: CCDC 1878634: Experimental Crystal Structure Determination
CCDC 1878634: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1878632: Experimental Crystal Structure Determination
CCDC 1878632: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1878626: Experimental Crystal Structure Determination
CCDC 1878626: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1878631: Experimental Crystal Structure Determination
CCDC 1878631: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1878627: Experimental Crystal Structure Determination
CCDC 1878627: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1878629: Experimental Crystal Structure Determination
CCDC 1878629: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1878625: Experimental Crystal Structure Determination
CCDC 1878625: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1878628: Experimental Crystal Structure Determination
CCDC 1878628: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1878630: Experimental Crystal Structure Determination
CCDC 1878630: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1558318: Experimental Crystal Structure Determination
CCDC 1558318: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1878624: Experimental Crystal Structure Determination
CCDC 1878624: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1878633: Experimental Crystal Structure Determination
CCDC 1878633: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1443854: Experimental Crystal Structure Determination
CCDC 1443854: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Linear Optical, Quadratic and Cubic Nonlinear Optical, Electrochemical, and Theoretical Studies of “Rigid‐Rod” Bis‐Alkynyl Ruthenium Complexes
Linear Optical, Quadratic and Cubic Nonlinear Optical, Electrochemical, and Theoretical Studies of “Rigid‐Rod” Bis‐Alkynyl Ruthenium Complexes Open
The syntheses of oligo( p‐ phenylene ethynylene)s (OPEs) end‐functionalized by a nitro acceptor group and with a ligated ruthenium unit at varying locations in the OPE chain, namely, trans ‐[Ru{(C≡C‐1,4‐C 6 H 4 ) n NO 2 }(C≡CR)(dppe) 2 ] (…
View article: CCDC 1533616: Experimental Crystal Structure Determination
CCDC 1533616: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1533617: Experimental Crystal Structure Determination
CCDC 1533617: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Iron and Ruthenium Alkynyl Complexes with 2‐Fluorenyl Groups: Some Linear and Nonlinear Optical Absorption Properties
Iron and Ruthenium Alkynyl Complexes with 2‐Fluorenyl Groups: Some Linear and Nonlinear Optical Absorption Properties Open
Four new mononuclear alkynyl complexes each featuring a terminal 2‐fluorenyl group, namely Fe(η 5 ‐C 5 Me 5 )(CO) 2 [C≡C(2‐C 21 H 25 )] ( 2 ), Ru(κ 2 ‐dppe) 2 Cl[C≡C(2‐C 21 H 25 )] ( 3 ), Ru(κ 2 ‐dppe) 2 [C≡C(4‐C 6 H 4 NO 2 )][C≡C(2‐C 21 H…
View article: CCDC 1456585: Experimental Crystal Structure Determination
CCDC 1456585: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 988100: Experimental Crystal Structure Determination
CCDC 988100: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1433855: Experimental Crystal Structure Determination
CCDC 1433855: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1460738: Experimental Crystal Structure Determination
CCDC 1460738: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …