Robin D. Rogers
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View article: Nose-to-brain translocation of inhaled ultrafine elongated particles: facts and mysteries
Nose-to-brain translocation of inhaled ultrafine elongated particles: facts and mysteries Open
In this study, we report that inhaled nanosized elongated mineral particles (EMPs) reach the human central nervous system (CNS) via two neuronal pathways, cranial nerve I (olfactorius) and cranial nerve V (trigeminus), from deposits on the…
View article: Crystallographic Snapshots of Pre- and Post-Lanthanide Halide Hydrolysis─Reaction Products Captured by the 4-Amino-1,2,4-triazole Ligand
Crystallographic Snapshots of Pre- and Post-Lanthanide Halide Hydrolysis─Reaction Products Captured by the 4-Amino-1,2,4-triazole Ligand Open
Reactions of lanthanide-(III) chloride salts with 4-amino-1,2,4-triazole (4-NH2-1,2,4-Triaz) in azole melts have led to the isolation of both hydrolysis and nonhydrolysis products in the same synthesis, with the inclusion of a variety of l…
View article: Is Kraft Pulping the Future of Biorefineries? A Perspective on the Sustainability of Lignocellulosic Product Development
Is Kraft Pulping the Future of Biorefineries? A Perspective on the Sustainability of Lignocellulosic Product Development Open
By reflecting on the history and environmental impact of conventional biorefining, such as kraft pulping, we aim to explore important questions about how natural polymers can be more sustainably sourced to develop bio-products and reduce r…
View article: Use of Ionic Liquids for Hemp Fiber Degumming
Use of Ionic Liquids for Hemp Fiber Degumming Open
Degumming or retting to remove pectin, lignin, and hemicellulose is a critical step in the production of high-quality hemp fibers. Current technologies, including traditional water or dew retting, as well as chemical, enzymatic, and physic…
View article: Exploring the Nature of f-Element Soft Donor Interactions Using Electronically Tunable Azolate Ionic Liquids
Exploring the Nature of f-Element Soft Donor Interactions Using Electronically Tunable Azolate Ionic Liquids Open
This project was undertaken to advance the understanding of how f-elements interact with moderately soft donors, a heavily investigated yet open question which is of prime importance in spent nuclear fuel processing and fundamental inorgan…
View article: Novel strategies for terephthalic acid processing under soft conditions using ionic liquids
Novel strategies for terephthalic acid processing under soft conditions using ionic liquids Open
Terephthalic acid (H2TPA) solubility in several ionic liquids (ILs) at multiple concentrations is higher than for any other known solvents at lower temperatures and pressures which suggests low energy purification of H2TPA from its major i…
View article: CCDC 2304512: Experimental Crystal Structure Determination
CCDC 2304512: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2304513: Experimental Crystal Structure Determination
CCDC 2304513: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2304514: Experimental Crystal Structure Determination
CCDC 2304514: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2304511: Experimental Crystal Structure Determination
CCDC 2304511: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Exploring the Role of Neutral 4-Amino-1,2,4-triazole in the Formation of Hexanuclear f-Element Hydrolysis Products
Exploring the Role of Neutral 4-Amino-1,2,4-triazole in the Formation of Hexanuclear f-Element Hydrolysis Products Open
Our recent observations of an unexpected Ce(III) hydrolysis product from the reaction of 4-amino-1,2,4-triazole (4-NH2-1,2,4-Triaz) with CeCl3·7H2O, [Ce6(μ3-O)4(μ3-OH)2(μ3-Cl)2(Cl)6(μ2-4-NH2-1,2,4-Triaz)12]·7H2O, the first high-nuclearity …
View article: CCDC 1920436: Experimental Crystal Structure Determination
CCDC 1920436: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1920438: Experimental Crystal Structure Determination
CCDC 1920438: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1920437: Experimental Crystal Structure Determination
CCDC 1920437: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2255844: Experimental Crystal Structure Determination
CCDC 2255844: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2064906: Experimental Crystal Structure Determination
CCDC 2064906: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2064904: Experimental Crystal Structure Determination
CCDC 2064904: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2064902: Experimental Crystal Structure Determination
CCDC 2064902: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2064903: Experimental Crystal Structure Determination
CCDC 2064903: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2249342: Experimental Crystal Structure Determination
CCDC 2249342: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Trapping an Unexpected/Unprecedented Hexanuclear Ce(III) Hydrolysis Product with Neutral 4‐Amino‐1,2,4‐triazole
Trapping an Unexpected/Unprecedented Hexanuclear Ce(III) Hydrolysis Product with Neutral 4‐Amino‐1,2,4‐triazole Open
Using Ce(III) as both a representative lanthanide and actinide analog, the ability of mixtures of acidic and basic azoles to allow direct access to homoleptic N‐donor f‐element complexes in one pot reactions from hydrated salts as starting…
View article: CCDC 1963861: Experimental Crystal Structure Determination
CCDC 1963861: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2041904: Experimental Crystal Structure Determination
CCDC 2041904: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2041903: Experimental Crystal Structure Determination
CCDC 2041903: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: The 8‐Hydroxyquinolinium Cation as a Lead Structure for Efficient Color‐Tunable Ionic Small Molecule Emitting Materials
The 8‐Hydroxyquinolinium Cation as a Lead Structure for Efficient Color‐Tunable Ionic Small Molecule Emitting Materials Open
In article number 2200279, Anja-Verena Mudring and coworkers identified 8-hydroxyquinolinium cation as a lead structure for luminescent ionic small molecules with good potential for expansion. All obtained compounds showed comparable, and …
View article: Cellulose Gel Mechanoreceptors – Principles, Applications and Prospects
Cellulose Gel Mechanoreceptors – Principles, Applications and Prospects Open
In order to effectively harness varieties of mechanical waves or vibrations for the purpose of monitoring and/or powering, developments in responsive materials and conversion technologies are taking place driven by the world's current and …
View article: The 8‐Hydroxyquinolinium Cation as a Lead Structure for Efficient Color‐Tunable Ionic Small Molecule Emitting Materials
The 8‐Hydroxyquinolinium Cation as a Lead Structure for Efficient Color‐Tunable Ionic Small Molecule Emitting Materials Open
Albeit tris(8‐hydroxyquinolinato) aluminum (Alq 3 ) and its derivatives are prominent emitter materials for organic lighting devices, and the optical transitions occur among ligand‐centered states, the use of metal‐free 8‐hydroxyquinoline …
View article: Process for separating and recovering an anionic dye from an aqueous solution
Process for separating and recovering an anionic dye from an aqueous solution Open
A solid/liquid phase process for the separation and recovery of an anionic dye from an aqueous solution is disclosed. The solid phase comprises separation particles having surface-bonded poly(ethylene glycol) groups, whereas the aqueous so…
View article: Process for recovering chaotropic anions from an aqueous solution also containing other ions
Process for recovering chaotropic anions from an aqueous solution also containing other ions Open
A solid/liquid process for the separation and recovery of chaotropic anions from an aqueous solution is disclosed. The solid support comprises separation particles having surface-bonded poly(ethylene glycol) groups, whereas the aqueous sol…