Robin N. Perutz
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View article: Platinum(II) Phenylpyridyl Schiff Base Complexes as Latent, Photoactivated, Alkene Hydrosilylation Catalysts
Platinum(II) Phenylpyridyl Schiff Base Complexes as Latent, Photoactivated, Alkene Hydrosilylation Catalysts Open
Photoactivated catalysts for the hydrosilylation of alkenes with silanes offer temporal control in manufacturing processes that require silicone curing. We report the development of a range of air-stable Pt(II) (salicylaldimine)(phenylpyri…
View article: Applications of Transition Metal-Catalyzed <i>ortho</i>-Fluorine-Directed C–H Functionalization of (Poly)fluoroarenes in Organic Synthesis
Applications of Transition Metal-Catalyzed <i>ortho</i>-Fluorine-Directed C–H Functionalization of (Poly)fluoroarenes in Organic Synthesis Open
The synthesis of organic compounds efficiently via fewer steps but in higher yields is desirable as this reduces energy and reagent use, waste production, and thus environmental impact as well as cost. The reactivity of C-H bonds ortho to …
View article: Opening a Pandora’s Flask on a Prototype Catalytic Direct Arylation Reaction of Pentafluorobenzene: The Ag<sub>2</sub>CO<sub>3</sub>/Pd(OAc)<sub>2</sub>/PPh<sub>3</sub> System
Opening a Pandora’s Flask on a Prototype Catalytic Direct Arylation Reaction of Pentafluorobenzene: The Ag<sub>2</sub>CO<sub>3</sub>/Pd(OAc)<sub>2</sub>/PPh<sub>3</sub> System Open
Direct C-H functionalization reactions have opened new avenues in catalysis, removing the need for prefunctionalization of at least one of the substrates. Although C-H functionalization catalyzed by palladium complexes in the presence of a…
View article: CCDC 2214532: Experimental Crystal Structure Determination
CCDC 2214532: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214531: Experimental Crystal Structure Determination
CCDC 2214531: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214533: Experimental Crystal Structure Determination
CCDC 2214533: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Solid-State <sup>19</sup>F NMR Chemical Shift in Square-Planar Nickel–Fluoride Complexes Linked by Halogen Bonds
Solid-State <sup>19</sup>F NMR Chemical Shift in Square-Planar Nickel–Fluoride Complexes Linked by Halogen Bonds Open
The halogen bond (XB) is a highly directional class of noncovalent interactions widely explored by experimental and computational studies. However, the NMR signature of the XB has attracted limited attention. The prediction and analysis of…
View article: CCDC 2110194: Experimental Crystal Structure Determination
CCDC 2110194: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2110193: Experimental Crystal Structure Determination
CCDC 2110193: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2110192: Experimental Crystal Structure Determination
CCDC 2110192: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2160367: Experimental Crystal Structure Determination
CCDC 2160367: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Direct Evidence for Competitive C–H Activation by a Well-Defined Silver XPhos Complex in Palladium-Catalyzed C–H Functionalization
Direct Evidence for Competitive C–H Activation by a Well-Defined Silver XPhos Complex in Palladium-Catalyzed C–H Functionalization Open
Increasing evidence indicates that silver salts can play a role in the C–H activation step of palladium-catalyzed C–H functionalization. Here we isolate a silver(I) complex by C–H bond activation and demonstrate its catalytic competence fo…
View article: Graphical Abstract: Angew. Chem. Int. Ed. 5/2022
Graphical Abstract: Angew. Chem. Int. Ed. 5/2022 Open
SonosensitizersAn aggregation-enhanced sonodynamic activity (AESA) effect is reported by Mei-Rong Ke,Jian-Dong Huang et al. in their Communication (e202113506).The AESA effect could open up anew avenue for the development of efficient sono…
View article: Photochemistry of transition metal carbonyls
Photochemistry of transition metal carbonyls Open
Ultrafast photodissociation of metal carbonyls leads to wavelength-selective photochemistry with applications in photo-induced polymerisation, catalysis, CO-release, synthesis and surface modification.
View article: Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism
Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism Open
In 2007 two of us defined the σ‐Complex Assisted Metathesis mechanism (Perutz and Sabo‐Etienne, Angew. Chem. Int. Ed . 2007 , 46 , 2578–2592), that is, the σ‐CAM concept. This new approach to reaction mechanisms brought together metathesis…
View article: Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism
Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism Open
In 2007 two of us defined the σ‐Complex Assisted Metathesis mechanism (Perutz and Sabo‐Etienne, Angew. Chem. Int. Ed . 2007 , 46 , 2578–2592), that is, the σ‐CAM concept. This new approach to reaction mechanisms brought together metathesis…
View article: CCDC 1952928: Experimental Crystal Structure Determination
CCDC 1952928: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Benchmarking of Halogen Bond Strength in Solution with Nickel Fluorides: Bromine versus Iodine and Perfluoroaryl versus Perfluoroalkyl Donors
Benchmarking of Halogen Bond Strength in Solution with Nickel Fluorides: Bromine versus Iodine and Perfluoroaryl versus Perfluoroalkyl Donors Open
The energetics of halogen bond formation in solution have been investigated for a series of nickel fluoride halogen bond acceptors; trans ‐[NiF(2‐C 5 NF 4 )(PEt 3 ) 2 ] ( A1 ), trans ‐[NiF{2‐C 5 NF 3 (4‐H)}(PEt 3 ) 2 ] ( A2 ), trans ‐[NiF{…
View article: CCDC 1874663: Experimental Crystal Structure Determination
CCDC 1874663: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1874662: Experimental Crystal Structure Determination
CCDC 1874662: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Towards measuring reactivity on micro-to-millisecond timescales with laser pump, NMR probe spectroscopy
Towards measuring reactivity on micro-to-millisecond timescales with laser pump, NMR probe spectroscopy Open
We present a quantitative analysis of the timescales of reactivity that are accessible to a laser pump, NMR probe spectroscopy method using para-hydrogen induced polarisation (PHIP) and identify three kinetic regimes: fast, intermediate an…
View article: Mechanistic insight into organic and industrial transformations: general discussion
Mechanistic insight into organic and industrial transformations: general discussion Open
\n Contains fulltext :\n 215022.pdf (Publisher’s version ) (Open Access)\n
View article: Computational and theoretical approaches for mechanistic understanding: general discussion
Computational and theoretical approaches for mechanistic understanding: general discussion Open
The first page of this article is displayed as the abstract.
View article: Physical methods for mechanistic understanding: general discussion
Physical methods for mechanistic understanding: general discussion Open
Contains fulltext : 214864.pdf (Publisher’s version ) (Open Access)
View article: Competing Pathways in the Photochemistry of Ru(H)<sub>2</sub>(CO)(PPh<sub>3</sub>)<sub>3</sub>
Competing Pathways in the Photochemistry of Ru(H)<sub>2</sub>(CO)(PPh<sub>3</sub>)<sub>3</sub> Open
The photochemistry of Ru(H)(CO)(PPh) (1) has been reinvestigated employing laser and conventional light sources in conjunction with NMR spectroscopy and IR spectroscopy. The sensitivity of NMR experiments was enhanced by use of p-H-induced…
View article: CCDC 1825445: Experimental Crystal Structure Determination
CCDC 1825445: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …